Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium

In the mononuclear title complex, [CdBr2(C20H17N3)(C3H7NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd2+ atom is distorted trigonal bipyramidal, the axial positions being occupied by the q...
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Autor*in:	Md. Serajul Haque Faizi [verfasserIn] Natalia O. Sharkina [verfasserIn] Yuliya M. Davydenko [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2015

Schlagwörter:	crystal structure CdII complex with IQME quinolinyl-containing Schiff base N—H...Br interactions

Übergeordnetes Werk:	In: Acta Crystallographica Section E: Crystallographic Communications - International Union of Crystallography, 2015, 71(2015), 2, Seite m31-m32
Übergeordnetes Werk:	volume:71 ; year:2015 ; number:2 ; pages:m31-m32

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1107/S2056989015000778

Katalog-ID:	DOAJ018232000

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spelling	10.1107/S2056989015000778 doi (DE-627)DOAJ018232000 (DE-599)DOAJ6d4ee192db2540459af2d7ac38b0f198 DE-627 ger DE-627 rakwb eng QD901-999 Md. Serajul Haque Faizi verfasserin aut Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the mononuclear title complex, [CdBr2(C20H17N3)(C3H7NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd2+ atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one dimethylformamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the CdII atom from the equatorial plane being 0.046 (1) Å. An intramolecular C—H...Br interaction occurs. In the crystal, N—H...Br interactions generate [101] chains. crystal structure CdII complex with IQME quinolinyl-containing Schiff base N—H...Br interactions Crystallography Natalia O. Sharkina verfasserin aut Yuliya M. Davydenko verfasserin aut In Acta Crystallographica Section E: Crystallographic Communications International Union of Crystallography, 2015 71(2015), 2, Seite m31-m32 (DE-627)845400835 (DE-600)2843762-7 20569890 nnns volume:71 year:2015 number:2 pages:m31-m32 https://doi.org/10.1107/S2056989015000778 kostenfrei https://doaj.org/article/6d4ee192db2540459af2d7ac38b0f198 kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2056989015000778 kostenfrei https://doaj.org/toc/2056-9890 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 71 2015 2 m31-m32
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language	English
source	In Acta Crystallographica Section E: Crystallographic Communications 71(2015), 2, Seite m31-m32 volume:71 year:2015 number:2 pages:m31-m32
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topic_facet	crystal structure CdII complex with IQME quinolinyl-containing Schiff base N—H...Br interactions Crystallography
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callnumber-first	Q - Science
author	Md. Serajul Haque Faizi
spellingShingle	Md. Serajul Haque Faizi misc QD901-999 misc crystal structure misc CdII complex with IQME misc quinolinyl-containing Schiff base misc N—H...Br interactions misc Crystallography Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium
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topic_title	QD901-999 Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium crystal structure CdII complex with IQME quinolinyl-containing Schiff base N—H...Br interactions
topic	misc QD901-999 misc crystal structure misc CdII complex with IQME misc quinolinyl-containing Schiff base misc N—H...Br interactions misc Crystallography
topic_unstemmed	misc QD901-999 misc crystal structure misc CdII complex with IQME misc quinolinyl-containing Schiff base misc N—H...Br interactions misc Crystallography
topic_browse	misc QD901-999 misc crystal structure misc CdII complex with IQME misc quinolinyl-containing Schiff base misc N—H...Br interactions misc Crystallography
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title	Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium
ctrlnum	(DE-627)DOAJ018232000 (DE-599)DOAJ6d4ee192db2540459af2d7ac38b0f198
title_full	Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium
author_sort	Md. Serajul Haque Faizi
journal	Acta Crystallographica Section E: Crystallographic Communications
journalStr	Acta Crystallographica Section E: Crystallographic Communications
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author_browse	Md. Serajul Haque Faizi Natalia O. Sharkina Yuliya M. Davydenko
container_volume	71
class	QD901-999
format_se	Elektronische Aufsätze
author-letter	Md. Serajul Haque Faizi
doi_str_mv	10.1107/S2056989015000778
author2-role	verfasserin
title_sort	crystal structure of dibromido(n,n-dimethylformamide-κo){2-(1h-indol-3-yl)-n-[(quinolin-2-yl-κn)methylidene]ethanamine-κn}cadmium
callnumber	QD901-999
title_auth	Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium
abstract	In the mononuclear title complex, [CdBr2(C20H17N3)(C3H7NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd2+ atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one dimethylformamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the CdII atom from the equatorial plane being 0.046 (1) Å. An intramolecular C—H...Br interaction occurs. In the crystal, N—H...Br interactions generate [101] chains.
abstractGer	In the mononuclear title complex, [CdBr2(C20H17N3)(C3H7NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd2+ atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one dimethylformamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the CdII atom from the equatorial plane being 0.046 (1) Å. An intramolecular C—H...Br interaction occurs. In the crystal, N—H...Br interactions generate [101] chains.
abstract_unstemmed	In the mononuclear title complex, [CdBr2(C20H17N3)(C3H7NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd2+ atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one dimethylformamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the CdII atom from the equatorial plane being 0.046 (1) Å. An intramolecular C—H...Br interaction occurs. In the crystal, N—H...Br interactions generate [101] chains.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700
container_issue	2
title_short	Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium
url	https://doi.org/10.1107/S2056989015000778 https://doaj.org/article/6d4ee192db2540459af2d7ac38b0f198 http://scripts.iucr.org/cgi-bin/paper?S2056989015000778 https://doaj.org/toc/2056-9890
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author2	Natalia O. Sharkina Yuliya M. Davydenko
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doi_str	10.1107/S2056989015000778
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up_date	2024-07-03T16:42:04.725Z
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Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium

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