Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions

The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techn...
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Autor*in:	Kun Sheng [verfasserIn] Honghua Ge [verfasserIn] Xin Huang [verfasserIn] Yi Zhang [verfasserIn] Yanfang Song [verfasserIn] Fang Ge [verfasserIn] Yuzeng Zhao [verfasserIn] Xinjing Meng [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	calcium carbonate crystals cathodic polarization crystal distortion cathode scale inhibition 2-phosphonobutane-1,2,4-tricarboxylic acid

Übergeordnetes Werk:	In: Crystals - MDPI AG, 2011, 10(2020), 4, p 275
Übergeordnetes Werk:	volume:10 ; year:2020 ; number:4, p 275

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/cryst10040275

Katalog-ID:	DOAJ023901160

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520			\|a The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals.
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allfields	10.3390/cryst10040275 doi (DE-627)DOAJ023901160 (DE-599)DOAJf8c2e7b29730460dbb0c48e24d50c185 DE-627 ger DE-627 rakwb eng QD901-999 Kun Sheng verfasserin aut Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals. calcium carbonate crystals cathodic polarization crystal distortion cathode scale inhibition 2-phosphonobutane-1,2,4-tricarboxylic acid Crystallography Honghua Ge verfasserin aut Xin Huang verfasserin aut Yi Zhang verfasserin aut Yanfang Song verfasserin aut Fang Ge verfasserin aut Yuzeng Zhao verfasserin aut Xinjing Meng verfasserin aut In Crystals MDPI AG, 2011 10(2020), 4, p 275 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:10 year:2020 number:4, p 275 https://doi.org/10.3390/cryst10040275 kostenfrei https://doaj.org/article/f8c2e7b29730460dbb0c48e24d50c185 kostenfrei https://www.mdpi.com/2073-4352/10/4/275 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2020 4, p 275
spelling	10.3390/cryst10040275 doi (DE-627)DOAJ023901160 (DE-599)DOAJf8c2e7b29730460dbb0c48e24d50c185 DE-627 ger DE-627 rakwb eng QD901-999 Kun Sheng verfasserin aut Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals. calcium carbonate crystals cathodic polarization crystal distortion cathode scale inhibition 2-phosphonobutane-1,2,4-tricarboxylic acid Crystallography Honghua Ge verfasserin aut Xin Huang verfasserin aut Yi Zhang verfasserin aut Yanfang Song verfasserin aut Fang Ge verfasserin aut Yuzeng Zhao verfasserin aut Xinjing Meng verfasserin aut In Crystals MDPI AG, 2011 10(2020), 4, p 275 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:10 year:2020 number:4, p 275 https://doi.org/10.3390/cryst10040275 kostenfrei https://doaj.org/article/f8c2e7b29730460dbb0c48e24d50c185 kostenfrei https://www.mdpi.com/2073-4352/10/4/275 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2020 4, p 275
allfields_unstemmed	10.3390/cryst10040275 doi (DE-627)DOAJ023901160 (DE-599)DOAJf8c2e7b29730460dbb0c48e24d50c185 DE-627 ger DE-627 rakwb eng QD901-999 Kun Sheng verfasserin aut Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals. calcium carbonate crystals cathodic polarization crystal distortion cathode scale inhibition 2-phosphonobutane-1,2,4-tricarboxylic acid Crystallography Honghua Ge verfasserin aut Xin Huang verfasserin aut Yi Zhang verfasserin aut Yanfang Song verfasserin aut Fang Ge verfasserin aut Yuzeng Zhao verfasserin aut Xinjing Meng verfasserin aut In Crystals MDPI AG, 2011 10(2020), 4, p 275 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:10 year:2020 number:4, p 275 https://doi.org/10.3390/cryst10040275 kostenfrei https://doaj.org/article/f8c2e7b29730460dbb0c48e24d50c185 kostenfrei https://www.mdpi.com/2073-4352/10/4/275 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2020 4, p 275
allfieldsGer	10.3390/cryst10040275 doi (DE-627)DOAJ023901160 (DE-599)DOAJf8c2e7b29730460dbb0c48e24d50c185 DE-627 ger DE-627 rakwb eng QD901-999 Kun Sheng verfasserin aut Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals. calcium carbonate crystals cathodic polarization crystal distortion cathode scale inhibition 2-phosphonobutane-1,2,4-tricarboxylic acid Crystallography Honghua Ge verfasserin aut Xin Huang verfasserin aut Yi Zhang verfasserin aut Yanfang Song verfasserin aut Fang Ge verfasserin aut Yuzeng Zhao verfasserin aut Xinjing Meng verfasserin aut In Crystals MDPI AG, 2011 10(2020), 4, p 275 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:10 year:2020 number:4, p 275 https://doi.org/10.3390/cryst10040275 kostenfrei https://doaj.org/article/f8c2e7b29730460dbb0c48e24d50c185 kostenfrei https://www.mdpi.com/2073-4352/10/4/275 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2020 4, p 275
allfieldsSound	10.3390/cryst10040275 doi (DE-627)DOAJ023901160 (DE-599)DOAJf8c2e7b29730460dbb0c48e24d50c185 DE-627 ger DE-627 rakwb eng QD901-999 Kun Sheng verfasserin aut Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals. calcium carbonate crystals cathodic polarization crystal distortion cathode scale inhibition 2-phosphonobutane-1,2,4-tricarboxylic acid Crystallography Honghua Ge verfasserin aut Xin Huang verfasserin aut Yi Zhang verfasserin aut Yanfang Song verfasserin aut Fang Ge verfasserin aut Yuzeng Zhao verfasserin aut Xinjing Meng verfasserin aut In Crystals MDPI AG, 2011 10(2020), 4, p 275 (DE-627)718303067 (DE-600)2661516-2 20734352 nnns volume:10 year:2020 number:4, p 275 https://doi.org/10.3390/cryst10040275 kostenfrei https://doaj.org/article/f8c2e7b29730460dbb0c48e24d50c185 kostenfrei https://www.mdpi.com/2073-4352/10/4/275 kostenfrei https://doaj.org/toc/2073-4352 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2020 4, p 275
