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Rational Design of Ni-Doped V<sub<2</sub<O<sub<5</sub<3D Ni Core/Shell Composites for High-Voltage and High-Rate Aqueous Zinc-Ion Batteries
Aqueous zinc-ion batteries (ZIBs) have significant potential for large energy storage systems because of their high energy density, cost-effectiveness and environmental friendliness. However, the limited voltage window, poor reaction kinetics and structural instability of cathode materials are curre...
Ausführliche Beschreibung
Aqueous zinc-ion batteries (ZIBs) have significant potential for large energy storage systems because of their high energy density, cost-effectiveness and environmental friendliness. However, the limited voltage window, poor reaction kinetics and structural instability of cathode materials are current bottlenecks which contain the further development of ZIBs. In this work, we rationally design a Ni-doped V<sub<2</sub<O<sub<5</sub<3D Ni core/shell composite on a carbon cloth electrode (Ni-V<sub<2</sub<O<sub<5</sub<@3D Ni@CC) by growing Ni-V<sub<2</sub<O<sub<5</sub< on free-standing 3D Ni metal nanonets for high-voltage and high-capacity ZIBs. Impressively, embedded Ni doping increases the interlayer spacing of V<sub<2</sub<O<sub<5</sub<, extending the working voltage and improving the zinc-ion (Zn<sub<30</sub<<sup<2+</sup<) reaction kinetics of the cathode materials; at the same time, the 3D structure, with its high specific surface area and superior electronic conductivity, aids in fast Zn<sub<30</sub<<sup<2+</sup< transport. Consequently, the as-designed Ni-V<sub<2</sub<O<sub<5</sub<@3D Ni@CC cathodes can operate within a wide voltage window from 0.3 to 1.8 V vs. Zn<sub<30</sub</Zn<sub<30</sub<<sup<2+</sup< and deliver a high capacity of 270 mAh g<sup<−1</sup< (~1050 mAh cm<sup<−3</sup<) at a high current density of 0.8 A g<sup<−1</sup<. In addition, reversible Zn<sup<2+</sup< (de)incorporation reaction mechanisms in the Ni-V<sub<2</sub<O<sub<5</sub<@3D Ni@CC cathodes are investigated through multiple characterization methods (SEM, TEM, XRD, XPS, etc.). As a result, we achieved significant progress toward practical applications of ZIBs. Ausführliche Beschreibung