Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films

Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk fi...
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Autor*in:	Hao Lyu [verfasserIn] Ziyang Sun [verfasserIn] Yang Liu [verfasserIn] Xin Yu [verfasserIn] Chengchen Guo [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	silk film glycerol molecular structures mechanical properties

Übergeordnetes Werk:	In: Molecules - MDPI AG, 2003, 27(2022), 4, p 1339
Übergeordnetes Werk:	volume:27 ; year:2022 ; number:4, p 1339

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/molecules27041339

Katalog-ID:	DOAJ014865874

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allfields	10.3390/molecules27041339 doi (DE-627)DOAJ014865874 (DE-599)DOAJ47c64327335144beb161ae6020ec5fe4 DE-627 ger DE-627 rakwb eng QD241-441 Hao Lyu verfasserin aut Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. In addition, the stretchability and toughness of the films were significantly enhanced. The role of glycerol as a plasticizer in regulating the silk protein structures and determining the properties of the films was thoroughly discussed. silk film glycerol molecular structures mechanical properties Organic chemistry Ziyang Sun verfasserin aut Yang Liu verfasserin aut Xin Yu verfasserin aut Chengchen Guo verfasserin aut In Molecules MDPI AG, 2003 27(2022), 4, p 1339 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:4, p 1339 https://doi.org/10.3390/molecules27041339 kostenfrei https://doaj.org/article/47c64327335144beb161ae6020ec5fe4 kostenfrei https://www.mdpi.com/1420-3049/27/4/1339 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 4, p 1339
spelling	10.3390/molecules27041339 doi (DE-627)DOAJ014865874 (DE-599)DOAJ47c64327335144beb161ae6020ec5fe4 DE-627 ger DE-627 rakwb eng QD241-441 Hao Lyu verfasserin aut Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. In addition, the stretchability and toughness of the films were significantly enhanced. The role of glycerol as a plasticizer in regulating the silk protein structures and determining the properties of the films was thoroughly discussed. silk film glycerol molecular structures mechanical properties Organic chemistry Ziyang Sun verfasserin aut Yang Liu verfasserin aut Xin Yu verfasserin aut Chengchen Guo verfasserin aut In Molecules MDPI AG, 2003 27(2022), 4, p 1339 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:4, p 1339 https://doi.org/10.3390/molecules27041339 kostenfrei https://doaj.org/article/47c64327335144beb161ae6020ec5fe4 kostenfrei https://www.mdpi.com/1420-3049/27/4/1339 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 4, p 1339
allfields_unstemmed	10.3390/molecules27041339 doi (DE-627)DOAJ014865874 (DE-599)DOAJ47c64327335144beb161ae6020ec5fe4 DE-627 ger DE-627 rakwb eng QD241-441 Hao Lyu verfasserin aut Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. In addition, the stretchability and toughness of the films were significantly enhanced. The role of glycerol as a plasticizer in regulating the silk protein structures and determining the properties of the films was thoroughly discussed. silk film glycerol molecular structures mechanical properties Organic chemistry Ziyang Sun verfasserin aut Yang Liu verfasserin aut Xin Yu verfasserin aut Chengchen Guo verfasserin aut In Molecules MDPI AG, 2003 27(2022), 4, p 1339 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:4, p 1339 https://doi.org/10.3390/molecules27041339 kostenfrei https://doaj.org/article/47c64327335144beb161ae6020ec5fe4 kostenfrei https://www.mdpi.com/1420-3049/27/4/1339 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 4, p 1339
allfieldsGer	10.3390/molecules27041339 doi (DE-627)DOAJ014865874 (DE-599)DOAJ47c64327335144beb161ae6020ec5fe4 DE-627 ger DE-627 rakwb eng QD241-441 Hao Lyu verfasserin aut Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. In addition, the stretchability and toughness of the films were significantly enhanced. The role of glycerol as a plasticizer in regulating the silk protein structures and determining the properties of the films was thoroughly discussed. silk film glycerol molecular structures mechanical properties Organic chemistry Ziyang Sun verfasserin aut Yang Liu verfasserin aut Xin Yu verfasserin aut Chengchen Guo verfasserin aut In Molecules MDPI AG, 2003 27(2022), 4, p 1339 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:4, p 1339 https://doi.org/10.3390/molecules27041339 kostenfrei https://doaj.org/article/47c64327335144beb161ae6020ec5fe4 kostenfrei https://www.mdpi.com/1420-3049/27/4/1339 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 4, p 1339
