Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization

Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this momen...
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Autor*in:	Stanislaw Penczek [verfasserIn] Julia Pretula [verfasserIn] Piotr Lewiński [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2017

Schlagwörter:	dormant polymers living polymerization controlled polymerization ring-opening polymerization

Übergeordnetes Werk:	In: Polymers - MDPI AG, 2011, 9(2017), 12, p 646
Übergeordnetes Werk:	volume:9 ; year:2017 ; number:12, p 646

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/polym9120646

Katalog-ID:	DOAJ00773395X

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language	English
source	In Polymers 9(2017), 12, p 646 volume:9 year:2017 number:12, p 646
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topic_facet	dormant polymers living polymerization controlled polymerization ring-opening polymerization Organic chemistry
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authorswithroles_txt_mv	Stanislaw Penczek @@aut@@ Julia Pretula @@aut@@ Piotr Lewiński @@aut@@
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callnumber-first	Q - Science
author	Stanislaw Penczek
spellingShingle	Stanislaw Penczek misc QD241-441 misc dormant polymers misc living polymerization misc controlled polymerization misc ring-opening polymerization misc Organic chemistry Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization
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topic_title	QD241-441 Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization dormant polymers living polymerization controlled polymerization ring-opening polymerization
topic	misc QD241-441 misc dormant polymers misc living polymerization misc controlled polymerization misc ring-opening polymerization misc Organic chemistry
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title	Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization
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title_full	Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization
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title_sort	dormant polymers and their role in living and controlled polymerizations; influence on polymer chemistry, particularly on the ring opening polymerization
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title_auth	Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization
abstract	Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this moment and becoming active in the process of activation. These processes are at least equally important although less known. This mini review is devoted to these particular living polymerizations, mostly polymerizations by the Ring-Opening Polymerization mechanisms (ROP) compared with some selected close to living vinyl polymerizations (the most spectacular is Atom Transfer Radical Polymerization (ATRP)) involving dormancy. Cationic polymerization of tetrahydrofuran was the first one, based on equilibrium between oxonium ions (active) and covalent (esters) dormant species, i.e., temporarily inactive, and is described in detail. The other systems discussed are polymerization of oxazolines and cyclic esters as well as controlled radical and cationic polymerizations of vinyl monomers.
abstractGer	Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this moment and becoming active in the process of activation. These processes are at least equally important although less known. This mini review is devoted to these particular living polymerizations, mostly polymerizations by the Ring-Opening Polymerization mechanisms (ROP) compared with some selected close to living vinyl polymerizations (the most spectacular is Atom Transfer Radical Polymerization (ATRP)) involving dormancy. Cationic polymerization of tetrahydrofuran was the first one, based on equilibrium between oxonium ions (active) and covalent (esters) dormant species, i.e., temporarily inactive, and is described in detail. The other systems discussed are polymerization of oxazolines and cyclic esters as well as controlled radical and cationic polymerizations of vinyl monomers.
abstract_unstemmed	Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this moment and becoming active in the process of activation. These processes are at least equally important although less known. This mini review is devoted to these particular living polymerizations, mostly polymerizations by the Ring-Opening Polymerization mechanisms (ROP) compared with some selected close to living vinyl polymerizations (the most spectacular is Atom Transfer Radical Polymerization (ATRP)) involving dormancy. Cationic polymerization of tetrahydrofuran was the first one, based on equilibrium between oxonium ions (active) and covalent (esters) dormant species, i.e., temporarily inactive, and is described in detail. The other systems discussed are polymerization of oxazolines and cyclic esters as well as controlled radical and cationic polymerizations of vinyl monomers.
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title_short	Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization
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Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization

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