Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery

Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed a...
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Autor*in:	Jiajie Cui [verfasserIn] Xianwen Wu [verfasserIn] Sinian Yang [verfasserIn] Chuanchang Li [verfasserIn] Fang Tang [verfasserIn] Jian Chen [verfasserIn] Ying Chen [verfasserIn] Yanhong Xiang [verfasserIn] Xianming Wu [verfasserIn] Zeqiang He [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	intercalated potassium compound aqueous rechargeable battery cathode material energy storage and conversion self-discharge

Übergeordnetes Werk:	In: Frontiers in Chemistry - Frontiers Media S.A., 2014, 6(2018)
Übergeordnetes Werk:	volume:6 ; year:2018

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3389/fchem.2018.00352

Katalog-ID:	DOAJ01473480X

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allfields	10.3389/fchem.2018.00352 doi (DE-627)DOAJ01473480X (DE-599)DOAJc2eca9aa463e4aaa845ce7951b4f4ed4 DE-627 ger DE-627 rakwb eng QD1-999 Jiajie Cui verfasserin aut Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed at 400°C for 3 h. The morphology and microstructure of as-prepared KMn8O16 investigated by field-emission scanning electron microscopy (FE-SEM) with the energy spectrum analysis (EDS) and transmission electron microscopy (TEM) demonstrate that one-dimensional nano rods with the length of about 500 nm constitute the microspheres with the diameter about 0.5~2 μm. The cyclic voltammetry measurement displays that the abundant intercalation of zinc ions on the cathode takes place during the initial discharge process, indicating that cryptomelane-type KMn8O16 can be used as the potential cathode material for aqueous zinc ion batteries. The electrode shows a good cycling performance with a reversible capacity of up to 77.0 mAh/g even after 100 cycles and a small self-discharge phenomenon. intercalated potassium compound aqueous rechargeable battery cathode material energy storage and conversion self-discharge Chemistry Xianwen Wu verfasserin aut Xianwen Wu verfasserin aut Sinian Yang verfasserin aut Chuanchang Li verfasserin aut Fang Tang verfasserin aut Jian Chen verfasserin aut Ying Chen verfasserin aut Yanhong Xiang verfasserin aut Xianming Wu verfasserin aut Xianming Wu verfasserin aut Zeqiang He verfasserin aut In Frontiers in Chemistry Frontiers Media S.A., 2014 6(2018) (DE-627)742224538 (DE-600)2711776-5 22962646 nnns volume:6 year:2018 https://doi.org/10.3389/fchem.2018.00352 kostenfrei https://doaj.org/article/c2eca9aa463e4aaa845ce7951b4f4ed4 kostenfrei https://www.frontiersin.org/article/10.3389/fchem.2018.00352/full kostenfrei https://doaj.org/toc/2296-2646 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2018
spelling	10.3389/fchem.2018.00352 doi (DE-627)DOAJ01473480X (DE-599)DOAJc2eca9aa463e4aaa845ce7951b4f4ed4 DE-627 ger DE-627 rakwb eng QD1-999 Jiajie Cui verfasserin aut Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed at 400°C for 3 h. The morphology and microstructure of as-prepared KMn8O16 investigated by field-emission scanning electron microscopy (FE-SEM) with the energy spectrum analysis (EDS) and transmission electron microscopy (TEM) demonstrate that one-dimensional nano rods with the length of about 500 nm constitute the microspheres with the diameter about 0.5~2 μm. The cyclic voltammetry measurement displays that the abundant intercalation of zinc ions on the cathode takes place during the initial discharge process, indicating that cryptomelane-type KMn8O16 can be used as the potential cathode material for aqueous zinc ion batteries. The electrode shows a good cycling performance with a reversible capacity of up to 77.0 mAh/g even after 100 cycles and a small self-discharge phenomenon. intercalated potassium compound aqueous rechargeable battery cathode material energy storage and conversion self-discharge Chemistry Xianwen Wu verfasserin