Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization
Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this momen...
Ausführliche Beschreibung
Autor*in: |
Stanislaw Penczek [verfasserIn] Julia Pretula [verfasserIn] Piotr Lewiński [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2017 |
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Übergeordnetes Werk: |
In: Polymers - MDPI AG, 2011, 9(2017), 12, p 646 |
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Übergeordnetes Werk: |
volume:9 ; year:2017 ; number:12, p 646 |
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DOI / URN: |
10.3390/polym9120646 |
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Katalog-ID: |
DOAJ00773395X |
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10.3390/polym9120646 doi (DE-627)DOAJ00773395X (DE-599)DOAJ85923259ac7e4e80a140ae7b9e977121 DE-627 ger DE-627 rakwb eng QD241-441 Stanislaw Penczek verfasserin aut Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this moment and becoming active in the process of activation. These processes are at least equally important although less known. This mini review is devoted to these particular living polymerizations, mostly polymerizations by the Ring-Opening Polymerization mechanisms (ROP) compared with some selected close to living vinyl polymerizations (the most spectacular is Atom Transfer Radical Polymerization (ATRP)) involving dormancy. Cationic polymerization of tetrahydrofuran was the first one, based on equilibrium between oxonium ions (active) and covalent (esters) dormant species, i.e., temporarily inactive, and is described in detail. The other systems discussed are polymerization of oxazolines and cyclic esters as well as controlled radical and cationic polymerizations of vinyl monomers. dormant polymers living polymerization controlled polymerization ring-opening polymerization Organic chemistry Julia Pretula verfasserin aut Piotr Lewiński verfasserin aut In Polymers MDPI AG, 2011 9(2017), 12, p 646 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:9 year:2017 number:12, p 646 https://doi.org/10.3390/polym9120646 kostenfrei https://doaj.org/article/85923259ac7e4e80a140ae7b9e977121 kostenfrei https://www.mdpi.com/2073-4360/9/12/646 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2017 12, p 646 |
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Dormant Polymers and Their Role in Living and Controlled Polymerizations; Influence on Polymer Chemistry, Particularly on the Ring Opening Polymerization |
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Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this moment and becoming active in the process of activation. These processes are at least equally important although less known. This mini review is devoted to these particular living polymerizations, mostly polymerizations by the Ring-Opening Polymerization mechanisms (ROP) compared with some selected close to living vinyl polymerizations (the most spectacular is Atom Transfer Radical Polymerization (ATRP)) involving dormancy. Cationic polymerization of tetrahydrofuran was the first one, based on equilibrium between oxonium ions (active) and covalent (esters) dormant species, i.e., temporarily inactive, and is described in detail. The other systems discussed are polymerization of oxazolines and cyclic esters as well as controlled radical and cationic polymerizations of vinyl monomers. |
abstractGer |
Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this moment and becoming active in the process of activation. These processes are at least equally important although less known. This mini review is devoted to these particular living polymerizations, mostly polymerizations by the Ring-Opening Polymerization mechanisms (ROP) compared with some selected close to living vinyl polymerizations (the most spectacular is Atom Transfer Radical Polymerization (ATRP)) involving dormancy. Cationic polymerization of tetrahydrofuran was the first one, based on equilibrium between oxonium ions (active) and covalent (esters) dormant species, i.e., temporarily inactive, and is described in detail. The other systems discussed are polymerization of oxazolines and cyclic esters as well as controlled radical and cationic polymerizations of vinyl monomers. |
abstract_unstemmed |
Living polymerization discovered by Professor Szwarc is known well to all chemists. Some of the living polymerizations involve dormancy, a process in which there is an equilibrium (or at least exchange) between two types of living polymers, namely active at the given moment and dormant at this moment and becoming active in the process of activation. These processes are at least equally important although less known. This mini review is devoted to these particular living polymerizations, mostly polymerizations by the Ring-Opening Polymerization mechanisms (ROP) compared with some selected close to living vinyl polymerizations (the most spectacular is Atom Transfer Radical Polymerization (ATRP)) involving dormancy. Cationic polymerization of tetrahydrofuran was the first one, based on equilibrium between oxonium ions (active) and covalent (esters) dormant species, i.e., temporarily inactive, and is described in detail. The other systems discussed are polymerization of oxazolines and cyclic esters as well as controlled radical and cationic polymerizations of vinyl monomers. |
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