Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor

Ceramic matrix composite (CMC) materials have been considered a desired solution for lightweight and high-temperature applications. Simultaneously, among all different CMC reinforcements, polymer-derived ceramic (PDC) fibres have gained attention for the intrinsic thermal stability and mechanical st...
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Autor*in:	Zhongkan Ren [verfasserIn] Christel Gervais [verfasserIn] Gurpreet Singh [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	polymer-derived ceramic fibres ceramic matrix composite ceramics polymers

Übergeordnetes Werk:	In: Royal Society Open Science - The Royal Society, 2015, 6(2019), 10
Übergeordnetes Werk:	volume:6 ; year:2019 ; number:10

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1098/rsos.190690

Katalog-ID:	DOAJ006828493

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spelling	10.1098/rsos.190690 doi (DE-627)DOAJ006828493 (DE-599)DOAJ74d676c040e2482ab951376e01bf1a34 DE-627 ger DE-627 rakwb eng Zhongkan Ren verfasserin aut Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ceramic matrix composite (CMC) materials have been considered a desired solution for lightweight and high-temperature applications. Simultaneously, among all different CMC reinforcements, polymer-derived ceramic (PDC) fibres have gained attention for the intrinsic thermal stability and mechanical strength with simple and cost-effective synthesis techniques. Here, carbon-rich SiOCN fibres were synthesized via hand-drawing and polymer pyrolysis of a hybrid precursor of 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasilazane (TTCSZ) and poly-acrylic acid (PAA). The type of silazane reported in this work is considered as a major precursor for SiCN; however, it is unspinnable, due to its unfavourable physical properties (low viscosity) and chemical structure (cyclic rather than linear structure). The introduction of PAA to TTCSZ to create a hybrid precursor remarkably improved the spinnability of the silazane and should be widely applicable to other unspinnable PDC pre-ceramic polymers. Investigations on the structural and compositional development of the fibres were mainly conducted via Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, nuclear magnetic resonance and thermo-gravimetric analysis to determine spinnability, free carbon content, cross-linking and pyrolysis behaviour of the fibres, respectively. polymer-derived ceramic fibres ceramic matrix composite ceramics polymers Science Q Christel Gervais verfasserin aut Gurpreet Singh verfasserin aut In Royal Society Open Science The Royal Society, 2015 6(2019), 10 (DE-627)798561173 (DE-600)2787755-3 20545703 nnns volume:6 year:2019 number:10 https://doi.org/10.1098/rsos.190690 kostenfrei https://doaj.org/article/74d676c040e2482ab951376e01bf1a34 kostenfrei https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.190690 kostenfrei https://doaj.org/toc/2054-5703 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2005 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2019 10
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authorswithroles_txt_mv	Zhongkan Ren @@aut@@ Christel Gervais @@aut@@ Gurpreet Singh @@aut@@
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author	Zhongkan Ren
spellingShingle	Zhongkan Ren misc polymer-derived ceramic misc fibres misc ceramic matrix composite misc ceramics misc polymers misc Science misc Q Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor
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topic_title	Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor polymer-derived ceramic fibres ceramic matrix composite ceramics polymers
topic	misc polymer-derived ceramic misc fibres misc ceramic matrix composite misc ceramics misc polymers misc Science misc Q
topic_unstemmed	misc polymer-derived ceramic misc fibres misc ceramic matrix composite misc ceramics misc polymers misc Science misc Q
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title	Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor
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title_full	Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor
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title_sort	preparation and structure of siocn fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor
title_auth	Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor
abstract	Ceramic matrix composite (CMC) materials have been considered a desired solution for lightweight and high-temperature applications. Simultaneously, among all different CMC reinforcements, polymer-derived ceramic (PDC) fibres have gained attention for the intrinsic thermal stability and mechanical strength with simple and cost-effective synthesis techniques. Here, carbon-rich SiOCN fibres were synthesized via hand-drawing and polymer pyrolysis of a hybrid precursor of 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasilazane (TTCSZ) and poly-acrylic acid (PAA). The type of silazane reported in this work is considered as a major precursor for SiCN; however, it is unspinnable, due to its unfavourable physical properties (low viscosity) and chemical structure (cyclic rather than linear structure). The introduction of PAA to TTCSZ to create a hybrid precursor remarkably improved the spinnability of the silazane and should be widely applicable to other unspinnable PDC pre-ceramic polymers. Investigations on the structural and compositional development of the fibres were mainly conducted via Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, nuclear magnetic resonance and thermo-gravimetric analysis to determine spinnability, free carbon content, cross-linking and pyrolysis behaviour of the fibres, respectively.
abstractGer	Ceramic matrix composite (CMC) materials have been considered a desired solution for lightweight and high-temperature applications. Simultaneously, among all different CMC reinforcements, polymer-derived ceramic (PDC) fibres have gained attention for the intrinsic thermal stability and mechanical strength with simple and cost-effective synthesis techniques. Here, carbon-rich SiOCN fibres were synthesized via hand-drawing and polymer pyrolysis of a hybrid precursor of 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasilazane (TTCSZ) and poly-acrylic acid (PAA). The type of silazane reported in this work is considered as a major precursor for SiCN; however, it is unspinnable, due to its unfavourable physical properties (low viscosity) and chemical structure (cyclic rather than linear structure). The introduction of PAA to TTCSZ to create a hybrid precursor remarkably improved the spinnability of the silazane and should be widely applicable to other unspinnable PDC pre-ceramic polymers. Investigations on the structural and compositional development of the fibres were mainly conducted via Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, nuclear magnetic resonance and thermo-gravimetric analysis to determine spinnability, free carbon content, cross-linking and pyrolysis behaviour of the fibres, respectively.
abstract_unstemmed	Ceramic matrix composite (CMC) materials have been considered a desired solution for lightweight and high-temperature applications. Simultaneously, among all different CMC reinforcements, polymer-derived ceramic (PDC) fibres have gained attention for the intrinsic thermal stability and mechanical strength with simple and cost-effective synthesis techniques. Here, carbon-rich SiOCN fibres were synthesized via hand-drawing and polymer pyrolysis of a hybrid precursor of 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasilazane (TTCSZ) and poly-acrylic acid (PAA). The type of silazane reported in this work is considered as a major precursor for SiCN; however, it is unspinnable, due to its unfavourable physical properties (low viscosity) and chemical structure (cyclic rather than linear structure). The introduction of PAA to TTCSZ to create a hybrid precursor remarkably improved the spinnability of the silazane and should be widely applicable to other unspinnable PDC pre-ceramic polymers. Investigations on the structural and compositional development of the fibres were mainly conducted via Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, nuclear magnetic resonance and thermo-gravimetric analysis to determine spinnability, free carbon content, cross-linking and pyrolysis behaviour of the fibres, respectively.
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title_short	Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor
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Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor

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