Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate

Oxidation of benzyl alcohol and some meta- and para- substituted alcohols by phenyliodoso acetate (PIA) in t-butyl alcohol–water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction was found to be 1:1. The reaction was first order each in substrate...
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Autor*in:	R. Girija [verfasserIn] S. Aruna [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2011

Übergeordnetes Werk:	In: E-Journal of Chemistry - Hindawi Limited, 2016, 8(2011), 1, Seite 264-268
Übergeordnetes Werk:	volume:8 ; year:2011 ; number:1 ; pages:264-268

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc Journal toc

DOI / URN:	10.1155/2011/783916

Katalog-ID:	DOAJ011808322

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spelling	10.1155/2011/783916 doi (DE-627)DOAJ011808322 (DE-599)DOAJdeac5e23792c477c96b0ac14d253f360 DE-627 ger DE-627 rakwb eng QD1-999 R. Girija verfasserin aut Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Oxidation of benzyl alcohol and some meta- and para- substituted alcohols by phenyliodoso acetate (PIA) in t-butyl alcohol–water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction was found to be 1:1. The reaction was first order each in substrate and oxidant concentrations. This reaction was studied at four different temperatures and the activation parameters were calculated. Correlation analysis was carried out using Taft’s and Swain’s dual substituent parameter (DSP) equation. The rate data of meta- compounds showed good correlation with (F,R) values, para-substituted benzyl alcohols showed good correlation with σIσR+ A suitable mechanism has been proposed. Chemistry S. Aruna verfasserin aut In E-Journal of Chemistry Hindawi Limited, 2016 8(2011), 1, Seite 264-268 (DE-627)548128820 (DE-600)2393625-3 20909810 nnns volume:8 year:2011 number:1 pages:264-268 https://doi.org/10.1155/2011/783916 kostenfrei https://doaj.org/article/deac5e23792c477c96b0ac14d253f360 kostenfrei http://dx.doi.org/10.1155/2011/783916 kostenfrei https://doaj.org/toc/0973-4945 Journal toc kostenfrei https://doaj.org/toc/2090-9810 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2011 1 264-268
allfields_unstemmed	10.1155/2011/783916 doi (DE-627)DOAJ011808322 (DE-599)DOAJdeac5e23792c477c96b0ac14d253f360 DE-627 ger DE-627 rakwb eng QD1-999 R. Girija verfasserin aut Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Oxidation of benzyl alcohol and some meta- and para- substituted alcohols by phenyliodoso acetate (PIA) in t-butyl alcohol–water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction was found to be 1:1. The reaction was first order each in substrate and oxidant concentrations. This reaction was studied at four different temperatures and the activation parameters were calculated. Correlation analysis was carried out using Taft’s and Swain’s dual substituent parameter (DSP) equation. The rate data of meta- compounds showed good correlation with (F,R) values, para-substituted benzyl alcohols showed good correlation with σIσR+ A suitable mechanism has been proposed. Chemistry S. Aruna verfasserin aut In E-Journal of Chemistry Hindawi Limited, 2016 8(2011), 1, Seite 264-268 (DE-627)548128820 (DE-600)2393625-3 20909810 nnns volume:8 year:2011 number:1 pages:264-268 https://doi.org/10.1155/2011/783916 kostenfrei https://doaj.org/article/deac5e23792c477c96b0ac14d253f360 kostenfrei http://dx.doi.org/10.1155/2011/783916 kostenfrei https://doaj.org/toc/0973-4945 Journal toc kostenfrei https://doaj.org/toc/2090-9810 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2011 1 264-268
allfieldsGer	10.1155/2011/783916 doi (DE-627)DOAJ011808322 (DE-599)DOAJdeac5e23792c477c96b0ac14d253f360 DE-627 ger DE-627 rakwb eng QD1-999 R. Girija verfasserin aut Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Oxidation of benzyl alcohol and some meta- and para- substituted alcohols by phenyliodoso acetate (PIA) in t-butyl alcohol–water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction was found to be 1:1. The reaction was first order each in substrate and oxidant concentrations. This reaction was studied at four different temperatures and the activation parameters were calculated. Correlation analysis was carried out using Taft’s and Swain’s dual substituent parameter (DSP) equation. The rate data of meta- compounds showed good correlation with (F,R) values, para-substituted benzyl alcohols showed good correlation with σIσR+ A suitable mechanism has been proposed. Chemistry S. Aruna verfasserin aut In E-Journal of Chemistry Hindawi Limited, 2016 8(2011), 1, Seite 264-268 (DE-627)548128820 (DE-600)2393625-3 20909810 nnns volume:8 year:2011 number:1 pages:264-268 https://doi.org/10.1155/2011/783916 kostenfrei https://doaj.org/article/deac5e23792c477c96b0ac14d253f360 kostenfrei http://dx.doi.org/10.1155/2011/783916 kostenfrei https://doaj.org/toc/0973-4945 Journal toc kostenfrei https://doaj.org/toc/2090-9810 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2011 1 264-268
