Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)

In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geom...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Qiang Han [verfasserIn] Xiang-Cheng Wang [verfasserIn] Xiu-Ying Li [verfasserIn] Guan-Xin Yao [verfasserIn] Yong-Sheng Yan [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2009

Übergeordnetes Werk:	In: Acta Crystallographica Section E - International Union of Crystallography, 2005, 65(2009), 11, Seite m1282-m1283
Übergeordnetes Werk:	volume:65 ; year:2009 ; number:11 ; pages:m1282-m1283

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1107/S1600536809039154

Katalog-ID:	DOAJ013649604

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spelling	10.1107/S1600536809039154 doi (DE-627)DOAJ013649604 (DE-599)DOAJ4607ffd91dd649f6a4b069f72f2315db DE-627 ger DE-627 rakwb eng QD901-999 Qiang Han verfasserin aut Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II) 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H...O, O—H...N and N—H...(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å]. Crystallography Xiang-Cheng Wang verfasserin aut Xiu-Ying Li verfasserin aut Guan-Xin Yao verfasserin aut Yong-Sheng Yan verfasserin aut In Acta Crystallographica Section E International Union of Crystallography, 2005 65(2009), 11, Seite m1282-m1283 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:65 year:2009 number:11 pages:m1282-m1283 https://doi.org/10.1107/S1600536809039154 kostenfrei https://doaj.org/article/4607ffd91dd649f6a4b069f72f2315db kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536809039154 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 65 2009 11 m1282-m1283
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allfieldsGer	10.1107/S1600536809039154 doi (DE-627)DOAJ013649604 (DE-599)DOAJ4607ffd91dd649f6a4b069f72f2315db DE-627 ger DE-627 rakwb eng QD901-999 Qiang Han verfasserin aut Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II) 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H...O, O—H...N and N—H...(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å]. Crystallography Xiang-Cheng Wang verfasserin aut Xiu-Ying Li verfasserin aut Guan-Xin Yao verfasserin aut Yong-Sheng Yan verfasserin aut In Acta Crystallographica Section E International Union of Crystallography, 2005 65(2009), 11, Seite m1282-m1283 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:65 year:2009 number:11 pages:m1282-m1283 https://doi.org/10.1107/S1600536809039154 kostenfrei https://doaj.org/article/4607ffd91dd649f6a4b069f72f2315db kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536809039154 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 65 2009 11 m1282-m1283
allfieldsSound	10.1107/S1600536809039154 doi (DE-627)DOAJ013649604 (DE-599)DOAJ4607ffd91dd649f6a4b069f72f2315db DE-627 ger DE-627 rakwb eng QD901-999 Qiang Han verfasserin aut Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II) 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H...O, O—H...N and N—H...(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å]. Crystallography Xiang-Cheng Wang verfasserin aut Xiu-Ying Li verfasserin aut Guan-Xin Yao verfasserin aut Yong-Sheng Yan verfasserin aut In Acta Crystallographica Section E International Union of Crystallography, 2005 65(2009), 11, Seite m1282-m1283 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:65 year:2009 number:11 pages:m1282-m1283 https://doi.org/10.1107/S1600536809039154 kostenfrei https://doaj.org/article/4607ffd91dd649f6a4b069f72f2315db kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536809039154 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 65 2009 11 m1282-m1283
language	English
source	In Acta Crystallographica Section E 65(2009), 11, Seite m1282-m1283 volume:65 year:2009 number:11 pages:m1282-m1283
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authorswithroles_txt_mv	Qiang Han @@aut@@ Xiang-Cheng Wang @@aut@@ Xiu-Ying Li @@aut@@ Guan-Xin Yao @@aut@@ Yong-Sheng Yan @@aut@@
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callnumber-first	Q - Science
author	Qiang Han
spellingShingle	Qiang Han misc QD901-999 misc Crystallography Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
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topic_title	QD901-999 Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
topic	misc QD901-999 misc Crystallography
topic_unstemmed	misc QD901-999 misc Crystallography
topic_browse	misc QD901-999 misc Crystallography
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title	Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
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title_full	Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
author_sort	Qiang Han
journal	Acta Crystallographica Section E
journalStr	Acta Crystallographica Section E
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lang_code	eng
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author_browse	Qiang Han Xiang-Cheng Wang Xiu-Ying Li Guan-Xin Yao Yong-Sheng Yan
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format_se	Elektronische Aufsätze
author-letter	Qiang Han
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title_sort	aqua(2-hydroxy-5-sulfonatobenzoato-κo1)bis(2-phenyl-1h-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2n7,n8)zinc(ii)
callnumber	QD901-999
title_auth	Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
abstract	In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H...O, O—H...N and N—H...(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å].
abstractGer	In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H...O, O—H...N and N—H...(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å].
abstract_unstemmed	In the title compound, [Zn(C7H4O6S)(C19H12N4)2(H2O)], the ZnII ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO2N4 octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H...O, O—H...N and N—H...(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å].
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container_issue	11
title_short	Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)
url	https://doi.org/10.1107/S1600536809039154 https://doaj.org/article/4607ffd91dd649f6a4b069f72f2315db http://scripts.iucr.org/cgi-bin/paper?S1600536809039154 https://doaj.org/toc/1600-5368
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doi_str	10.1107/S1600536809039154
callnumber-a	QD901-999
up_date	2024-07-03T18:48:15.705Z
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Aqua(2-hydroxy-5-sulfonatobenzoato-κO1)bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)zinc(II)

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