Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel

Recently, catalysts based on transition metal phosphides (TMPs) have attracted increasing interest for their use in hydrodeoxygenation (HDO) processes destined to synthesize biofuels (green or renewable diesel) from waste vegetable oils and fats (known as hydrotreated vegetable oils (HVO)), or from...
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Autor*in:	M. Consuelo Alvarez-Galvan [verfasserIn] Jose M. Campos-Martin [verfasserIn] Jose L. G. Fierro [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	transition metal phosphides (TMPs) hydrodeoxygenation (HDO) hydrotreated vegetable oils (HVO)

Übergeordnetes Werk:	In: Catalysts - MDPI AG, 2012, 9(2019), 3, p 293
Übergeordnetes Werk:	volume:9 ; year:2019 ; number:3, p 293

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/catal9030293

Katalog-ID:	DOAJ00715058X

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callnumber-first	T - Technology
author	M. Consuelo Alvarez-Galvan
spellingShingle	M. Consuelo Alvarez-Galvan misc TP1-1185 misc QD1-999 misc transition metal phosphides (TMPs) misc hydrodeoxygenation (HDO) misc hydrotreated vegetable oils (HVO) misc Chemical technology misc Chemistry Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel
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topic_title	TP1-1185 QD1-999 Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel transition metal phosphides (TMPs) hydrodeoxygenation (HDO) hydrotreated vegetable oils (HVO)
topic	misc TP1-1185 misc QD1-999 misc transition metal phosphides (TMPs) misc hydrodeoxygenation (HDO) misc hydrotreated vegetable oils (HVO) misc Chemical technology misc Chemistry
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title	Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel
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title_full	Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel
author_sort	M. Consuelo Alvarez-Galvan
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title_sort	transition metal phosphides for the catalytic hydrodeoxygenation of waste oils into green diesel
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title_auth	Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel
abstract	Recently, catalysts based on transition metal phosphides (TMPs) have attracted increasing interest for their use in hydrodeoxygenation (HDO) processes destined to synthesize biofuels (green or renewable diesel) from waste vegetable oils and fats (known as hydrotreated vegetable oils (HVO)), or from bio-oils. This fossil-free diesel product is produced completely from renewable raw materials with exceptional quality. These efficient HDO catalysts present electronic properties similar to noble metals, are cost-efficient, and are more stable and resistant to the presence of water than other classical catalytic formulations used for hydrotreatment reactions based on transition metal sulfides, but they do not require the continuous supply of a sulfide source. TMPs develop a bifunctional character (metallic and acidic) and present tunable catalytic properties related to the metal type, phosphorous-metal ratio, support nature, texture properties, and so on. Here, the recent progress in TMP-based catalysts for HDO of waste oils is reviewed. First, the use of TMPs in catalysis is addressed; then, the general aspects of green diesel (from bio-oils or from waste vegetable oils and fats) production by HDO of nonedible oil compounds are presented; and, finally, we attempt to describe the main advances in the development of catalysts based on TMPs for HDO, with an emphasis on the influence of the nature of active phases and effects of phosphorous, promoters, and preparation methods on reactivity.
abstractGer	Recently, catalysts based on transition metal phosphides (TMPs) have attracted increasing interest for their use in hydrodeoxygenation (HDO) processes destined to synthesize biofuels (green or renewable diesel) from waste vegetable oils and fats (known as hydrotreated vegetable oils (HVO)), or from bio-oils. This fossil-free diesel product is produced completely from renewable raw materials with exceptional quality. These efficient HDO catalysts present electronic properties similar to noble metals, are cost-efficient, and are more stable and resistant to the presence of water than other classical catalytic formulations used for hydrotreatment reactions based on transition metal sulfides, but they do not require the continuous supply of a sulfide source. TMPs develop a bifunctional character (metallic and acidic) and present tunable catalytic properties related to the metal type, phosphorous-metal ratio, support nature, texture properties, and so on. Here, the recent progress in TMP-based catalysts for HDO of waste oils is reviewed. First, the use of TMPs in catalysis is addressed; then, the general aspects of green diesel (from bio-oils or from waste vegetable oils and fats) production by HDO of nonedible oil compounds are presented; and, finally, we attempt to describe the main advances in the development of catalysts based on TMPs for HDO, with an emphasis on the influence of the nature of active phases and effects of phosphorous, promoters, and preparation methods on reactivity.
abstract_unstemmed	Recently, catalysts based on transition metal phosphides (TMPs) have attracted increasing interest for their use in hydrodeoxygenation (HDO) processes destined to synthesize biofuels (green or renewable diesel) from waste vegetable oils and fats (known as hydrotreated vegetable oils (HVO)), or from bio-oils. This fossil-free diesel product is produced completely from renewable raw materials with exceptional quality. These efficient HDO catalysts present electronic properties similar to noble metals, are cost-efficient, and are more stable and resistant to the presence of water than other classical catalytic formulations used for hydrotreatment reactions based on transition metal sulfides, but they do not require the continuous supply of a sulfide source. TMPs develop a bifunctional character (metallic and acidic) and present tunable catalytic properties related to the metal type, phosphorous-metal ratio, support nature, texture properties, and so on. Here, the recent progress in TMP-based catalysts for HDO of waste oils is reviewed. First, the use of TMPs in catalysis is addressed; then, the general aspects of green diesel (from bio-oils or from waste vegetable oils and fats) production by HDO of nonedible oil compounds are presented; and, finally, we attempt to describe the main advances in the development of catalysts based on TMPs for HDO, with an emphasis on the influence of the nature of active phases and effects of phosphorous, promoters, and preparation methods on reactivity.
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title_short	Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel
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Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel

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