Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties

Blends of cyanate ester and phthalonitrile–polyhedral oligomeric silsesquioxane copolymers were prepared, and their cure behavior and properties were compared via differential scanning calorimetry (DSC) analysis, thermogravimetric (TG) analysis, dynamic mechanical analysis, Fourier-transfo...
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Autor*in:	Xiaodan Li [verfasserIn] Fei Zhou [verfasserIn] Ting Zheng [verfasserIn] Ziqiao Wang [verfasserIn] Heng Zhou [verfasserIn] Haoran Chen [verfasserIn] Lin Xiao [verfasserIn] Dongxing Zhang [verfasserIn] Guanhui Wang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	phthalonitrile polymers phthalonitrile-polyhedral oligomeric silsesquioxane copolymers cyanate ester blends thermal properties

Übergeordnetes Werk:	In: Polymers - MDPI AG, 2011, 11(2019), 1, p 54
Übergeordnetes Werk:	volume:11 ; year:2019 ; number:1, p 54

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/polym11010054

Katalog-ID:	DOAJ011462728

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spelling	10.3390/polym11010054 doi (DE-627)DOAJ011462728 (DE-599)DOAJ087e8637572b475bb73c5b8ae41c924c DE-627 ger DE-627 rakwb eng QD241-441 Xiaodan Li verfasserin aut Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Blends of cyanate ester and phthalonitrile–polyhedral oligomeric silsesquioxane copolymers were prepared, and their cure behavior and properties were compared via differential scanning calorimetry (DSC) analysis, thermogravimetric (TG) analysis, dynamic mechanical analysis, Fourier-transform far-infrared (FTIR) spectroscopy, and rheometric studies. The copolymer blends showed high chemical reactivity, low viscosity, and good thermal stability (TG temperatures were above 400 °C). The glass-transition temperature of the blends increased by at least 140 °C compared to cyanate ester resin. The blends are suitable for preparing carbon-fiber-reinforced composite materials via a winding process and a prepreg lay-up process with a molding technique. The FTIR data showed that the polymerization products contained triazine-ring structures that were responsible for the superior thermal properties. phthalonitrile polymers phthalonitrile-polyhedral oligomeric silsesquioxane copolymers cyanate ester blends thermal properties Organic chemistry Fei Zhou verfasserin aut Ting Zheng verfasserin aut Ziqiao Wang verfasserin aut Heng Zhou verfasserin aut Haoran Chen verfasserin aut Lin Xiao verfasserin aut Dongxing Zhang verfasserin aut Guanhui Wang verfasserin aut In Polymers MDPI AG, 2011 11(2019), 1, p 54 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:11 year:2019 number:1, p 54 https://doi.org/10.3390/polym11010054 kostenfrei https://doaj.org/article/087e8637572b475bb73c5b8ae41c924c kostenfrei http://www.mdpi.com/2073-4360/11/1/54 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2019 1, p 54
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allfieldsGer	10.3390/polym11010054 doi (DE-627)DOAJ011462728 (DE-599)DOAJ087e8637572b475bb73c5b8ae41c924c DE-627 ger DE-627 rakwb eng QD241-441 Xiaodan Li verfasserin aut Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Blends of cyanate ester and phthalonitrile–polyhedral oligomeric silsesquioxane copolymers were prepared, and their cure behavior and properties were compared via differential scanning calorimetry (DSC) analysis, thermogravimetric (TG) analysis, dynamic mechanical analysis, Fourier-transform far-infrared (FTIR) spectroscopy, and rheometric studies. The copolymer blends showed high chemical reactivity, low viscosity, and good thermal stability (TG temperatures were above 400 °C). The glass-transition temperature of the blends increased by at least 140 °C compared to cyanate ester resin. The blends are suitable for preparing carbon-fiber-reinforced composite materials via a winding process and a prepreg lay-up process with a molding technique. The FTIR data showed that the polymerization products contained triazine-ring structures that were responsible for the superior thermal properties. phthalonitrile polymers phthalonitrile-polyhedral oligomeric silsesquioxane copolymers cyanate ester blends thermal properties Organic chemistry Fei Zhou verfasserin aut Ting Zheng verfasserin aut Ziqiao Wang verfasserin aut Heng Zhou verfasserin aut Haoran Chen verfasserin aut Lin Xiao verfasserin aut Dongxing Zhang verfasserin aut Guanhui Wang verfasserin aut In Polymers MDPI AG, 2011 11(2019), 1, p 54 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:11 year:2019 number:1, p 54 https://doi.org/10.3390/polym11010054 kostenfrei https://doaj.org/article/087e8637572b475bb73c5b8ae41c924c kostenfrei http://www.mdpi.com/2073-4360/11/1/54 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2019 1, p 54
allfieldsSound	10.3390/polym11010054 doi (DE-627)DOAJ011462728 (DE-599)DOAJ087e8637572b475bb73c5b8ae41c924c DE-627 ger DE-627 rakwb eng QD241-441 Xiaodan Li verfasserin aut Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Blends of cyanate ester and phthalonitrile–polyhedral oligomeric silsesquioxane copolymers were prepared, and their cure behavior and properties were compared via differential scanning calorimetry (DSC) analysis, thermogravimetric (TG) analysis, dynamic mechanical analysis, Fourier-transform far-infrared (FTIR) spectroscopy, and rheometric studies. The copolymer blends showed high chemical reactivity, low viscosity, and good thermal stability (TG temperatures were above 400 °C). The glass-transition temperature of the blends increased by at least 140 °C compared to cyanate ester resin. The blends are suitable for preparing carbon-fiber-reinforced composite materials via a winding process and a prepreg lay-up process with a molding technique. The FTIR data showed that the polymerization products contained triazine-ring structures that were responsible for the superior thermal properties. phthalonitrile polymers phthalonitrile-polyhedral oligomeric silsesquioxane copolymers cyanate ester blends thermal properties Organic chemistry Fei Zhou verfasserin aut Ting Zheng verfasserin aut Ziqiao Wang verfasserin aut Heng Zhou verfasserin aut Haoran Chen verfasserin aut Lin Xiao verfasserin aut Dongxing Zhang verfasserin aut Guanhui Wang verfasserin aut In Polymers MDPI AG, 2011 11(2019), 1, p 54 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:11 year:2019 number:1, p 54 https://doi.org/10.3390/polym11010054 kostenfrei https://doaj.org/article/087e8637572b475bb73c5b8ae41c924c kostenfrei http://www.mdpi.com/2073-4360/11/1/54 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2019 1, p 54
