From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation

A simple preparation of metal sulfide nanoparticles via the decomposition of thiobenzoate precursors at room temperature is presented and discussed. Long chain alkylamines were found to mediate the breakdown of metal thiobenzoates, such as those containing Ag, Cu, In and Cd, to produce uniform Ag2S,...
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Autor*in:	Fenfang Yin [verfasserIn] Hairuo Xu [verfasserIn] Chiong Teck Wong [verfasserIn] Wen Pei Lim [verfasserIn] Zhihua Zhang [verfasserIn] Wee Shong Chin [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2012

Schlagwörter:	metal sulfide nanoparticles thiobenzoates silver sulfide copper sulfide indium sulfide cadmium sulfide

Übergeordnetes Werk:	In: Nanomaterials - MDPI AG, 2012, 2(2012), 2, Seite 113-133
Übergeordnetes Werk:	volume:2 ; year:2012 ; number:2 ; pages:113-133

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/nano2020113

Katalog-ID:	DOAJ011581166

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520			\|a A simple preparation of metal sulfide nanoparticles via the decomposition of thiobenzoate precursors at room temperature is presented and discussed. Long chain alkylamines were found to mediate the breakdown of metal thiobenzoates, such as those containing Ag, Cu, In and Cd, to produce uniform Ag2S, Cu2−xS, In2S3 and CdS nanoparticles respectively. The long chain amines are assumed to play dual roles as the nucleophilic reagent and the capping agent. It was found that sizes of the nanoparticles can be controlled by changing the type of amine used, as well as the molar ratio between amine and the precursor. We performed DFT calculations on a proposed mechanism involving an initial nucleophilic addition of amine molecule onto the thiocarboxylates. The proposed reaction was also confirmed through the analysis of by-products via infrared spectroscopy. On the basis of this understanding, we propose to manipulate the stability of the precursors by coordination with suitable stabilizing groups, such that the reaction kinetics can be modified to generate different nanostructures of interest.
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allfields	10.3390/nano2020113 doi (DE-627)DOAJ011581166 (DE-599)DOAJ41166888580743ba96d78bfa007d480b DE-627 ger DE-627 rakwb eng QD1-999 Fenfang Yin verfasserin aut From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A simple preparation of metal sulfide nanoparticles via the decomposition of thiobenzoate precursors at room temperature is presented and discussed. Long chain alkylamines were found to mediate the breakdown of metal thiobenzoates, such as those containing Ag, Cu, In and Cd, to produce uniform Ag2S, Cu2−xS, In2S3 and CdS nanoparticles respectively. The long chain amines are assumed to play dual roles as the nucleophilic reagent and the capping agent. It was found that sizes of the nanoparticles can be controlled by changing the type of amine used, as well as the molar ratio between amine and the precursor. We performed DFT calculations on a proposed mechanism involving an initial nucleophilic addition of amine molecule onto the thiocarboxylates. The proposed reaction was also confirmed through the analysis of by-products via infrared spectroscopy. On the basis of this understanding, we propose to manipulate the stability of the precursors by coordination with suitable stabilizing groups, such that the reaction kinetics can be modified to generate different nanostructures of interest. metal sulfide nanoparticles thiobenzoates silver sulfide copper sulfide indium sulfide cadmium sulfide Chemistry Hairuo Xu verfasserin aut Chiong Teck Wong verfasserin aut Wen Pei Lim verfasserin aut Zhihua Zhang verfasserin aut Wee Shong Chin verfasserin aut In Nanomaterials MDPI AG, 2012 2(2012), 2, Seite 113-133 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:2 year:2012 number:2 pages:113-133 https://doi.org/10.3390/nano2020113 kostenfrei https://doaj.org/article/41166888580743ba96d78bfa007d480b kostenfrei http://www.mdpi.com/2079-4991/2/2/113 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 2 2012 2 113-133
