Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries

Cathode materials made of xLiVPO4F·yLi3V2(PO4)3/C (x:y = 1:0, 2:1, 0:1) are synthesized via a feasible sol-gel method for high-performance lithium-ion batteries. The structures, morphology, and electrochemical properties of the composites are thoroughly investigated. The results show that LiVPO4F/C,...
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Autor*in:	Shengkui Zhong [verfasserIn] Xiaoping Zhang [verfasserIn] Jiequn Liu [verfasserIn] Yulei Sui [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	lithium-ion batteries cathode material LiVPO4F Li3V2(PO4)3 electrochemical performance

Übergeordnetes Werk:	In: Frontiers in Chemistry - Frontiers Media S.A., 2014, 8(2020)
Übergeordnetes Werk:	volume:8 ; year:2020

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3389/fchem.2020.00361

Katalog-ID:	DOAJ003562794

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520			\|a Cathode materials made of xLiVPO4F·yLi3V2(PO4)3/C (x:y = 1:0, 2:1, 0:1) are synthesized via a feasible sol-gel method for high-performance lithium-ion batteries. The structures, morphology, and electrochemical properties of the composites are thoroughly investigated. The results show that LiVPO4F/C, Li3V2(PO4)3/C, and 2LiVPO4F·Li3V2(PO4)3/C can be synthesized under 750°C without the formation of impurities. Meanwhile, the unique morphology of the 2LiVPO4F·Li3V2(PO4)3/C composite, which is porous, with nanoflakes adhering to the surface, is revealed. This composite integrates the advantages of LiVPO4F and Li3V2(PO4)3. There are four discharge plateaus near 4.2, 4.1, 3.7, and 3.6 V, and the cathode material delivers high capacities of 143.4, 141.6, 133.2, 124.1, and 117.6 mAh g−1 at rates of 0.1, 0.2, 0.5, 1, and 2 C, respectively. More importantly, the discharge capacity can be almost fully recovered when the discharge rate returns to 0.1 C. The study is highly promising for the development of cathode material for LIBs.
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spelling	10.3389/fchem.2020.00361 doi (DE-627)DOAJ003562794 (DE-599)DOAJfccc464199e84e5a9f88ed2a54497f1b DE-627 ger DE-627 rakwb eng QD1-999 Shengkui Zhong verfasserin aut Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Cathode materials made of xLiVPO4F·yLi3V2(PO4)3/C (x:y = 1:0, 2:1, 0:1) are synthesized via a feasible sol-gel method for high-performance lithium-ion batteries. The structures, morphology, and electrochemical properties of the composites are thoroughly investigated. The results show that LiVPO4F/C, Li3V2(PO4)3/C, and 2LiVPO4F·Li3V2(PO4)3/C can be synthesized under 750°C without the formation of impurities. Meanwhile, the unique morphology of the 2LiVPO4F·Li3V2(PO4)3/C composite, which is porous, with nanoflakes adhering to the surface, is revealed. This composite integrates the advantages of LiVPO4F and Li3V2(PO4)3. There are four discharge plateaus near 4.2, 4.1, 3.7, and 3.6 V, and the cathode material delivers high capacities of 143.4, 141.6, 133.2, 124.1, and 117.6 mAh g−1 at rates of 0.1, 0.2, 0.5, 1, and 2 C, respectively. More importantly, the discharge capacity can be almost fully recovered when the discharge rate returns to 0.1 C. The study is highly promising for the development of cathode material for LIBs. lithium-ion batteries cathode material LiVPO4F Li3V2(PO4)3 electrochemical performance Chemistry Xiaoping Zhang verfasserin aut Jiequn Liu verfasserin aut Yulei Sui verfasserin aut In Frontiers in Chemistry Frontiers Media S.A., 2014 8(2020) (DE-627)742224538 (DE-600)2711776-5 22962646 nnns volume:8 year:2020 https://doi.org/10.3389/fchem.2020.00361 kostenfrei https://doaj.org/article/fccc464199e84e5a9f88ed2a54497f1b kostenfrei https://www.frontiersin.org/article/10.3389/fchem.2020.00361/full kostenfrei https://doaj.org/toc/2296-2646 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2020
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callnumber-first	Q - Science
author	Shengkui Zhong
spellingShingle	Shengkui Zhong misc QD1-999 misc lithium-ion batteries misc cathode material misc LiVPO4F misc Li3V2(PO4)3 misc electrochemical performance misc Chemistry Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries
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topic_title	QD1-999 Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries lithium-ion batteries cathode material LiVPO4F Li3V2(PO4)3 electrochemical performance
topic	misc QD1-999 misc lithium-ion batteries misc cathode material misc LiVPO4F misc Li3V2(PO4)3 misc electrochemical performance misc Chemistry
topic_unstemmed	misc QD1-999 misc lithium-ion batteries misc cathode material misc LiVPO4F misc Li3V2(PO4)3 misc electrochemical performance misc Chemistry
