Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules
The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic...
Ausführliche Beschreibung
Autor*in: |
Yi Cui [verfasserIn] Shuyi Gao [verfasserIn] Ruiyun Zhang [verfasserIn] Longdi Cheng [verfasserIn] Jianyong Yu [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2020 |
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Übergeordnetes Werk: |
In: Polymers - MDPI AG, 2011, 12(2020), 1, p 98 |
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Übergeordnetes Werk: |
volume:12 ; year:2020 ; number:1, p 98 |
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DOI / URN: |
10.3390/polym12010098 |
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Katalog-ID: |
DOAJ004214293 |
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520 | |a The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. | ||
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10.3390/polym12010098 doi (DE-627)DOAJ004214293 (DE-599)DOAJ83aa1c35380a4bb992565468c193ac02 DE-627 ger DE-627 rakwb eng QD241-441 Yi Cui verfasserin aut Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. hygroscopic exothermic fiber gab model moisture content the net isosteric heats of sorption simultaneous thermal analysis Organic chemistry Shuyi Gao verfasserin aut Ruiyun Zhang verfasserin aut Longdi Cheng verfasserin aut Jianyong Yu verfasserin aut In Polymers MDPI AG, 2011 12(2020), 1, p 98 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:12 year:2020 number:1, p 98 https://doi.org/10.3390/polym12010098 kostenfrei https://doaj.org/article/83aa1c35380a4bb992565468c193ac02 kostenfrei https://www.mdpi.com/2073-4360/12/1/98 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1, p 98 |
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10.3390/polym12010098 doi (DE-627)DOAJ004214293 (DE-599)DOAJ83aa1c35380a4bb992565468c193ac02 DE-627 ger DE-627 rakwb eng QD241-441 Yi Cui verfasserin aut Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. hygroscopic exothermic fiber gab model moisture content the net isosteric heats of sorption simultaneous thermal analysis Organic chemistry Shuyi Gao verfasserin aut Ruiyun Zhang verfasserin aut Longdi Cheng verfasserin aut Jianyong Yu verfasserin aut In Polymers MDPI AG, 2011 12(2020), 1, p 98 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:12 year:2020 number:1, p 98 https://doi.org/10.3390/polym12010098 kostenfrei https://doaj.org/article/83aa1c35380a4bb992565468c193ac02 kostenfrei https://www.mdpi.com/2073-4360/12/1/98 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1, p 98 |
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10.3390/polym12010098 doi (DE-627)DOAJ004214293 (DE-599)DOAJ83aa1c35380a4bb992565468c193ac02 DE-627 ger DE-627 rakwb eng QD241-441 Yi Cui verfasserin aut Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. hygroscopic exothermic fiber gab model moisture content the net isosteric heats of sorption simultaneous thermal analysis Organic chemistry Shuyi Gao verfasserin aut Ruiyun Zhang verfasserin aut Longdi Cheng verfasserin aut Jianyong Yu verfasserin aut In Polymers MDPI AG, 2011 12(2020), 1, p 98 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:12 year:2020 number:1, p 98 https://doi.org/10.3390/polym12010098 kostenfrei https://doaj.org/article/83aa1c35380a4bb992565468c193ac02 kostenfrei https://www.mdpi.com/2073-4360/12/1/98 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1, p 98 |
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10.3390/polym12010098 doi (DE-627)DOAJ004214293 (DE-599)DOAJ83aa1c35380a4bb992565468c193ac02 DE-627 ger DE-627 rakwb eng QD241-441 Yi Cui verfasserin aut Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. hygroscopic exothermic fiber gab model moisture content the net isosteric heats of sorption simultaneous thermal analysis Organic chemistry Shuyi Gao verfasserin aut Ruiyun Zhang verfasserin aut Longdi Cheng verfasserin aut Jianyong Yu verfasserin aut In Polymers MDPI AG, 2011 12(2020), 1, p 98 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:12 year:2020 number:1, p 98 https://doi.org/10.3390/polym12010098 kostenfrei https://doaj.org/article/83aa1c35380a4bb992565468c193ac02 kostenfrei https://www.mdpi.com/2073-4360/12/1/98 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1, p 98 |
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10.3390/polym12010098 doi (DE-627)DOAJ004214293 (DE-599)DOAJ83aa1c35380a4bb992565468c193ac02 DE-627 ger DE-627 rakwb eng QD241-441 Yi Cui verfasserin aut Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. hygroscopic exothermic fiber gab model moisture content the net isosteric heats of sorption simultaneous thermal analysis Organic chemistry Shuyi Gao verfasserin aut Ruiyun Zhang verfasserin aut Longdi Cheng verfasserin aut Jianyong Yu verfasserin aut In Polymers MDPI AG, 2011 12(2020), 1, p 98 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:12 year:2020 number:1, p 98 https://doi.org/10.3390/polym12010098 kostenfrei https://doaj.org/article/83aa1c35380a4bb992565468c193ac02 kostenfrei https://www.mdpi.com/2073-4360/12/1/98 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2020 1, p 98 |
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QD241-441 Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules hygroscopic exothermic fiber gab model moisture content the net isosteric heats of sorption simultaneous thermal analysis |
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Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules |
abstract |
The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. |
abstractGer |
The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. |
abstract_unstemmed |
The aim of this paper is to study the hygroscopic behavior of hygroscopic exothermic fiber-based materials and to obtain a better understanding of the thermal performance of these fibers during the moisture absorption process. The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. This was further proven by the heat of desorption. |
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Study on the Moisture Absorption and Thermal Properties of Hygroscopic Exothermic Fibers and Related Interactions with Water Molecules |
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The temperature distribution of different kinds of hygroscopic exothermic fibers in the process of moisture absorption, observed by infrared camera, demonstrated two types of heating performance of these fibers, which might be related to its hygroscopic behavior. Based on the sorption isotherms, a Guggenheim-Anderson-de Boer (GAB) multi-layer adsorption model was selected as the optimal moisture absorption fitting model to describe the moisture absorption process of these fibers, which illustrated that water sorption capacity and the water−fiber/water−water interaction had a significant influence on its heating performance. The net isosteric heats of sorption decreased with an increase of moisture content, which further explained the main factor affecting the heat dissipation of fibers under different moisture contents. The state of adsorbed water and water vapor interaction on the fiber surface were studied by simultaneous thermal analysis (TGA-DSC) measurement. The percentage of bound and unbound water formation at low and high humidity had a profound effect on the thermal performance of fibers. It can therefore be concluded that the content of tightly bound water a strong water−fiber interaction was the main factor affecting the heating performance of fibers at low moisture content, and the content of loosely bound water reflected that water sorption capacity was the main factor affecting the heating performance of fibers at high moisture content. 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