Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD
2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be consider...
Ausführliche Beschreibung
Autor*in: |
Abdollah Dargahi [verfasserIn] Mehdi Vosoughi [verfasserIn] S. Ahmad Mokhtari [verfasserIn] Yaser Vaziri [verfasserIn] Mortaza Alighadri [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Schlagwörter: |
Three-dimensional electrocatalytic reactor (3DER) |
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Übergeordnetes Werk: |
In: Arabian Journal of Chemistry - Elsevier, 2016, 15(2022), 3, Seite 103648- |
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Übergeordnetes Werk: |
volume:15 ; year:2022 ; number:3 ; pages:103648- |
Links: |
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DOI / URN: |
10.1016/j.arabjc.2021.103648 |
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Katalog-ID: |
DOAJ008235708 |
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245 | 1 | 0 | |a Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD |
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520 | |a 2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. | ||
650 | 4 | |a 2,4-Dinitrotoluene (DNT) | |
650 | 4 | |a Three-dimensional electrocatalytic reactor (3DER) | |
650 | 4 | |a GAC and MCZ@Fe3O4 nanoparticles | |
650 | 4 | |a Evaluation of toxicity | |
650 | 4 | |a G/β-PbO2 anode | |
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653 | 0 | |a Chemistry | |
700 | 0 | |a Mehdi Vosoughi |e verfasserin |4 aut | |
700 | 0 | |a S. Ahmad Mokhtari |e verfasserin |4 aut | |
700 | 0 | |a Yaser Vaziri |e verfasserin |4 aut | |
700 | 0 | |a Mortaza Alighadri |e verfasserin |4 aut | |
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10.1016/j.arabjc.2021.103648 doi (DE-627)DOAJ008235708 (DE-599)DOAJa015d0bc0d124d019bb4a19122a651a3 DE-627 ger DE-627 rakwb eng QD1-999 Abdollah Dargahi verfasserin aut Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. 2,4-Dinitrotoluene (DNT) Three-dimensional electrocatalytic reactor (3DER) GAC and MCZ@Fe3O4 nanoparticles Evaluation of toxicity G/β-PbO2 anode RSM-CCD Chemistry Mehdi Vosoughi verfasserin aut S. Ahmad Mokhtari verfasserin aut Yaser Vaziri verfasserin aut Mortaza Alighadri verfasserin aut In Arabian Journal of Chemistry Elsevier, 2016 15(2022), 3, Seite 103648- (DE-627)609401564 (DE-600)2515214-2 18785352 nnns volume:15 year:2022 number:3 pages:103648- https://doi.org/10.1016/j.arabjc.2021.103648 kostenfrei https://doaj.org/article/a015d0bc0d124d019bb4a19122a651a3 kostenfrei http://www.sciencedirect.com/science/article/pii/S1878535221006638 kostenfrei https://doaj.org/toc/1878-5352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 3 103648- |
spelling |
10.1016/j.arabjc.2021.103648 doi (DE-627)DOAJ008235708 (DE-599)DOAJa015d0bc0d124d019bb4a19122a651a3 DE-627 ger DE-627 rakwb eng QD1-999 Abdollah Dargahi verfasserin aut Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. 2,4-Dinitrotoluene (DNT) Three-dimensional electrocatalytic reactor (3DER) GAC and MCZ@Fe3O4 nanoparticles Evaluation of toxicity G/β-PbO2 anode RSM-CCD Chemistry Mehdi Vosoughi verfasserin aut S. Ahmad Mokhtari verfasserin aut Yaser Vaziri verfasserin aut Mortaza Alighadri verfasserin aut In Arabian Journal of Chemistry Elsevier, 2016 15(2022), 3, Seite 103648- (DE-627)609401564 (DE-600)2515214-2 18785352 nnns volume:15 year:2022 number:3 pages:103648- https://doi.org/10.1016/j.arabjc.2021.103648 kostenfrei https://doaj.org/article/a015d0bc0d124d019bb4a19122a651a3 kostenfrei http://www.sciencedirect.com/science/article/pii/S1878535221006638 kostenfrei https://doaj.org/toc/1878-5352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 3 103648- |
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10.1016/j.arabjc.2021.103648 doi (DE-627)DOAJ008235708 (DE-599)DOAJa015d0bc0d124d019bb4a19122a651a3 DE-627 ger DE-627 rakwb eng QD1-999 Abdollah Dargahi verfasserin aut Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. 2,4-Dinitrotoluene (DNT) Three-dimensional electrocatalytic reactor (3DER) GAC and MCZ@Fe3O4 nanoparticles Evaluation of toxicity G/β-PbO2 anode RSM-CCD Chemistry Mehdi Vosoughi verfasserin aut S. Ahmad Mokhtari verfasserin aut Yaser Vaziri verfasserin aut Mortaza Alighadri verfasserin aut In Arabian Journal of Chemistry Elsevier, 2016 15(2022), 3, Seite 103648- (DE-627)609401564 (DE-600)2515214-2 18785352 nnns volume:15 year:2022 number:3 pages:103648- https://doi.org/10.1016/j.arabjc.2021.103648 kostenfrei https://doaj.org/article/a015d0bc0d124d019bb4a19122a651a3 kostenfrei http://www.sciencedirect.com/science/article/pii/S1878535221006638 kostenfrei https://doaj.org/toc/1878-5352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 3 103648- |
