Initiation of MMA polymerization by iniferters based on dithiocarbamates

Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of...
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Autor*in:	Jovanović Slobodan M. [verfasserIn] Nastasović Aleksandra B. [verfasserIn] Džunuzović Enis S. [verfasserIn] Jeremić Katarina B. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch ; srp

Erschienen:	2005

Schlagwörter:	iniferters dithiocarbamates MMA polymerization

Übergeordnetes Werk:	In: Hemijska Industrija - Association of Chemical Engineers of Serbia, 2010, 59(2005), 11-12, Seite 311-316
Übergeordnetes Werk:	volume:59 ; year:2005 ; number:11-12 ; pages:311-316

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.2298/HEMIND0512311J

Katalog-ID:	DOAJ02185176X

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allfields	10.2298/HEMIND0512311J doi (DE-627)DOAJ02185176X (DE-599)DOAJ8bbefbcca44d49c78237ed94007ff58b DE-627 ger DE-627 rakwb eng srp TP1-1185 Jovanović Slobodan M. verfasserin aut Initiation of MMA polymerization by iniferters based on dithiocarbamates 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N',N'-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S Benzyl - N,N - dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide. iniferters dithiocarbamates MMA polymerization Chemical technology Nastasović Aleksandra B. verfasserin aut Džunuzović Enis S. verfasserin aut Jeremić Katarina B. verfasserin aut In Hemijska Industrija Association of Chemical Engineers of Serbia, 2010 59(2005), 11-12, Seite 311-316 (DE-627)1019885629 22177426 nnns volume:59 year:2005 number:11-12 pages:311-316 https://doi.org/10.2298/HEMIND0512311J kostenfrei https://doaj.org/article/8bbefbcca44d49c78237ed94007ff58b kostenfrei http://www.doiserbia.nb.rs/img/doi/0367-598X/2005/0367-598X0512311J.pdf kostenfrei https://doaj.org/toc/0367-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 59 2005 11-12 311-316
spelling	10.2298/HEMIND0512311J doi (DE-627)DOAJ02185176X (DE-599)DOAJ8bbefbcca44d49c78237ed94007ff58b DE-627 ger DE-627 rakwb eng srp TP1-1185 Jovanović Slobodan M. verfasserin aut Initiation of MMA polymerization by iniferters based on dithiocarbamates 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N',N'-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S Benzyl - N,N - dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide. iniferters dithiocarbamates MMA polymerization Chemical technology Nastasović Aleksandra B. verfasserin aut Džunuzović Enis S. verfasserin aut Jeremić Katarina B. verfasserin aut In Hemijska Industrija Association of Chemical Engineers of Serbia, 2010 59(2005), 11-12, Seite 311-316 (DE-627)1019885629 22177426 nnns volume:59 year:2005 number:11-12 pages:311-316 https://doi.org/10.2298/HEMIND0512311J kostenfrei https://doaj.org/article/8bbefbcca44d49c78237ed94007ff58b kostenfrei http://www.doiserbia.nb.rs/img/doi/0367-598X/2005/0367-598X0512311J.pdf kostenfrei https://doaj.org/toc/0367-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 59 2005 11-12 311-316
allfields_unstemmed	10.2298/HEMIND0512311J doi (DE-627)DOAJ02185176X (DE-599)DOAJ8bbefbcca44d49c78237ed94007ff58b DE-627 ger DE-627 rakwb eng srp TP1-1185 Jovanović Slobodan M. verfasserin aut Initiation of MMA polymerization by iniferters based on dithiocarbamates 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N',N'-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S Benzyl - N,N - dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide. iniferters dithiocarbamates MMA polymerization Chemical technology Nastasović Aleksandra B. verfasserin aut Džunuzović Enis S. verfasserin aut Jeremić Katarina B. verfasserin aut In Hemijska Industrija Association of Chemical Engineers of Serbia, 2010 59(2005), 11-12, Seite 311-316 (DE-627)1019885629 22177426 nnns volume:59 year:2005 number:11-12 pages:311-316 https://doi.org/10.2298/HEMIND0512311J kostenfrei https://doaj.org/article/8bbefbcca44d49c78237ed94007ff58b kostenfrei http://www.doiserbia.nb.rs/img/doi/0367-598X/2005/0367-598X0512311J.pdf kostenfrei https://doaj.org/toc/0367-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 59 2005 11-12 311-316
