(2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II)

In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar en...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Mackenzie J. Freige [verfasserIn] Nilmini K. Senaratne [verfasserIn] David M. Eichhorn [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	crystal structure nickel complex tridentate ligand thiolate ligand imine ligand amine ligand

Übergeordnetes Werk:	In: IUCrData - International Union of Crystallography, 2016, 3(2018), 8, p x181167
Übergeordnetes Werk:	volume:3 ; year:2018 ; number:8, p x181167

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1107/S2414314618011677

Katalog-ID:	DOAJ014481103

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spelling	10.1107/S2414314618011677 doi (DE-627)DOAJ014481103 (DE-599)DOAJ0290ca403395483093d95c2bccfadd40 DE-627 ger DE-627 rakwb eng QD901-999 Mackenzie J. Freige verfasserin aut (2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II) 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar environment. The Ni—Namine bond in the coordination plane is approximately 0.1 Å longer than the Ni—Nimine bond. crystal structure nickel complex tridentate ligand thiolate ligand imine ligand amine ligand Crystallography Nilmini K. Senaratne verfasserin aut David M. Eichhorn verfasserin aut In IUCrData International Union of Crystallography, 2016 3(2018), 8, p x181167 (DE-627)848322010 (DE-600)2847714-5 24143146 nnns volume:3 year:2018 number:8, p x181167 https://doi.org/10.1107/S2414314618011677 kostenfrei https://doaj.org/article/0290ca403395483093d95c2bccfadd40 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2414314618011677 kostenfrei https://doaj.org/toc/2414-3146 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 3 2018 8, p x181167
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allfieldsGer	10.1107/S2414314618011677 doi (DE-627)DOAJ014481103 (DE-599)DOAJ0290ca403395483093d95c2bccfadd40 DE-627 ger DE-627 rakwb eng QD901-999 Mackenzie J. Freige verfasserin aut (2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II) 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar environment. The Ni—Namine bond in the coordination plane is approximately 0.1 Å longer than the Ni—Nimine bond. crystal structure nickel complex tridentate ligand thiolate ligand imine ligand amine ligand Crystallography Nilmini K. Senaratne verfasserin aut David M. Eichhorn verfasserin aut In IUCrData International Union of Crystallography, 2016 3(2018), 8, p x181167 (DE-627)848322010 (DE-600)2847714-5 24143146 nnns volume:3 year:2018 number:8, p x181167 https://doi.org/10.1107/S2414314618011677 kostenfrei https://doaj.org/article/0290ca403395483093d95c2bccfadd40 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2414314618011677 kostenfrei https://doaj.org/toc/2414-3146 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 3 2018 8, p x181167
allfieldsSound	10.1107/S2414314618011677 doi (DE-627)DOAJ014481103 (DE-599)DOAJ0290ca403395483093d95c2bccfadd40 DE-627 ger DE-627 rakwb eng QD901-999 Mackenzie J. Freige verfasserin aut (2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II) 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar environment. The Ni—Namine bond in the coordination plane is approximately 0.1 Å longer than the Ni—Nimine bond. crystal structure nickel complex tridentate ligand thiolate ligand imine ligand amine ligand Crystallography Nilmini K. Senaratne verfasserin aut David M. Eichhorn verfasserin aut In IUCrData International Union of Crystallography, 2016 3(2018), 8, p x181167 (DE-627)848322010 (DE-600)2847714-5 24143146 nnns volume:3 year:2018 number:8, p x181167 https://doi.org/10.1107/S2414314618011677 kostenfrei https://doaj.org/article/0290ca403395483093d95c2bccfadd40 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2414314618011677 kostenfrei https://doaj.org/toc/2414-3146 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 3 2018 8, p x181167
language	English
source	In IUCrData 3(2018), 8, p x181167 volume:3 year:2018 number:8, p x181167
sourceStr	In IUCrData 3(2018), 8, p x181167 volume:3 year:2018 number:8, p x181167
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	crystal structure nickel complex tridentate ligand thiolate ligand imine ligand amine ligand Crystallography
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container_title	IUCrData
authorswithroles_txt_mv	Mackenzie J. Freige @@aut@@ Nilmini K. Senaratne @@aut@@ David M. Eichhorn @@aut@@
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callnumber-first	Q - Science
author	Mackenzie J. Freige
spellingShingle	Mackenzie J. Freige misc QD901-999 misc crystal structure misc nickel complex misc tridentate ligand misc thiolate ligand misc imine ligand misc amine ligand misc Crystallography (2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II)
authorStr	Mackenzie J. Freige
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illustrated	Not Illustrated
issn	24143146
topic_title	QD901-999 (2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II) crystal structure nickel complex tridentate ligand thiolate ligand imine ligand amine ligand
topic	misc QD901-999 misc crystal structure misc nickel complex misc tridentate ligand misc thiolate ligand misc imine ligand misc amine ligand misc Crystallography
topic_unstemmed	misc QD901-999 misc crystal structure misc nickel complex misc tridentate ligand misc thiolate ligand misc imine ligand misc amine ligand misc Crystallography
topic_browse	misc QD901-999 misc crystal structure misc nickel complex misc tridentate ligand misc thiolate ligand misc imine ligand misc amine ligand misc Crystallography
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	(2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II)
ctrlnum	(DE-627)DOAJ014481103 (DE-599)DOAJ0290ca403395483093d95c2bccfadd40
title_full	(2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II)
author_sort	Mackenzie J. Freige
journal	IUCrData
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author_browse	Mackenzie J. Freige Nilmini K. Senaratne David M. Eichhorn
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class	QD901-999
format_se	Elektronische Aufsätze
author-letter	Mackenzie J. Freige
doi_str_mv	10.1107/S2414314618011677
author2-role	verfasserin
title_sort	(2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3n,n′,s)(4-methoxybenzenethiolato-κs)nickel(ii)
callnumber	QD901-999
title_auth	(2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II)
abstract	In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar environment. The Ni—Namine bond in the coordination plane is approximately 0.1 Å longer than the Ni—Nimine bond.
abstractGer	In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar environment. The Ni—Namine bond in the coordination plane is approximately 0.1 Å longer than the Ni—Nimine bond.
abstract_unstemmed	In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar environment. The Ni—Namine bond in the coordination plane is approximately 0.1 Å longer than the Ni—Nimine bond.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700
container_issue	8, p x181167
title_short	(2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II)
url	https://doi.org/10.1107/S2414314618011677 https://doaj.org/article/0290ca403395483093d95c2bccfadd40 http://scripts.iucr.org/cgi-bin/paper?S2414314618011677 https://doaj.org/toc/2414-3146
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author2	Nilmini K. Senaratne David M. Eichhorn
author2Str	Nilmini K. Senaratne David M. Eichhorn
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doi_str	10.1107/S2414314618011677
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up_date	2024-07-03T23:13:37.255Z
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