spelling	10.3390/nano2020113 doi (DE-627)DOAJ011581166 (DE-599)DOAJ41166888580743ba96d78bfa007d480b DE-627 ger DE-627 rakwb eng QD1-999 Fenfang Yin verfasserin aut From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A simple preparation of metal sulfide nanoparticles via the decomposition of thiobenzoate precursors at room temperature is presented and discussed. Long chain alkylamines were found to mediate the breakdown of metal thiobenzoates, such as those containing Ag, Cu, In and Cd, to produce uniform Ag2S, Cu2−xS, In2S3 and CdS nanoparticles respectively. The long chain amines are assumed to play dual roles as the nucleophilic reagent and the capping agent. It was found that sizes of the nanoparticles can be controlled by changing the type of amine used, as well as the molar ratio between amine and the precursor. We performed DFT calculations on a proposed mechanism involving an initial nucleophilic addition of amine molecule onto the thiocarboxylates. The proposed reaction was also confirmed through the analysis of by-products via infrared spectroscopy. On the basis of this understanding, we propose to manipulate the stability of the precursors by coordination with suitable stabilizing groups, such that the reaction kinetics can be modified to generate different nanostructures of interest. metal sulfide nanoparticles thiobenzoates silver sulfide copper sulfide indium sulfide cadmium sulfide Chemistry Hairuo Xu verfasserin aut Chiong Teck Wong verfasserin aut Wen Pei Lim verfasserin aut Zhihua Zhang verfasserin aut Wee Shong Chin verfasserin aut In Nanomaterials MDPI AG, 2012 2(2012), 2, Seite 113-133 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:2 year:2012 number:2 pages:113-133 https://doi.org/10.3390/nano2020113 kostenfrei https://doaj.org/article/41166888580743ba96d78bfa007d480b kostenfrei http://www.mdpi.com/2079-4991/2/2/113 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 2 2012 2 113-133
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allfieldsSound	10.3390/nano2020113 doi (DE-627)DOAJ011581166 (DE-599)DOAJ41166888580743ba96d78bfa007d480b DE-627 ger DE-627 rakwb eng QD1-999 Fenfang Yin verfasserin aut From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A simple preparation of metal sulfide nanoparticles via the decomposition of thiobenzoate precursors at room temperature is presented and discussed. Long chain alkylamines were found to mediate the breakdown of metal thiobenzoates, such as those containing Ag, Cu, In and Cd, to produce uniform Ag2S, Cu2−xS, In2S3 and CdS nanoparticles respectively. The long chain amines are assumed to play dual roles as the nucleophilic reagent and the capping agent. It was found that sizes of the nanoparticles can be controlled by changing the type of amine used, as well as the molar ratio between amine and the precursor. We performed DFT calculations on a proposed mechanism involving an initial nucleophilic addition of amine molecule onto the thiocarboxylates. The proposed reaction was also confirmed through the analysis of by-products via infrared spectroscopy. On the basis of this understanding, we propose to manipulate the stability of the precursors by coordination with suitable stabilizing groups, such that the reaction kinetics can be modified to generate different nanostructures of interest. metal sulfide nanoparticles thiobenzoates silver sulfide copper sulfide indium sulfide cadmium sulfide Chemistry Hairuo Xu verfasserin aut Chiong Teck Wong verfasserin aut Wen Pei Lim verfasserin aut Zhihua Zhang verfasserin aut Wee Shong Chin verfasserin aut In Nanomaterials MDPI AG, 2012 2(2012), 2, Seite 113-133 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:2 year:2012 number:2 pages:113-133 https://doi.org/10.3390/nano2020113 kostenfrei https://doaj.org/article/41166888580743ba96d78bfa007d480b kostenfrei http://www.mdpi.com/2079-4991/2/2/113 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 2 2012 2 113-133
language	English
source	In Nanomaterials 2(2012), 2, Seite 113-133 volume:2 year:2012 number:2 pages:113-133
sourceStr	In Nanomaterials 2(2012), 2, Seite 113-133 volume:2 year:2012 number:2 pages:113-133
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	metal sulfide nanoparticles thiobenzoates silver sulfide copper sulfide indium sulfide cadmium sulfide Chemistry
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container_title	Nanomaterials
authorswithroles_txt_mv	Fenfang Yin @@aut@@ Hairuo Xu @@aut@@ Chiong Teck Wong @@aut@@ Wen Pei Lim @@aut@@ Zhihua Zhang @@aut@@ Wee Shong Chin @@aut@@
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callnumber-first	Q - Science
author	Fenfang Yin
spellingShingle	Fenfang Yin misc QD1-999 misc metal sulfide nanoparticles misc thiobenzoates misc silver sulfide misc copper sulfide misc indium sulfide misc cadmium sulfide misc Chemistry From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation
