An irregular g factor in the NO"2 ^2B^2 state: Optical-radio-frequency double-resonance and zero-field level-crossing spectroscopy on NO"2

Optical-radio-frequency double-resonance and zero-field level-crossing spectroscopy are performed on NO"2 in a molecular beam excited at the 593.3 nm band with a dye laser. The g factor of the ^2B"2 state of NO"2 depends on the quantum number K of the near-prolate symmetric top, and t...
Ausführliche Beschreibung

Optical-radio-frequency double-resonance and zero-field level-crossing spectroscopy are performed on NO"2 in a molecular beam excited at the 593.3 nm band with a dye laser. The g factor of the ^2B"2 state of NO"2 depends on the quantum number K of the near-prolate symmetric top, and this is attributed to a contribution of a spin-linked unquenched orbital angular momentum. Ausführliche Beschreibung