NR/SBR composites reinforced with organically functionalized MWCNTs: simultaneous improvement of tensile strength and elongation and enhanced thermal stability

Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal p...
Ausführliche Beschreibung

Butyl acrylate-α-methyl methacrylate-glycidyl methacrylate (BA-MMA-GMA) terpolymer was successfully grafted onto carbon nanotubes (CNTs) via a facile grafting functionalization approach, affording an organically functionalized multiwalled CNTs (O-MWCNTs), which show improved mechanical and thermal properties in natural rubber/styrene-butadiene rubber (NR/SBR) composites. Under optimized conditions, the result of elongation at break of NR/SBR composites combined with 1.5 parts per hundred rubber (phr) O-MWCNTs is 450% compared to 376% of pristine NR/SBR composites, which is proportional to tensile strength due to the mixed O-MWCNTs in the rubber matrix. Transmission electron microscopy study shows that O-MWCNTs (1.5 phr) can disperse uniformly in NR/SBR/O-MWCNT composites. A scanning electron microscopy study on the fractured surface morphology of the optimized composites reveals that a BA-MMA-GMA terpolymer can interact with the rubber matrix strongly. The decreased height of the maximum tanδ peak shows that O-MWCNTs can reduce the heat buildup and damping capability of NR/SBR/O-MWCNT composites. The largest enhancement observed in the thermal degradation curves of composites is, for the first time, about 70°C, which can be attributed to enhanced interfacial interaction between MWCNTs and the rubber matrix. Ausführliche Beschreibung