Ruthenium nanoparticles in high-throughput studies of chemoselective carbonyl hydrogenation reactions
Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gmeiner, Julia Renate [verfasserIn] Behrens, Silke - 1969- [verfasserIn] Spliethoff, Bernd [verfasserIn] Trapp, Oliver - 1973- [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Schlagwörter: |
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| Anmerkung: |
First published: 23 December 2015 Gesehen am 19.06.2020 |
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| Umfang: |
6 |
| Übergeordnetes Werk: |
Enthalten in: ChemCatChem - Weinheim : Wiley-VCH, 2009, 8(2016), 3, Seite 571-576 |
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| Übergeordnetes Werk: |
volume:8 ; year:2016 ; number:3 ; pages:571-576 ; extent:6 |
| Links: |
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| DOI / URN: |
10.1002/cctc.201501069 |
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| Katalog-ID: |
1701149753 |
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| 520 | |a Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC?MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3?mol?% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis. | ||
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10.1002/cctc.201501069 doi (DE-627)1701149753 (DE-599)KXP1701149753 (OCoLC)1341340728 DE-627 ger DE-627 rda eng Gmeiner, Julia Renate verfasserin (DE-588)111586159X (DE-627)870105582 (DE-576)478102739 aut Ruthenium nanoparticles in high-throughput studies of chemoselective carbonyl hydrogenation reactions Julia Gmeiner, Silke Behrens, Bernd Spliethoff, and Oliver Trapp 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier First published: 23 December 2015 Gesehen am 19.06.2020 Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC?MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3?mol?% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis. 2015 heterogeneous catalysis high-throughput screening homogeneous catalysis hydrogenation nanoparticles Behrens, Silke 1969- verfasserin (DE-588)120297752 (DE-627)696543656 (DE-576)292145772 aut Spliethoff, Bernd verfasserin aut Trapp, Oliver 1973- verfasserin (DE-588)123258634 (DE-627)70623071X (DE-576)184366003 aut Enthalten in ChemCatChem Weinheim : Wiley-VCH, 2009 8(2016), 3, Seite 571-576 Online-Ressource (DE-627)603484395 (DE-600)2501161-3 (DE-576)308344928 1867-3899 nnns volume:8 year:2016 number:3 pages:571-576 extent:6 https://doi.org/10.1002/cctc.201501069 Verlag Resolving-System lizenzpflichtig Volltext https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cctc.201501069 Verlag lizenzpflichtig Volltext GBV_USEFLAG_U GBV_ILN_2013 ISIL_DE-16-250 SYSFLAG_1 GBV_KXP SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 8 2016 3 571-576 6 2013 01 DE-16-250 3688904524 00 --%%-- --%%-- --%%-- --%%-- l01 19-06-20 2013 01 DE-16-250 00 s hd2016 2013 01 DE-16-250 01 s (DE-627)1410508463 wissenschaftlicher Artikel (Zeitschrift) 2013 01 DE-16-250 02 s per_4 2013 01 DE-16-250 03 s s_6 2013 01 DE-16-250 04 p (DE-627)1669590852 Gmeiner, Julia Renate 2013 01 DE-16-250 04 k (DE-627)1416528067 Organisch-Chemisches Institut (OCI) 2013 01 DE-16-250 04 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 04 s pos_1 2013 01 DE-16-250 05 p (DE-627)1572348208 Behrens, Silke 2013 01 DE-16-250 05 k (DE-627)1416534733 Fakultät für Chemie und Geowissenschaften 2013 01 DE-16-250 05 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 05 s pos_2 2013 01 DE-16-250 06 p (DE-627)1439978034 Trapp, Oliver 2013 01 DE-16-250 06 k (DE-627)1416528067 Organisch-Chemisches Institut (OCI) 2013 01 DE-16-250 06 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 06 s pos_4 |
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10.1002/cctc.201501069 doi (DE-627)1701149753 (DE-599)KXP1701149753 (OCoLC)1341340728 DE-627 ger DE-627 rda eng Gmeiner, Julia Renate verfasserin (DE-588)111586159X (DE-627)870105582 (DE-576)478102739 aut Ruthenium nanoparticles in high-throughput studies of chemoselective carbonyl hydrogenation reactions Julia Gmeiner, Silke Behrens, Bernd Spliethoff, and Oliver Trapp 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier First published: 23 December 2015 Gesehen am 19.06.2020 Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC?MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3?mol?% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis. 2015 heterogeneous catalysis high-throughput screening homogeneous catalysis hydrogenation nanoparticles Behrens, Silke 1969- verfasserin (DE-588)120297752 (DE-627)696543656 (DE-576)292145772 aut Spliethoff, Bernd verfasserin aut Trapp, Oliver 1973- verfasserin (DE-588)123258634 (DE-627)70623071X (DE-576)184366003 aut Enthalten in ChemCatChem Weinheim : Wiley-VCH, 2009 8(2016), 3, Seite 571-576 Online-Ressource (DE-627)603484395 (DE-600)2501161-3 (DE-576)308344928 1867-3899 nnns volume:8 year:2016 number:3 pages:571-576 extent:6 https://doi.org/10.1002/cctc.201501069 Verlag Resolving-System lizenzpflichtig Volltext https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cctc.201501069 Verlag lizenzpflichtig Volltext GBV_USEFLAG_U GBV_ILN_2013 ISIL_DE-16-250 SYSFLAG_1 GBV_KXP SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 8 2016 3 571-576 6 2013 01 DE-16-250 3688904524 00 --%%-- --%%-- --%%-- --%%-- l01 19-06-20 2013 01 DE-16-250 00 s hd2016 2013 01 DE-16-250 01 s (DE-627)1410508463 wissenschaftlicher Artikel (Zeitschrift) 2013 01 DE-16-250 02 s per_4 2013 01 DE-16-250 03 s s_6 2013 01 DE-16-250 04 p (DE-627)1669590852 Gmeiner, Julia Renate 2013 01 DE-16-250 04 k (DE-627)1416528067 Organisch-Chemisches Institut (OCI) 2013 01 DE-16-250 04 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 04 s pos_1 2013 01 DE-16-250 05 p (DE-627)1572348208 Behrens, Silke 2013 01 DE-16-250 05 k (DE-627)1416534733 Fakultät für Chemie und Geowissenschaften 2013 01 DE-16-250 05 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 05 s pos_2 2013 01 DE-16-250 06 p (DE-627)1439978034 Trapp, Oliver 2013 01 DE-16-250 06 k (DE-627)1416528067 Organisch-Chemisches Institut (OCI) 2013 01 DE-16-250 06 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 06 s pos_4 |
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10.1002/cctc.201501069 doi (DE-627)1701149753 (DE-599)KXP1701149753 (OCoLC)1341340728 DE-627 ger DE-627 rda eng Gmeiner, Julia Renate verfasserin (DE-588)111586159X (DE-627)870105582 (DE-576)478102739 aut Ruthenium nanoparticles in high-throughput studies of chemoselective carbonyl hydrogenation reactions Julia Gmeiner, Silke Behrens, Bernd Spliethoff, and Oliver Trapp 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier First published: 23 December 2015 Gesehen am 19.06.2020 Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC?MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3?mol?% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis. 2015 heterogeneous catalysis high-throughput screening homogeneous catalysis hydrogenation nanoparticles Behrens, Silke 1969- verfasserin (DE-588)120297752 (DE-627)696543656 (DE-576)292145772 aut Spliethoff, Bernd verfasserin aut Trapp, Oliver 1973- verfasserin (DE-588)123258634 (DE-627)70623071X (DE-576)184366003 aut Enthalten in ChemCatChem Weinheim : Wiley-VCH, 2009 8(2016), 3, Seite 571-576 Online-Ressource (DE-627)603484395 (DE-600)2501161-3 (DE-576)308344928 1867-3899 nnns volume:8 year:2016 number:3 pages:571-576 extent:6 https://doi.org/10.1002/cctc.201501069 Verlag Resolving-System lizenzpflichtig Volltext https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cctc.201501069 Verlag lizenzpflichtig Volltext GBV_USEFLAG_U GBV_ILN_2013 ISIL_DE-16-250 SYSFLAG_1 GBV_KXP SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 8 2016 3 571-576 6 2013 01 DE-16-250 3688904524 00 --%%-- --%%-- --%%-- --%%-- l01 19-06-20 2013 01 DE-16-250 00 s hd2016 2013 01 DE-16-250 01 s (DE-627)1410508463 wissenschaftlicher Artikel (Zeitschrift) 2013 01 DE-16-250 02 s per_4 2013 01 DE-16-250 03 s s_6 2013 01 DE-16-250 04 p (DE-627)1669590852 Gmeiner, Julia Renate 2013 01 DE-16-250 04 k (DE-627)1416528067 Organisch-Chemisches Institut (OCI) 2013 01 DE-16-250 04 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 04 s pos_1 2013 01 DE-16-250 05 p (DE-627)1572348208 Behrens, Silke 2013 01 DE-16-250 05 k (DE-627)1416534733 Fakultät für Chemie und Geowissenschaften 2013 01 DE-16-250 05 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 05 s pos_2 2013 01 DE-16-250 06 p (DE-627)1439978034 Trapp, Oliver 2013 01 DE-16-250 06 k (DE-627)1416528067 Organisch-Chemisches Institut (OCI) 2013 01 DE-16-250 06 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 06 s pos_4 |