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10.1016/j.arabjc.2021.103648 doi (DE-627)DOAJ008235708 (DE-599)DOAJa015d0bc0d124d019bb4a19122a651a3 DE-627 ger DE-627 rakwb eng QD1-999 Abdollah Dargahi verfasserin aut Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. 2,4-Dinitrotoluene (DNT) Three-dimensional electrocatalytic reactor (3DER) GAC and MCZ@Fe3O4 nanoparticles Evaluation of toxicity G/β-PbO2 anode RSM-CCD Chemistry Mehdi Vosoughi verfasserin aut S. Ahmad Mokhtari verfasserin aut Yaser Vaziri verfasserin aut Mortaza Alighadri verfasserin aut In Arabian Journal of Chemistry Elsevier, 2016 15(2022), 3, Seite 103648- (DE-627)609401564 (DE-600)2515214-2 18785352 nnns volume:15 year:2022 number:3 pages:103648- https://doi.org/10.1016/j.arabjc.2021.103648 kostenfrei https://doaj.org/article/a015d0bc0d124d019bb4a19122a651a3 kostenfrei http://www.sciencedirect.com/science/article/pii/S1878535221006638 kostenfrei https://doaj.org/toc/1878-5352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 3 103648- |
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10.1016/j.arabjc.2021.103648 doi (DE-627)DOAJ008235708 (DE-599)DOAJa015d0bc0d124d019bb4a19122a651a3 DE-627 ger DE-627 rakwb eng QD1-999 Abdollah Dargahi verfasserin aut Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier 2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. 2,4-Dinitrotoluene (DNT) Three-dimensional electrocatalytic reactor (3DER) GAC and MCZ@Fe3O4 nanoparticles Evaluation of toxicity G/β-PbO2 anode RSM-CCD Chemistry Mehdi Vosoughi verfasserin aut S. Ahmad Mokhtari verfasserin aut Yaser Vaziri verfasserin aut Mortaza Alighadri verfasserin aut In Arabian Journal of Chemistry Elsevier, 2016 15(2022), 3, Seite 103648- (DE-627)609401564 (DE-600)2515214-2 18785352 nnns volume:15 year:2022 number:3 pages:103648- https://doi.org/10.1016/j.arabjc.2021.103648 kostenfrei https://doaj.org/article/a015d0bc0d124d019bb4a19122a651a3 kostenfrei http://www.sciencedirect.com/science/article/pii/S1878535221006638 kostenfrei https://doaj.org/toc/1878-5352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 15 2022 3 103648- |
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Abdollah Dargahi |
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Abdollah Dargahi misc QD1-999 misc 2,4-Dinitrotoluene (DNT) misc Three-dimensional electrocatalytic reactor (3DER) misc GAC and MCZ@Fe3O4 nanoparticles misc Evaluation of toxicity misc G/β-PbO2 anode misc RSM-CCD misc Chemistry Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD |
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QD1-999 Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD 2,4-Dinitrotoluene (DNT) Three-dimensional electrocatalytic reactor (3DER) GAC and MCZ@Fe3O4 nanoparticles Evaluation of toxicity G/β-PbO2 anode RSM-CCD |
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misc QD1-999 misc 2,4-Dinitrotoluene (DNT) misc Three-dimensional electrocatalytic reactor (3DER) misc GAC and MCZ@Fe3O4 nanoparticles misc Evaluation of toxicity misc G/β-PbO2 anode misc RSM-CCD misc Chemistry |
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Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD |
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Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD |
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Abdollah Dargahi Mehdi Vosoughi S. Ahmad Mokhtari Yaser Vaziri Mortaza Alighadri |
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electrochemical degradation of 2,4-dinitrotoluene (dnt) from aqueous solutions using three-dimensional electrocatalytic reactor (3der): degradation pathway, evaluation of toxicity and optimization using rsm-ccd |
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QD1-999 |
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Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD |
abstract |
2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. |
abstractGer |
2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. |
abstract_unstemmed |
2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater. |
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Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD |
