Structural Manipulation of the Conjugated Phenyl Moiety in 3-Phenylbenzofulvene Monomers: Effects on Spontaneous Polymerization

Spontaneous polymerization is an intriguing phenomenon in which pure monomers begin their polymerization without initiators or catalysts. Previously, 3-phenylbenzofulvene monomers were found to polymerize spontaneously after solvent removal. Here, eight new 3-substituted benzofulvene monomers 1a&...
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Autor*in:	Marco Paolino [verfasserIn] Giorgio Grisci [verfasserIn] Annalisa Reale [verfasserIn] Vincenzo Razzano [verfasserIn] Germano Giuliani [verfasserIn] Alessandro Donati [verfasserIn] Raniero Mendichi [verfasserIn] Daniele Piovani [verfasserIn] Antonella C. Boccia [verfasserIn] Alessandro Grillo [verfasserIn] Gianluca Giorgi [verfasserIn] Andrea Cappelli [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	spontaneous polymerization affinity polymerization π-conjugated polymer through-space conjugated polymer polybenzofulvene

Übergeordnetes Werk:	In: Polymers - MDPI AG, 2011, 10(2018), 7, p 752
Übergeordnetes Werk:	volume:10 ; year:2018 ; number:7, p 752

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/polym10070752

Katalog-ID:	DOAJ00917611X

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callnumber-first	Q - Science
author	Marco Paolino
spellingShingle	Marco Paolino misc QD241-441 misc spontaneous polymerization misc affinity polymerization misc π-conjugated polymer misc through-space conjugated polymer misc polybenzofulvene misc Organic chemistry Structural Manipulation of the Conjugated Phenyl Moiety in 3-Phenylbenzofulvene Monomers: Effects on Spontaneous Polymerization
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topic_title	QD241-441 Structural Manipulation of the Conjugated Phenyl Moiety in 3-Phenylbenzofulvene Monomers: Effects on Spontaneous Polymerization spontaneous polymerization affinity polymerization π-conjugated polymer through-space conjugated polymer polybenzofulvene
topic	misc QD241-441 misc spontaneous polymerization misc affinity polymerization misc π-conjugated polymer misc through-space conjugated polymer misc polybenzofulvene misc Organic chemistry
topic_unstemmed	misc QD241-441 misc spontaneous polymerization misc affinity polymerization misc π-conjugated polymer misc through-space conjugated polymer misc polybenzofulvene misc Organic chemistry
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title	Structural Manipulation of the Conjugated Phenyl Moiety in 3-Phenylbenzofulvene Monomers: Effects on Spontaneous Polymerization
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title_full	Structural Manipulation of the Conjugated Phenyl Moiety in 3-Phenylbenzofulvene Monomers: Effects on Spontaneous Polymerization
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author_browse	Marco Paolino Giorgio Grisci Annalisa Reale Vincenzo Razzano Germano Giuliani Alessandro Donati Raniero Mendichi Daniele Piovani Antonella C. Boccia Alessandro Grillo Gianluca Giorgi Andrea Cappelli
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title_sort	structural manipulation of the conjugated phenyl moiety in 3-phenylbenzofulvene monomers: effects on spontaneous polymerization
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title_auth	Structural Manipulation of the Conjugated Phenyl Moiety in 3-Phenylbenzofulvene Monomers: Effects on Spontaneous Polymerization
abstract	Spontaneous polymerization is an intriguing phenomenon in which pure monomers begin their polymerization without initiators or catalysts. Previously, 3-phenylbenzofulvene monomers were found to polymerize spontaneously after solvent removal. Here, eight new 3-substituted benzofulvene monomers 1a–h were synthesized in order to investigate the effects of differently substituted aromatic rings in position 3 of the benzofulvene scaffold on spontaneous polymerization. The newly synthesized monomers maintained the tendency toward spontaneous polymerization. However, monomer 1a, bearing an ortho-methoxy substituted phenyl, polymerized hardly, thus producing low polymerization yields, inhomogeneous structure, and low molecular weight of the obtained polymeric material. This result suggested the importance of the presence of hydrogen atoms in the 2′-position to achieve productive interactions among the monomers in the recognition step preluding the spontaneous polymerization and among the monomeric units in the polybenzofulvene backbones. Moreover, this study paves the way to modify the pendant rings in position 3 of the indene scaffold to synthesize new polybenzofulvene derivatives variously decorated.
abstractGer	Spontaneous polymerization is an intriguing phenomenon in which pure monomers begin their polymerization without initiators or catalysts. Previously, 3-phenylbenzofulvene monomers were found to polymerize spontaneously after solvent removal. Here, eight new 3-substituted benzofulvene monomers 1a–h were synthesized in order to investigate the effects of differently substituted aromatic rings in position 3 of the benzofulvene scaffold on spontaneous polymerization. The newly synthesized monomers maintained the tendency toward spontaneous polymerization. However, monomer 1a, bearing an ortho-methoxy substituted phenyl, polymerized hardly, thus producing low polymerization yields, inhomogeneous structure, and low molecular weight of the obtained polymeric material. This result suggested the importance of the presence of hydrogen atoms in the 2′-position to achieve productive interactions among the monomers in the recognition step preluding the spontaneous polymerization and among the monomeric units in the polybenzofulvene backbones. Moreover, this study paves the way to modify the pendant rings in position 3 of the indene scaffold to synthesize new polybenzofulvene derivatives variously decorated.
abstract_unstemmed	Spontaneous polymerization is an intriguing phenomenon in which pure monomers begin their polymerization without initiators or catalysts. Previously, 3-phenylbenzofulvene monomers were found to polymerize spontaneously after solvent removal. Here, eight new 3-substituted benzofulvene monomers 1a–h were synthesized in order to investigate the effects of differently substituted aromatic rings in position 3 of the benzofulvene scaffold on spontaneous polymerization. The newly synthesized monomers maintained the tendency toward spontaneous polymerization. However, monomer 1a, bearing an ortho-methoxy substituted phenyl, polymerized hardly, thus producing low polymerization yields, inhomogeneous structure, and low molecular weight of the obtained polymeric material. This result suggested the importance of the presence of hydrogen atoms in the 2′-position to achieve productive interactions among the monomers in the recognition step preluding the spontaneous polymerization and among the monomeric units in the polybenzofulvene backbones. Moreover, this study paves the way to modify the pendant rings in position 3 of the indene scaffold to synthesize new polybenzofulvene derivatives variously decorated.
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title_short	Structural Manipulation of the Conjugated Phenyl Moiety in 3-Phenylbenzofulvene Monomers: Effects on Spontaneous Polymerization
url	https://doi.org/10.3390/polym10070752 https://doaj.org/article/2bd6d03104094a988940d48ab67dd1d6 http://www.mdpi.com/2073-4360/10/7/752 https://doaj.org/toc/2073-4360
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up_date	2024-07-03T22:22:38.652Z
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Structural Manipulation of the Conjugated Phenyl Moiety in 3-Phenylbenzofulvene Monomers: Effects on Spontaneous Polymerization

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