aut Xianwen Wu verfasserin aut Sinian Yang verfasserin aut Chuanchang Li verfasserin aut Fang Tang verfasserin aut Jian Chen verfasserin aut Ying Chen verfasserin aut Yanhong Xiang verfasserin aut Xianming Wu verfasserin aut Xianming Wu verfasserin aut Zeqiang He verfasserin aut In Frontiers in Chemistry Frontiers Media S.A., 2014 6(2018) (DE-627)742224538 (DE-600)2711776-5 22962646 nnns volume:6 year:2018 https://doi.org/10.3389/fchem.2018.00352 kostenfrei https://doaj.org/article/c2eca9aa463e4aaa845ce7951b4f4ed4 kostenfrei https://www.frontiersin.org/article/10.3389/fchem.2018.00352/full kostenfrei https://doaj.org/toc/2296-2646 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2018
allfields_unstemmed	10.3389/fchem.2018.00352 doi (DE-627)DOAJ01473480X (DE-599)DOAJc2eca9aa463e4aaa845ce7951b4f4ed4 DE-627 ger DE-627 rakwb eng QD1-999 Jiajie Cui verfasserin aut Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed at 400°C for 3 h. The morphology and microstructure of as-prepared KMn8O16 investigated by field-emission scanning electron microscopy (FE-SEM) with the energy spectrum analysis (EDS) and transmission electron microscopy (TEM) demonstrate that one-dimensional nano rods with the length of about 500 nm constitute the microspheres with the diameter about 0.5~2 μm. The cyclic voltammetry measurement displays that the abundant intercalation of zinc ions on the cathode takes place during the initial discharge process, indicating that cryptomelane-type KMn8O16 can be used as the potential cathode material for aqueous zinc ion batteries. The electrode shows a good cycling performance with a reversible capacity of up to 77.0 mAh/g even after 100 cycles and a small self-discharge phenomenon. intercalated potassium compound aqueous rechargeable battery cathode material energy storage and conversion self-discharge Chemistry Xianwen Wu verfasserin aut Xianwen Wu verfasserin aut Sinian Yang verfasserin aut Chuanchang Li verfasserin aut Fang Tang verfasserin aut Jian Chen verfasserin aut Ying Chen verfasserin aut Yanhong Xiang verfasserin aut Xianming Wu verfasserin aut Xianming Wu verfasserin aut Zeqiang He verfasserin aut In Frontiers in Chemistry Frontiers Media S.A., 2014 6(2018) (DE-627)742224538 (DE-600)2711776-5 22962646 nnns volume:6 year:2018 https://doi.org/10.3389/fchem.2018.00352 kostenfrei https://doaj.org/article/c2eca9aa463e4aaa845ce7951b4f4ed4 kostenfrei https://www.frontiersin.org/article/10.3389/fchem.2018.00352/full kostenfrei https://doaj.org/toc/2296-2646 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2018
allfieldsGer	10.3389/fchem.2018.00352 doi (DE-627)DOAJ01473480X (DE-599)DOAJc2eca9aa463e4aaa845ce7951b4f4ed4 DE-627 ger DE-627 rakwb eng QD1-999 Jiajie Cui verfasserin aut Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed at 400°C for 3 h. The morphology and microstructure of as-prepared KMn8O16 investigated by field-emission scanning electron microscopy (FE-SEM) with the energy spectrum analysis (EDS) and transmission electron microscopy (TEM) demonstrate that one-dimensional nano rods with the length of about 500 nm constitute the microspheres with the diameter about 0.5~2 μm. The cyclic voltammetry measurement displays that the abundant intercalation of zinc ions on the cathode takes place during the initial discharge process, indicating that cryptomelane-type KMn8O16 can be used as the potential cathode material for aqueous zinc ion batteries. The electrode shows a good cycling performance with a reversible capacity of up to 77.0 mAh/g even after 100 cycles and a small self-discharge phenomenon. intercalated potassium compound aqueous rechargeable battery cathode material energy storage and conversion self-discharge Chemistry Xianwen Wu verfasserin aut Xianwen Wu verfasserin aut Sinian Yang verfasserin aut Chuanchang Li verfasserin aut Fang Tang verfasserin aut Jian Chen verfasserin aut Ying Chen verfasserin aut Yanhong Xiang verfasserin aut Xianming Wu verfasserin aut Xianming Wu verfasserin aut Zeqiang He verfasserin aut In Frontiers in Chemistry Frontiers Media S.A., 2014 6(2018) (DE-627)742224538 (DE-600)2711776-5 22962646 nnns volume:6 year:2018 https://doi.org/10.3389/fchem.2018.00352 kostenfrei https://doaj.org/article/c2eca9aa463e4aaa845ce7951b4f4ed4 kostenfrei https://www.frontiersin.org/article/10.3389/fchem.2018.00352/full kostenfrei https://doaj.org/toc/2296-2646 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2018
