Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst

The effects of reaction temperature on the hydrocarbon composition of biofuel produced in hydrocracking of Cerbera manghas oil with Ni-Zn/HZSM-5 catalyst were investigated. The incipient wetness impregnation method was applied to prepare the Ni-Zn/HZSM-5 catalysts. Furthermore, the properties of cat...
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Autor*in:	Lenny Marlinda [verfasserIn] Danawati Hari Prajitno [verfasserIn] Achmad Roesyadi [verfasserIn] Ignatius Gunardi [verfasserIn] Yustia Wulandari Mirzayanti [verfasserIn] Muhammad Al Muttaqii [verfasserIn] Agus Budianto [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Übergeordnetes Werk:	In: Eclética Química - Universidade Estadual Paulista, 2019, 47(2022), 1, Seite 17-39
Übergeordnetes Werk:	volume:47 ; year:2022 ; number:1 ; pages:17-39

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc Journal toc

DOI / URN:	10.26850/1678-4618eqj.v47.1.2022.p17-39

Katalog-ID:	DOAJ014115824

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author	Lenny Marlinda
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topic_title	QD1-999 Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst
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title	Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst
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title_full	Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst
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author_browse	Lenny Marlinda Danawati Hari Prajitno Achmad Roesyadi Ignatius Gunardi Yustia Wulandari Mirzayanti Muhammad Al Muttaqii Agus Budianto
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title_sort	biofuel from hydrocracking of cerbera manghas oil over ni-zn/hzsm-5 catalyst
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title_auth	Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst
abstract	The effects of reaction temperature on the hydrocarbon composition of biofuel produced in hydrocracking of Cerbera manghas oil with Ni-Zn/HZSM-5 catalyst were investigated. The incipient wetness impregnation method was applied to prepare the Ni-Zn/HZSM-5 catalysts. Furthermore, the properties of catalysts were measured by X-ray diffraction, atomic absorption spectrometry, and nitrogen physisorption. Hydrocracking process was carried out in Parr USA pressure batch reactor at pressure of 20 ± 5 bar after flowing H2 for 1 h. The reaction with a catalyst/oil ratio of 1 g/150 mL proceeded at various temperatures of 350, 375 and 400 °C for 2 h. Gas chromatography-mass spectrometry was used to analyze biofuel. The most abundant hydrocarbon compounds in biofuel were identified as pentadecane and heptadecane (a major diesel fuel compound) with a different amount at different reaction temperatures. It can be said that the hydrodecarboxylation/decarbonylation routes were the predominant reaction pathways and oxygen removal occurred during hydrocracking. The Cerbera manghas oil can be recommended as a promising biofeed to produce the gasoil as an alternative transportation fuel.
abstractGer	The effects of reaction temperature on the hydrocarbon composition of biofuel produced in hydrocracking of Cerbera manghas oil with Ni-Zn/HZSM-5 catalyst were investigated. The incipient wetness impregnation method was applied to prepare the Ni-Zn/HZSM-5 catalysts. Furthermore, the properties of catalysts were measured by X-ray diffraction, atomic absorption spectrometry, and nitrogen physisorption. Hydrocracking process was carried out in Parr USA pressure batch reactor at pressure of 20 ± 5 bar after flowing H2 for 1 h. The reaction with a catalyst/oil ratio of 1 g/150 mL proceeded at various temperatures of 350, 375 and 400 °C for 2 h. Gas chromatography-mass spectrometry was used to analyze biofuel. The most abundant hydrocarbon compounds in biofuel were identified as pentadecane and heptadecane (a major diesel fuel compound) with a different amount at different reaction temperatures. It can be said that the hydrodecarboxylation/decarbonylation routes were the predominant reaction pathways and oxygen removal occurred during hydrocracking. The Cerbera manghas oil can be recommended as a promising biofeed to produce the gasoil as an alternative transportation fuel.
abstract_unstemmed	The effects of reaction temperature on the hydrocarbon composition of biofuel produced in hydrocracking of Cerbera manghas oil with Ni-Zn/HZSM-5 catalyst were investigated. The incipient wetness impregnation method was applied to prepare the Ni-Zn/HZSM-5 catalysts. Furthermore, the properties of catalysts were measured by X-ray diffraction, atomic absorption spectrometry, and nitrogen physisorption. Hydrocracking process was carried out in Parr USA pressure batch reactor at pressure of 20 ± 5 bar after flowing H2 for 1 h. The reaction with a catalyst/oil ratio of 1 g/150 mL proceeded at various temperatures of 350, 375 and 400 °C for 2 h. Gas chromatography-mass spectrometry was used to analyze biofuel. The most abundant hydrocarbon compounds in biofuel were identified as pentadecane and heptadecane (a major diesel fuel compound) with a different amount at different reaction temperatures. It can be said that the hydrodecarboxylation/decarbonylation routes were the predominant reaction pathways and oxygen removal occurred during hydrocracking. The Cerbera manghas oil can be recommended as a promising biofeed to produce the gasoil as an alternative transportation fuel.
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title_short	Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst
url	https://doi.org/10.26850/1678-4618eqj.v47.1.2022.p17-39 https://doaj.org/article/20870885266140d3aaa0d105b7d90432 http://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/1197 https://doaj.org/toc/0100-4670 https://doaj.org/toc/1678-4618
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Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst

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