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institution	findex.gbv.de
topic_facet	phthalonitrile polymers phthalonitrile-polyhedral oligomeric silsesquioxane copolymers cyanate ester blends thermal properties Organic chemistry
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container_title	Polymers
authorswithroles_txt_mv	Xiaodan Li @@aut@@ Fei Zhou @@aut@@ Ting Zheng @@aut@@ Ziqiao Wang @@aut@@ Heng Zhou @@aut@@ Haoran Chen @@aut@@ Lin Xiao @@aut@@ Dongxing Zhang @@aut@@ Guanhui Wang @@aut@@
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callnumber-first	Q - Science
author	Xiaodan Li
spellingShingle	Xiaodan Li misc QD241-441 misc phthalonitrile polymers misc phthalonitrile-polyhedral oligomeric silsesquioxane copolymers misc cyanate ester misc blends misc thermal properties misc Organic chemistry Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties
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topic_title	QD241-441 Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties phthalonitrile polymers phthalonitrile-polyhedral oligomeric silsesquioxane copolymers cyanate ester blends thermal properties
topic	misc QD241-441 misc phthalonitrile polymers misc phthalonitrile-polyhedral oligomeric silsesquioxane copolymers misc cyanate ester misc blends misc thermal properties misc Organic chemistry
topic_unstemmed	misc QD241-441 misc phthalonitrile polymers misc phthalonitrile-polyhedral oligomeric silsesquioxane copolymers misc cyanate ester misc blends misc thermal properties misc Organic chemistry
topic_browse	misc QD241-441 misc phthalonitrile polymers misc phthalonitrile-polyhedral oligomeric silsesquioxane copolymers misc cyanate ester misc blends misc thermal properties misc Organic chemistry
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title	Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties
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title_full	Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties
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author_browse	Xiaodan Li Fei Zhou Ting Zheng Ziqiao Wang Heng Zhou Haoran Chen Lin Xiao Dongxing Zhang Guanhui Wang
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title_sort	blends of cyanate ester and phthalonitrile–polyhedral oligomeric silsesquioxane copolymers: cure behavior and properties
callnumber	QD241-441
title_auth	Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties
abstract	Blends of cyanate ester and phthalonitrile–polyhedral oligomeric silsesquioxane copolymers were prepared, and their cure behavior and properties were compared via differential scanning calorimetry (DSC) analysis, thermogravimetric (TG) analysis, dynamic mechanical analysis, Fourier-transform far-infrared (FTIR) spectroscopy, and rheometric studies. The copolymer blends showed high chemical reactivity, low viscosity, and good thermal stability (TG temperatures were above 400 °C). The glass-transition temperature of the blends increased by at least 140 °C compared to cyanate ester resin. The blends are suitable for preparing carbon-fiber-reinforced composite materials via a winding process and a prepreg lay-up process with a molding technique. The FTIR data showed that the polymerization products contained triazine-ring structures that were responsible for the superior thermal properties.
abstractGer	Blends of cyanate ester and phthalonitrile–polyhedral oligomeric silsesquioxane copolymers were prepared, and their cure behavior and properties were compared via differential scanning calorimetry (DSC) analysis, thermogravimetric (TG) analysis, dynamic mechanical analysis, Fourier-transform far-infrared (FTIR) spectroscopy, and rheometric studies. The copolymer blends showed high chemical reactivity, low viscosity, and good thermal stability (TG temperatures were above 400 °C). The glass-transition temperature of the blends increased by at least 140 °C compared to cyanate ester resin. The blends are suitable for preparing carbon-fiber-reinforced composite materials via a winding process and a prepreg lay-up process with a molding technique. The FTIR data showed that the polymerization products contained triazine-ring structures that were responsible for the superior thermal properties.
abstract_unstemmed	Blends of cyanate ester and phthalonitrile–polyhedral oligomeric silsesquioxane copolymers were prepared, and their cure behavior and properties were compared via differential scanning calorimetry (DSC) analysis, thermogravimetric (TG) analysis, dynamic mechanical analysis, Fourier-transform far-infrared (FTIR) spectroscopy, and rheometric studies. The copolymer blends showed high chemical reactivity, low viscosity, and good thermal stability (TG temperatures were above 400 °C). The glass-transition temperature of the blends increased by at least 140 °C compared to cyanate ester resin. The blends are suitable for preparing carbon-fiber-reinforced composite materials via a winding process and a prepreg lay-up process with a molding technique. The FTIR data showed that the polymerization products contained triazine-ring structures that were responsible for the superior thermal properties.
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container_issue	1, p 54
title_short	Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties
url	https://doi.org/10.3390/polym11010054 https://doaj.org/article/087e8637572b475bb73c5b8ae41c924c http://www.mdpi.com/2073-4360/11/1/54 https://doaj.org/toc/2073-4360
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up_date	2024-07-03T20:28:07.907Z
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Blends of Cyanate Ester and Phthalonitrile–Polyhedral Oligomeric Silsesquioxane Copolymers: Cure Behavior and Properties

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