allfieldsSound	10.3389/fchem.2018.00352 doi (DE-627)DOAJ01473480X (DE-599)DOAJc2eca9aa463e4aaa845ce7951b4f4ed4 DE-627 ger DE-627 rakwb eng QD1-999 Jiajie Cui verfasserin aut Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed at 400°C for 3 h. The morphology and microstructure of as-prepared KMn8O16 investigated by field-emission scanning electron microscopy (FE-SEM) with the energy spectrum analysis (EDS) and transmission electron microscopy (TEM) demonstrate that one-dimensional nano rods with the length of about 500 nm constitute the microspheres with the diameter about 0.5~2 μm. The cyclic voltammetry measurement displays that the abundant intercalation of zinc ions on the cathode takes place during the initial discharge process, indicating that cryptomelane-type KMn8O16 can be used as the potential cathode material for aqueous zinc ion batteries. The electrode shows a good cycling performance with a reversible capacity of up to 77.0 mAh/g even after 100 cycles and a small self-discharge phenomenon. intercalated potassium compound aqueous rechargeable battery cathode material energy storage and conversion self-discharge Chemistry Xianwen Wu verfasserin aut Xianwen Wu verfasserin aut Sinian Yang verfasserin aut Chuanchang Li verfasserin aut Fang Tang verfasserin aut Jian Chen verfasserin aut Ying Chen verfasserin aut Yanhong Xiang verfasserin aut Xianming Wu verfasserin aut Xianming Wu verfasserin aut Zeqiang He verfasserin aut In Frontiers in Chemistry Frontiers Media S.A., 2014 6(2018) (DE-627)742224538 (DE-600)2711776-5 22962646 nnns volume:6 year:2018 https://doi.org/10.3389/fchem.2018.00352 kostenfrei https://doaj.org/article/c2eca9aa463e4aaa845ce7951b4f4ed4 kostenfrei https://www.frontiersin.org/article/10.3389/fchem.2018.00352/full kostenfrei https://doaj.org/toc/2296-2646 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2018
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container_title	Frontiers in Chemistry
authorswithroles_txt_mv	Jiajie Cui @@aut@@ Xianwen Wu @@aut@@ Sinian Yang @@aut@@ Chuanchang Li @@aut@@ Fang Tang @@aut@@ Jian Chen @@aut@@ Ying Chen @@aut@@ Yanhong Xiang @@aut@@ Xianming Wu @@aut@@ Zeqiang He @@aut@@
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callnumber-first	Q - Science
author	Jiajie Cui
spellingShingle	Jiajie Cui misc QD1-999 misc intercalated potassium compound misc aqueous rechargeable battery misc cathode material misc energy storage and conversion misc self-discharge misc Chemistry Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery
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topic_title	QD1-999 Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery intercalated potassium compound aqueous rechargeable battery cathode material energy storage and conversion self-discharge
topic	misc QD1-999 misc intercalated potassium compound misc aqueous rechargeable battery misc cathode material misc energy storage and conversion misc self-discharge misc Chemistry
topic_unstemmed	misc QD1-999 misc intercalated potassium compound misc aqueous rechargeable battery misc cathode material misc energy storage and conversion misc self-discharge misc Chemistry
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title	Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery
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title_full	Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery