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source	In Crystals 10(2020), 4, p 275 volume:10 year:2020 number:4, p 275
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topic_facet	calcium carbonate crystals cathodic polarization crystal distortion cathode scale inhibition 2-phosphonobutane-1,2,4-tricarboxylic acid Crystallography
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authorswithroles_txt_mv	Kun Sheng @@aut@@ Honghua Ge @@aut@@ Xin Huang @@aut@@ Yi Zhang @@aut@@ Yanfang Song @@aut@@ Fang Ge @@aut@@ Yuzeng Zhao @@aut@@ Xinjing Meng @@aut@@
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callnumber-first	Q - Science
author	Kun Sheng
spellingShingle	Kun Sheng misc QD901-999 misc calcium carbonate crystals misc cathodic polarization misc crystal distortion misc cathode scale inhibition misc 2-phosphonobutane-1,2,4-tricarboxylic acid misc Crystallography Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions
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topic_title	QD901-999 Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions calcium carbonate crystals cathodic polarization crystal distortion cathode scale inhibition 2-phosphonobutane-1,2,4-tricarboxylic acid
topic	misc QD901-999 misc calcium carbonate crystals misc cathodic polarization misc crystal distortion misc cathode scale inhibition misc 2-phosphonobutane-1,2,4-tricarboxylic acid misc Crystallography
topic_unstemmed	misc QD901-999 misc calcium carbonate crystals misc cathodic polarization misc crystal distortion misc cathode scale inhibition misc 2-phosphonobutane-1,2,4-tricarboxylic acid misc Crystallography
topic_browse	misc QD901-999 misc calcium carbonate crystals misc cathodic polarization misc crystal distortion misc cathode scale inhibition misc 2-phosphonobutane-1,2,4-tricarboxylic acid misc Crystallography
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title	Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions
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title_full	Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions
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author_browse	Kun Sheng Honghua Ge Xin Huang Yi Zhang Yanfang Song Fang Ge Yuzeng Zhao Xinjing Meng
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title_sort	formation and inhibition of calcium carbonate crystals under cathodic polarization conditions
callnumber	QD901-999
title_auth	Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions
abstract	The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals.
abstractGer	The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals.
abstract_unstemmed	The formation of CaCO<sub<3</sub< crystals on the cathode surface and the scale-inhibition performance of scale inhibitor 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on the cathode surface were studied by methods of solution analysis, gravimetric analysis, SEM, FTIR, and XRD techniques. They were then compared with the results of the formation and suppression of CaCO<sub<3</sub< crystals in aqueous solution. PBTCA had a good solution-scale-inhibition performance and good lattice-distortion effects on CaCO<sub<3</sub< crystals in solution, which could change the CaCO<sub<3</sub< from calcite to vaterite and aragonite crystals. The solution-scale-inhibition efficiency exceeded 97% when the PBTCA concentration reached 8 mg/L. Under cathodic polarization conditions, the surface-scale-inhibition efficiency of the cathode and solution-scale-inhibition efficiency near the cathode surface both exceed 97% at polarization potential of −1V. The addition of PBTCA significantly reduced the amount of CaCO<sub<3</sub< crystals formed on the cathode surface and had good surface and solution-scale-inhibition effect. However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. The high-scale-inhibition effect of PBTCA under cathodic polarization was mainly due to the inhibition of the formation of calcium carbonate crystals by PBTCA, and not because of the lattice distortion of CaCO<sub<3</sub< crystals.
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container_issue	4, p 275
title_short	Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions
url	https://doi.org/10.3390/cryst10040275 https://doaj.org/article/f8c2e7b29730460dbb0c48e24d50c185 https://www.mdpi.com/2073-4352/10/4/275 https://doaj.org/toc/2073-4352
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author2	Honghua Ge Xin Huang Yi Zhang Yanfang Song Fang Ge Yuzeng Zhao Xinjing Meng
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up_date	2024-07-03T20:06:02.014Z
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However, the lattice-distortion effect of PBTCA on CaCO<sub<3</sub< crystals disappeared on the cathode surface, and the resulting CaCO<sub<3</sub< contained only calcite crystals. 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Formation and Inhibition of Calcium Carbonate Crystals under Cathodic Polarization Conditions

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