allfieldsGer	10.2298/HEMIND0512311J doi (DE-627)DOAJ02185176X (DE-599)DOAJ8bbefbcca44d49c78237ed94007ff58b DE-627 ger DE-627 rakwb eng srp TP1-1185 Jovanović Slobodan M. verfasserin aut Initiation of MMA polymerization by iniferters based on dithiocarbamates 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N',N'-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S Benzyl - N,N - dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide. iniferters dithiocarbamates MMA polymerization Chemical technology Nastasović Aleksandra B. verfasserin aut Džunuzović Enis S. verfasserin aut Jeremić Katarina B. verfasserin aut In Hemijska Industrija Association of Chemical Engineers of Serbia, 2010 59(2005), 11-12, Seite 311-316 (DE-627)1019885629 22177426 nnns volume:59 year:2005 number:11-12 pages:311-316 https://doi.org/10.2298/HEMIND0512311J kostenfrei https://doaj.org/article/8bbefbcca44d49c78237ed94007ff58b kostenfrei http://www.doiserbia.nb.rs/img/doi/0367-598X/2005/0367-598X0512311J.pdf kostenfrei https://doaj.org/toc/0367-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 59 2005 11-12 311-316
allfieldsSound	10.2298/HEMIND0512311J doi (DE-627)DOAJ02185176X (DE-599)DOAJ8bbefbcca44d49c78237ed94007ff58b DE-627 ger DE-627 rakwb eng srp TP1-1185 Jovanović Slobodan M. verfasserin aut Initiation of MMA polymerization by iniferters based on dithiocarbamates 2005 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N',N'-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S Benzyl - N,N - dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide. iniferters dithiocarbamates MMA polymerization Chemical technology Nastasović Aleksandra B. verfasserin aut Džunuzović Enis S. verfasserin aut Jeremić Katarina B. verfasserin aut In Hemijska Industrija Association of Chemical Engineers of Serbia, 2010 59(2005), 11-12, Seite 311-316 (DE-627)1019885629 22177426 nnns volume:59 year:2005 number:11-12 pages:311-316 https://doi.org/10.2298/HEMIND0512311J kostenfrei https://doaj.org/article/8bbefbcca44d49c78237ed94007ff58b kostenfrei http://www.doiserbia.nb.rs/img/doi/0367-598X/2005/0367-598X0512311J.pdf kostenfrei https://doaj.org/toc/0367-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 59 2005 11-12 311-316
language	English
source	In Hemijska Industrija 59(2005), 11-12, Seite 311-316 volume:59 year:2005 number:11-12 pages:311-316
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authorswithroles_txt_mv	Jovanović Slobodan M. @@aut@@ Nastasović Aleksandra B. @@aut@@ Džunuzović Enis S. @@aut@@ Jeremić Katarina B. @@aut@@
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callnumber-first	T - Technology
author	Jovanović Slobodan M.
spellingShingle	Jovanović Slobodan M. misc TP1-1185 misc iniferters misc dithiocarbamates misc MMA polymerization misc Chemical technology Initiation of MMA polymerization by iniferters based on dithiocarbamates
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topic_title	TP1-1185 Initiation of MMA polymerization by iniferters based on dithiocarbamates iniferters dithiocarbamates MMA polymerization
topic	misc TP1-1185 misc iniferters misc dithiocarbamates misc MMA polymerization misc Chemical technology
topic_unstemmed	misc TP1-1185 misc iniferters misc dithiocarbamates misc MMA polymerization misc Chemical technology
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title	Initiation of MMA polymerization by iniferters based on dithiocarbamates
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title_full	Initiation of MMA polymerization by iniferters based on dithiocarbamates
author_sort	Jovanović Slobodan M.
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author_browse	Jovanović Slobodan M. Nastasović Aleksandra B. Džunuzović Enis S. Jeremić Katarina B.
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title_sort	initiation of mma polymerization by iniferters based on dithiocarbamates
callnumber	TP1-1185
title_auth	Initiation of MMA polymerization by iniferters based on dithiocarbamates
abstract	Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N',N'-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S Benzyl - N,N - dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide.
abstractGer	Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N',N'-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S Benzyl - N,N - dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide.
abstract_unstemmed	Twelve modified dithiocarbamates and a thiuramdisulfide used for the initiation of methyl methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N',N'-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S Benzyl - N,N - dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide.
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title_short	Initiation of MMA polymerization by iniferters based on dithiocarbamates
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Initiation of MMA polymerization by iniferters based on dithiocarbamates

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