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https://doi.org/10.1016/j.arabjc.2021.103648 https://doaj.org/article/a015d0bc0d124d019bb4a19122a651a3 http://www.sciencedirect.com/science/article/pii/S1878535221006638 https://doaj.org/toc/1878-5352 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">DOAJ008235708</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230502135258.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230225s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.arabjc.2021.103648</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ008235708</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJa015d0bc0d124d019bb4a19122a651a3</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD1-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Abdollah Dargahi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Electrochemical degradation of 2,4-Dinitrotoluene (DNT) from aqueous solutions using three-dimensional electrocatalytic reactor (3DER): Degradation pathway, evaluation of toxicity and optimization using RSM-CCD</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">2,4-Dinitrotoluene (2,4-DNT) has been found to be an important petrochemical compound, which is primarily employed for the synthesis of tolylene diisocyanate and the production of dyes, rubber, and explosives. Since this compound has high toxicity and carcinogenicity, the cautions should be considered when wastewater contaminated with DNTs and their derivatives is released into the environment. Thus, the object of the present study was the investigation of the 2,4-DNT degradation efficiency using the three-dimensional electrocatalytic reactor (3DER) with two different types of particle electrodes (granular activated carbon (GAC) and magnetized clinoptilolite zeolite (MCZ)Fe3O4 nanoparticles)). Preparation of the graphite (G)/β-PbO2 anode was done by electrochemically depositing PbO2 layers on graphite sheets. The prepared graphite sheet and a stainless-steel 316 sheet (with the same dimensions) were employed as the anode and the cathode, respectively. Field emission scanning electron microscopy (FESEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy mapping (EDS-mapping) confirmed the successful preparation of G/β-PbO2 anode. The surface morphology, chemical composition of MCZ@Fe3O4 nanoparticles as a particle electrode were determined by scanning electron microscope (SEM) and XRD pattern. To determine the optimal conditions, we employed the response surface methodology-based central composite design (RSM-CCD) method. According to observed results, higher efficiency of 3DER was obtained by increasing the reaction time and current density and decreasing pH and the pollutant concentration. Studies highlighted the initial 2,4-DNT concentration of 23.5 mg/L, current density 4.8 mA/cm2, pH of 4.1, electrolysis time of 50 min, particle electrodes dose = 6 g/250 cc as optimum values of parameters. The 2,4-DNT degradation efficiencies using GAC and MCZ@Fe3O4 nanoparticles as particle electrodes under mentioned optimal conditions were 98.6% and 96.5%, respectively. Moreover, the chemical oxygen demand (COD) and total organic carbon (TOC) removal efficiencies were 88.5% and 80.9% at the end of 50 min, respectively. Furthermore, results were indicative of an enhancement in average oxidation state (AOS) (from 1.27 to 2.36) and carbon oxidation state (COS) (from 1.27 to 3.68) in the 3DER process and a reduction in the COD/TOC ratio (from 1.81 to 1.09); these signposts the effectiveness of 3DER system for providing the biodegradability of 2,4-DNT. Considering the results, the 3DER could lead to suitable results for the degradation of wastewater containing DNT and resistant contaminants as pretreatment and has remarkable applicability for enhancing the biodegradability of wastewater.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">2,4-Dinitrotoluene (DNT)</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Three-dimensional electrocatalytic reactor (3DER)</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">GAC and MCZ@Fe3O4 nanoparticles</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Evaluation of toxicity</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">G/β-PbO2 anode</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">RSM-CCD</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Chemistry</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Mehdi Vosoughi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">S. 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