allfieldsSound	10.1155/2011/783916 doi (DE-627)DOAJ011808322 (DE-599)DOAJdeac5e23792c477c96b0ac14d253f360 DE-627 ger DE-627 rakwb eng QD1-999 R. Girija verfasserin aut Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Oxidation of benzyl alcohol and some meta- and para- substituted alcohols by phenyliodoso acetate (PIA) in t-butyl alcohol–water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction was found to be 1:1. The reaction was first order each in substrate and oxidant concentrations. This reaction was studied at four different temperatures and the activation parameters were calculated. Correlation analysis was carried out using Taft’s and Swain’s dual substituent parameter (DSP) equation. The rate data of meta- compounds showed good correlation with (F,R) values, para-substituted benzyl alcohols showed good correlation with σIσR+ A suitable mechanism has been proposed. Chemistry S. Aruna verfasserin aut In E-Journal of Chemistry Hindawi Limited, 2016 8(2011), 1, Seite 264-268 (DE-627)548128820 (DE-600)2393625-3 20909810 nnns volume:8 year:2011 number:1 pages:264-268 https://doi.org/10.1155/2011/783916 kostenfrei https://doaj.org/article/deac5e23792c477c96b0ac14d253f360 kostenfrei http://dx.doi.org/10.1155/2011/783916 kostenfrei https://doaj.org/toc/0973-4945 Journal toc kostenfrei https://doaj.org/toc/2090-9810 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2011 1 264-268
language	English
source	In E-Journal of Chemistry 8(2011), 1, Seite 264-268 volume:8 year:2011 number:1 pages:264-268
sourceStr	In E-Journal of Chemistry 8(2011), 1, Seite 264-268 volume:8 year:2011 number:1 pages:264-268
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Chemistry
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container_title	E-Journal of Chemistry
authorswithroles_txt_mv	R. Girija @@aut@@ S. Aruna @@aut@@
publishDateDaySort_date	2011-01-01T00:00:00Z
hierarchy_top_id	548128820
id	DOAJ011808322
language_de	englisch
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author	R. Girija
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topic_title	QD1-999 Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate
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title	Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate
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title_full	Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate
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title_sort	kinetics and oxidation of substituted benzyl alcohols by phenyliodoso acetate
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title_auth	Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate
abstract	Oxidation of benzyl alcohol and some meta- and para- substituted alcohols by phenyliodoso acetate (PIA) in t-butyl alcohol–water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction was found to be 1:1. The reaction was first order each in substrate and oxidant concentrations. This reaction was studied at four different temperatures and the activation parameters were calculated. Correlation analysis was carried out using Taft’s and Swain’s dual substituent parameter (DSP) equation. The rate data of meta- compounds showed good correlation with (F,R) values, para-substituted benzyl alcohols showed good correlation with σIσR+ A suitable mechanism has been proposed.
abstractGer	Oxidation of benzyl alcohol and some meta- and para- substituted alcohols by phenyliodoso acetate (PIA) in t-butyl alcohol–water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction was found to be 1:1. The reaction was first order each in substrate and oxidant concentrations. This reaction was studied at four different temperatures and the activation parameters were calculated. Correlation analysis was carried out using Taft’s and Swain’s dual substituent parameter (DSP) equation. The rate data of meta- compounds showed good correlation with (F,R) values, para-substituted benzyl alcohols showed good correlation with σIσR+ A suitable mechanism has been proposed.
abstract_unstemmed	Oxidation of benzyl alcohol and some meta- and para- substituted alcohols by phenyliodoso acetate (PIA) in t-butyl alcohol–water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction was found to be 1:1. The reaction was first order each in substrate and oxidant concentrations. This reaction was studied at four different temperatures and the activation parameters were calculated. Correlation analysis was carried out using Taft’s and Swain’s dual substituent parameter (DSP) equation. The rate data of meta- compounds showed good correlation with (F,R) values, para-substituted benzyl alcohols showed good correlation with σIσR+ A suitable mechanism has been proposed.
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title_short	Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate
url	https://doi.org/10.1155/2011/783916 https://doaj.org/article/deac5e23792c477c96b0ac14d253f360 http://dx.doi.org/10.1155/2011/783916 https://doaj.org/toc/0973-4945 https://doaj.org/toc/2090-9810
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Kinetics and Oxidation of Substituted Benzyl Alcohols by Phenyliodoso Acetate

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