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10.1002/cctc.201501069 doi (DE-627)1701149753 (DE-599)KXP1701149753 (OCoLC)1341340728 DE-627 ger DE-627 rda eng Gmeiner, Julia Renate verfasserin (DE-588)111586159X (DE-627)870105582 (DE-576)478102739 aut Ruthenium nanoparticles in high-throughput studies of chemoselective carbonyl hydrogenation reactions Julia Gmeiner, Silke Behrens, Bernd Spliethoff, and Oliver Trapp 2016 6 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier First published: 23 December 2015 Gesehen am 19.06.2020 Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC?MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3?mol?% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis. 2015 heterogeneous catalysis high-throughput screening homogeneous catalysis hydrogenation nanoparticles Behrens, Silke 1969- verfasserin (DE-588)120297752 (DE-627)696543656 (DE-576)292145772 aut Spliethoff, Bernd verfasserin aut Trapp, Oliver 1973- verfasserin (DE-588)123258634 (DE-627)70623071X (DE-576)184366003 aut Enthalten in ChemCatChem Weinheim : Wiley-VCH, 2009 8(2016), 3, Seite 571-576 Online-Ressource (DE-627)603484395 (DE-600)2501161-3 (DE-576)308344928 1867-3899 nnns volume:8 year:2016 number:3 pages:571-576 extent:6 https://doi.org/10.1002/cctc.201501069 Verlag Resolving-System lizenzpflichtig Volltext https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cctc.201501069 Verlag lizenzpflichtig Volltext GBV_USEFLAG_U GBV_ILN_2013 ISIL_DE-16-250 SYSFLAG_1 GBV_KXP SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 8 2016 3 571-576 6 2013 01 DE-16-250 3688904524 00 --%%-- --%%-- --%%-- --%%-- l01 19-06-20 2013 01 DE-16-250 00 s hd2016 2013 01 DE-16-250 01 s (DE-627)1410508463 wissenschaftlicher Artikel (Zeitschrift) 2013 01 DE-16-250 02 s per_4 2013 01 DE-16-250 03 s s_6 2013 01 DE-16-250 04 p (DE-627)1669590852 Gmeiner, Julia Renate 2013 01 DE-16-250 04 k (DE-627)1416528067 Organisch-Chemisches Institut (OCI) 2013 01 DE-16-250 04 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 04 s pos_1 2013 01 DE-16-250 05 p (DE-627)1572348208 Behrens, Silke 2013 01 DE-16-250 05 k (DE-627)1416534733 Fakultät für Chemie und Geowissenschaften 2013 01 DE-16-250 05 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 05 s pos_2 2013 01 DE-16-250 06 p (DE-627)1439978034 Trapp, Oliver 2013 01 DE-16-250 06 k (DE-627)1416528067 Organisch-Chemisches Institut (OCI) 2013 01 DE-16-250 06 s (DE-627)1410501914 Verfasser 2013 01 DE-16-250 06 s pos_4 |
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Elektronische Aufsätze |
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Gmeiner, Julia Renate |
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ruthenium nanoparticles in high-throughput studies of chemoselective carbonyl hydrogenation reactions |
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Ruthenium nanoparticles in high-throughput studies of chemoselective carbonyl hydrogenation reactions |
| abstract |
Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC?MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3?mol?% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis. First published: 23 December 2015 Gesehen am 19.06.2020 |
| abstractGer |
Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC?MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3?mol?% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis. First published: 23 December 2015 Gesehen am 19.06.2020 |
| abstract_unstemmed |
Abstract Small (≤1.4?nm) and very active Ru nanoparticles, stabilized in a polysiloxane matrix, were prepared and studied in hydrogenation reactions by the integration of catalysis and analysis. We used our strategy to combine catalytic activity and separation selectivity in a capillary microreactor, installed in a GC?MS instrument, to develop a fast and reliable screening tool for catalysis over Ru nanoparticles. A high conversion using a low catalyst loading of 0.3?mol?% and temperature and long-term stability of the catalytically active column were observed for the hydrogenation of various carbonyl compounds, which included aldehydes, ketones, and pyruvates. Additionally, we observed a high chemoselectivity for aromatic carbonyl systems. Comprehensive measurements were performed in this high-throughput experimental setup to gain important insights into the kinetics of hydrogenation reactions at the interface between heterogeneous and homogeneous catalysis. First published: 23 December 2015 Gesehen am 19.06.2020 |
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Ruthenium nanoparticles in high-throughput studies of chemoselective carbonyl hydrogenation reactions |
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