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author_browse	Jiajie Cui Xianwen Wu Sinian Yang Chuanchang Li Fang Tang Jian Chen Ying Chen Yanhong Xiang Xianming Wu Zeqiang He
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title_sort	cryptomelane-type kmn8o16 as potential cathode material — for aqueous zinc ion battery
callnumber	QD1-999
title_auth	Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery
abstract	Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed at 400°C for 3 h. The morphology and microstructure of as-prepared KMn8O16 investigated by field-emission scanning electron microscopy (FE-SEM) with the energy spectrum analysis (EDS) and transmission electron microscopy (TEM) demonstrate that one-dimensional nano rods with the length of about 500 nm constitute the microspheres with the diameter about 0.5~2 μm. The cyclic voltammetry measurement displays that the abundant intercalation of zinc ions on the cathode takes place during the initial discharge process, indicating that cryptomelane-type KMn8O16 can be used as the potential cathode material for aqueous zinc ion batteries. The electrode shows a good cycling performance with a reversible capacity of up to 77.0 mAh/g even after 100 cycles and a small self-discharge phenomenon.
abstractGer	Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed at 400°C for 3 h. The morphology and microstructure of as-prepared KMn8O16 investigated by field-emission scanning electron microscopy (FE-SEM) with the energy spectrum analysis (EDS) and transmission electron microscopy (TEM) demonstrate that one-dimensional nano rods with the length of about 500 nm constitute the microspheres with the diameter about 0.5~2 μm. The cyclic voltammetry measurement displays that the abundant intercalation of zinc ions on the cathode takes place during the initial discharge process, indicating that cryptomelane-type KMn8O16 can be used as the potential cathode material for aqueous zinc ion batteries. The electrode shows a good cycling performance with a reversible capacity of up to 77.0 mAh/g even after 100 cycles and a small self-discharge phenomenon.
abstract_unstemmed	Aqueous battery has been gained much more interest for large-scale energy storage fields due to its excellent safety, high power density and low cost. Cryptomelane-type KMn8O16 confirmed by X-ray diffraction (XRD) was successfully synthesized by a modified hydrothermal method, followed by annealed at 400°C for 3 h. The morphology and microstructure of as-prepared KMn8O16 investigated by field-emission scanning electron microscopy (FE-SEM) with the energy spectrum analysis (EDS) and transmission electron microscopy (TEM) demonstrate that one-dimensional nano rods with the length of about 500 nm constitute the microspheres with the diameter about 0.5~2 μm. The cyclic voltammetry measurement displays that the abundant intercalation of zinc ions on the cathode takes place during the initial discharge process, indicating that cryptomelane-type KMn8O16 can be used as the potential cathode material for aqueous zinc ion batteries. The electrode shows a good cycling performance with a reversible capacity of up to 77.0 mAh/g even after 100 cycles and a small self-discharge phenomenon.
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title_short	Cryptomelane-Type KMn8O16 as Potential Cathode Material — for Aqueous Zinc Ion Battery
url	https://doi.org/10.3389/fchem.2018.00352 https://doaj.org/article/c2eca9aa463e4aaa845ce7951b4f4ed4 https://www.frontiersin.org/article/10.3389/fchem.2018.00352/full https://doaj.org/toc/2296-2646
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author2	Xianwen Wu Sinian Yang Chuanchang Li Fang Tang Jian Chen Ying Chen Yanhong Xiang Xianming Wu Zeqiang He
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up_date	2024-07-04T00:17:06.106Z
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