topic_browse	misc QD1-999 misc lithium-ion batteries misc cathode material misc LiVPO4F misc Li3V2(PO4)3 misc electrochemical performance misc Chemistry
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title	Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries
ctrlnum	(DE-627)DOAJ003562794 (DE-599)DOAJfccc464199e84e5a9f88ed2a54497f1b
title_full	Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries
author_sort	Shengkui Zhong
journal	Frontiers in Chemistry
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author_browse	Shengkui Zhong Xiaoping Zhang Jiequn Liu Yulei Sui
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author-letter	Shengkui Zhong
doi_str_mv	10.3389/fchem.2020.00361
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title_sort	study on xlivpo4f·yli3v2(po4)3/c composite for high-performance cathode material for lithium-ion batteries
callnumber	QD1-999
title_auth	Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries
abstract	Cathode materials made of xLiVPO4F·yLi3V2(PO4)3/C (x:y = 1:0, 2:1, 0:1) are synthesized via a feasible sol-gel method for high-performance lithium-ion batteries. The structures, morphology, and electrochemical properties of the composites are thoroughly investigated. The results show that LiVPO4F/C, Li3V2(PO4)3/C, and 2LiVPO4F·Li3V2(PO4)3/C can be synthesized under 750°C without the formation of impurities. Meanwhile, the unique morphology of the 2LiVPO4F·Li3V2(PO4)3/C composite, which is porous, with nanoflakes adhering to the surface, is revealed. This composite integrates the advantages of LiVPO4F and Li3V2(PO4)3. There are four discharge plateaus near 4.2, 4.1, 3.7, and 3.6 V, and the cathode material delivers high capacities of 143.4, 141.6, 133.2, 124.1, and 117.6 mAh g−1 at rates of 0.1, 0.2, 0.5, 1, and 2 C, respectively. More importantly, the discharge capacity can be almost fully recovered when the discharge rate returns to 0.1 C. The study is highly promising for the development of cathode material for LIBs.
abstractGer	Cathode materials made of xLiVPO4F·yLi3V2(PO4)3/C (x:y = 1:0, 2:1, 0:1) are synthesized via a feasible sol-gel method for high-performance lithium-ion batteries. The structures, morphology, and electrochemical properties of the composites are thoroughly investigated. The results show that LiVPO4F/C, Li3V2(PO4)3/C, and 2LiVPO4F·Li3V2(PO4)3/C can be synthesized under 750°C without the formation of impurities. Meanwhile, the unique morphology of the 2LiVPO4F·Li3V2(PO4)3/C composite, which is porous, with nanoflakes adhering to the surface, is revealed. This composite integrates the advantages of LiVPO4F and Li3V2(PO4)3. There are four discharge plateaus near 4.2, 4.1, 3.7, and 3.6 V, and the cathode material delivers high capacities of 143.4, 141.6, 133.2, 124.1, and 117.6 mAh g−1 at rates of 0.1, 0.2, 0.5, 1, and 2 C, respectively. More importantly, the discharge capacity can be almost fully recovered when the discharge rate returns to 0.1 C. The study is highly promising for the development of cathode material for LIBs.
abstract_unstemmed	Cathode materials made of xLiVPO4F·yLi3V2(PO4)3/C (x:y = 1:0, 2:1, 0:1) are synthesized via a feasible sol-gel method for high-performance lithium-ion batteries. The structures, morphology, and electrochemical properties of the composites are thoroughly investigated. The results show that LiVPO4F/C, Li3V2(PO4)3/C, and 2LiVPO4F·Li3V2(PO4)3/C can be synthesized under 750°C without the formation of impurities. Meanwhile, the unique morphology of the 2LiVPO4F·Li3V2(PO4)3/C composite, which is porous, with nanoflakes adhering to the surface, is revealed. This composite integrates the advantages of LiVPO4F and Li3V2(PO4)3. There are four discharge plateaus near 4.2, 4.1, 3.7, and 3.6 V, and the cathode material delivers high capacities of 143.4, 141.6, 133.2, 124.1, and 117.6 mAh g−1 at rates of 0.1, 0.2, 0.5, 1, and 2 C, respectively. More importantly, the discharge capacity can be almost fully recovered when the discharge rate returns to 0.1 C. The study is highly promising for the development of cathode material for LIBs.
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title_short	Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries
url	https://doi.org/10.3389/fchem.2020.00361 https://doaj.org/article/fccc464199e84e5a9f88ed2a54497f1b https://www.frontiersin.org/article/10.3389/fchem.2020.00361/full https://doaj.org/toc/2296-2646
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author2	Xiaoping Zhang Jiequn Liu Yulei Sui
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up_date	2024-07-03T18:44:35.085Z
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Study on xLiVPO4F·yLi3V2(PO4)3/C Composite for High-Performance Cathode Material for Lithium-Ion Batteries

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