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topic_title	QD1-999 From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation metal sulfide nanoparticles thiobenzoates silver sulfide copper sulfide indium sulfide cadmium sulfide
topic	misc QD1-999 misc metal sulfide nanoparticles misc thiobenzoates misc silver sulfide misc copper sulfide misc indium sulfide misc cadmium sulfide misc Chemistry
topic_unstemmed	misc QD1-999 misc metal sulfide nanoparticles misc thiobenzoates misc silver sulfide misc copper sulfide misc indium sulfide misc cadmium sulfide misc Chemistry
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title	From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation
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title_sort	from metal thiobenzoates to metal sulfide nanocrystals: an experimental and theoretical investigation
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title_auth	From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation
abstract	A simple preparation of metal sulfide nanoparticles via the decomposition of thiobenzoate precursors at room temperature is presented and discussed. Long chain alkylamines were found to mediate the breakdown of metal thiobenzoates, such as those containing Ag, Cu, In and Cd, to produce uniform Ag2S, Cu2−xS, In2S3 and CdS nanoparticles respectively. The long chain amines are assumed to play dual roles as the nucleophilic reagent and the capping agent. It was found that sizes of the nanoparticles can be controlled by changing the type of amine used, as well as the molar ratio between amine and the precursor. We performed DFT calculations on a proposed mechanism involving an initial nucleophilic addition of amine molecule onto the thiocarboxylates. The proposed reaction was also confirmed through the analysis of by-products via infrared spectroscopy. On the basis of this understanding, we propose to manipulate the stability of the precursors by coordination with suitable stabilizing groups, such that the reaction kinetics can be modified to generate different nanostructures of interest.
abstractGer	A simple preparation of metal sulfide nanoparticles via the decomposition of thiobenzoate precursors at room temperature is presented and discussed. Long chain alkylamines were found to mediate the breakdown of metal thiobenzoates, such as those containing Ag, Cu, In and Cd, to produce uniform Ag2S, Cu2−xS, In2S3 and CdS nanoparticles respectively. The long chain amines are assumed to play dual roles as the nucleophilic reagent and the capping agent. It was found that sizes of the nanoparticles can be controlled by changing the type of amine used, as well as the molar ratio between amine and the precursor. We performed DFT calculations on a proposed mechanism involving an initial nucleophilic addition of amine molecule onto the thiocarboxylates. The proposed reaction was also confirmed through the analysis of by-products via infrared spectroscopy. On the basis of this understanding, we propose to manipulate the stability of the precursors by coordination with suitable stabilizing groups, such that the reaction kinetics can be modified to generate different nanostructures of interest.
abstract_unstemmed	A simple preparation of metal sulfide nanoparticles via the decomposition of thiobenzoate precursors at room temperature is presented and discussed. Long chain alkylamines were found to mediate the breakdown of metal thiobenzoates, such as those containing Ag, Cu, In and Cd, to produce uniform Ag2S, Cu2−xS, In2S3 and CdS nanoparticles respectively. The long chain amines are assumed to play dual roles as the nucleophilic reagent and the capping agent. It was found that sizes of the nanoparticles can be controlled by changing the type of amine used, as well as the molar ratio between amine and the precursor. We performed DFT calculations on a proposed mechanism involving an initial nucleophilic addition of amine molecule onto the thiocarboxylates. The proposed reaction was also confirmed through the analysis of by-products via infrared spectroscopy. On the basis of this understanding, we propose to manipulate the stability of the precursors by coordination with suitable stabilizing groups, such that the reaction kinetics can be modified to generate different nanostructures of interest.
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title_short	From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation
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