allfieldsSound	10.3390/molecules27041339 doi (DE-627)DOAJ014865874 (DE-599)DOAJ47c64327335144beb161ae6020ec5fe4 DE-627 ger DE-627 rakwb eng QD241-441 Hao Lyu verfasserin aut Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. In addition, the stretchability and toughness of the films were significantly enhanced. The role of glycerol as a plasticizer in regulating the silk protein structures and determining the properties of the films was thoroughly discussed. silk film glycerol molecular structures mechanical properties Organic chemistry Ziyang Sun verfasserin aut Yang Liu verfasserin aut Xin Yu verfasserin aut Chengchen Guo verfasserin aut In Molecules MDPI AG, 2003 27(2022), 4, p 1339 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:4, p 1339 https://doi.org/10.3390/molecules27041339 kostenfrei https://doaj.org/article/47c64327335144beb161ae6020ec5fe4 kostenfrei https://www.mdpi.com/1420-3049/27/4/1339 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 4, p 1339
language	English
source	In Molecules 27(2022), 4, p 1339 volume:27 year:2022 number:4, p 1339
sourceStr	In Molecules 27(2022), 4, p 1339 volume:27 year:2022 number:4, p 1339
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Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. 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callnumber-first	Q - Science
author	Hao Lyu
spellingShingle	Hao Lyu misc QD241-441 misc silk film misc glycerol misc molecular structures misc mechanical properties misc Organic chemistry Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films
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topic_title	QD241-441 Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films silk film glycerol molecular structures mechanical properties
topic	misc QD241-441 misc silk film misc glycerol misc molecular structures misc mechanical properties misc Organic chemistry
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title	Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films
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title_sort	processing-structure-properties relationships of glycerol-plasticized silk films
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title_auth	Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films
abstract	Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. In addition, the stretchability and toughness of the films were significantly enhanced. The role of glycerol as a plasticizer in regulating the silk protein structures and determining the properties of the films was thoroughly discussed.
abstractGer	Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. In addition, the stretchability and toughness of the films were significantly enhanced. The role of glycerol as a plasticizer in regulating the silk protein structures and determining the properties of the films was thoroughly discussed.
abstract_unstemmed	Silk possesses excellent mechanical properties and biocompatibility due to its unique protein sequences and hierarchical structures. Thus, it has been widely used as a biomaterial in a broad spectrum of biomedical applications. In this study, an in-depth investigation of glycerol-plasticized silk films was carried out to understand the processing-structure-properties relationships. A series of glycerol-plasticized silk films with glycerol contents in the range of 0 to 30% (<i<w</i</<i<w</i<) were prepared. The molecular structures and organizations of silk proteins and the interactions between glycerol and proteins were studied using FTIR, XRD, and DSC. At a low glycerol content (<12%), DSC revealed that the glass transition temperature and thermally induced crystallization temperature decreased as the glycerol content increased, implying that glycerol mainly interacts with silk proteins through hydrogen bonding. As the glycerol content further increased, the chain mobility of the silk proteins was promoted, leading to the formation of β-sheet structures, water insolubility, and increased crystallinity. In addition, the stretchability and toughness of the films were significantly enhanced. The role of glycerol as a plasticizer in regulating the silk protein structures and determining the properties of the films was thoroughly discussed.
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title_short	Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films
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score	7.3995066

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Processing-Structure-Properties Relationships of Glycerol-Plasticized Silk Films

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