Luminescent Hybrid Material Based on Boron Organic Phosphor and Silica Aerogel Matrix
A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed....
Ausführliche Beschreibung
Autor*in: |
Roman Avetisov [verfasserIn] Artem Lebedev [verfasserIn] Ekaterina Suslova [verfasserIn] Ksenia Kazmina [verfasserIn] Kristina Runina [verfasserIn] Vlada Kovaleva [verfasserIn] Andrew Khomyakov [verfasserIn] Artem Barkanov [verfasserIn] Marina Zykova [verfasserIn] Olga Petrova [verfasserIn] Alisa Mukhsinova [verfasserIn] Denis Shepel [verfasserIn] Artyom Astafiev [verfasserIn] Natalia Menshutina [verfasserIn] Igor Avetissov [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Übergeordnetes Werk: |
In: Molecules - MDPI AG, 2003, 27(2022), 16, p 5226 |
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Übergeordnetes Werk: |
volume:27 ; year:2022 ; number:16, p 5226 |
Links: |
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DOI / URN: |
10.3390/molecules27165226 |
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Katalog-ID: |
DOAJ024488259 |
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10.3390/molecules27165226 doi (DE-627)DOAJ024488259 (DE-599)DOAJ9789efaa0d4e45089d8852a6ba361dbb DE-627 ger DE-627 rakwb eng QD241-441 Roman Avetisov verfasserin aut Luminescent Hybrid Material Based on Boron Organic Phosphor and Silica Aerogel Matrix 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline. Using in situ luminescent measurements, the mechanisms of the formation of boron-based luminescent complexes in isopropanol and tetrahydrofuran media were established. Both hydrophilic and hydrophobic silica aerogels were tested as matrices for the hybrid material. The formation of a thin layer of a boron-containing coordination luminescent compound on the highly developed surface of the SiO<sub<2</sub< aerogel made it possible to strongly stabilize the aerogel structure and noticeably increase the thermal stability of the synthesized hybrid material. aerogel luminescence boron-based phosphor hybrid material Organic chemistry Artem Lebedev verfasserin aut Ekaterina Suslova verfasserin aut Ksenia Kazmina verfasserin aut Kristina Runina verfasserin aut Vlada Kovaleva verfasserin aut Andrew Khomyakov verfasserin aut Artem Barkanov verfasserin aut Marina Zykova verfasserin aut Olga Petrova verfasserin aut Alisa Mukhsinova verfasserin aut Denis Shepel verfasserin aut Artyom Astafiev verfasserin aut Natalia Menshutina verfasserin aut Igor Avetissov verfasserin aut In Molecules MDPI AG, 2003 27(2022), 16, p 5226 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:16, p 5226 https://doi.org/10.3390/molecules27165226 kostenfrei https://doaj.org/article/9789efaa0d4e45089d8852a6ba361dbb kostenfrei https://www.mdpi.com/1420-3049/27/16/5226 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 16, p 5226 |
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10.3390/molecules27165226 doi (DE-627)DOAJ024488259 (DE-599)DOAJ9789efaa0d4e45089d8852a6ba361dbb DE-627 ger DE-627 rakwb eng QD241-441 Roman Avetisov verfasserin aut Luminescent Hybrid Material Based on Boron Organic Phosphor and Silica Aerogel Matrix 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline. Using in situ luminescent measurements, the mechanisms of the formation of boron-based luminescent complexes in isopropanol and tetrahydrofuran media were established. Both hydrophilic and hydrophobic silica aerogels were tested as matrices for the hybrid material. The formation of a thin layer of a boron-containing coordination luminescent compound on the highly developed surface of the SiO<sub<2</sub< aerogel made it possible to strongly stabilize the aerogel structure and noticeably increase the thermal stability of the synthesized hybrid material. aerogel luminescence boron-based phosphor hybrid material Organic chemistry Artem Lebedev verfasserin aut Ekaterina Suslova verfasserin aut Ksenia Kazmina verfasserin aut Kristina Runina verfasserin aut Vlada Kovaleva verfasserin aut Andrew Khomyakov verfasserin aut Artem Barkanov verfasserin aut Marina Zykova verfasserin aut Olga Petrova verfasserin aut Alisa Mukhsinova verfasserin aut Denis Shepel verfasserin aut Artyom Astafiev verfasserin aut Natalia Menshutina verfasserin aut Igor Avetissov verfasserin aut In Molecules MDPI AG, 2003 27(2022), 16, p 5226 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:16, p 5226 https://doi.org/10.3390/molecules27165226 kostenfrei https://doaj.org/article/9789efaa0d4e45089d8852a6ba361dbb kostenfrei https://www.mdpi.com/1420-3049/27/16/5226 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 16, p 5226 |
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10.3390/molecules27165226 doi (DE-627)DOAJ024488259 (DE-599)DOAJ9789efaa0d4e45089d8852a6ba361dbb DE-627 ger DE-627 rakwb eng QD241-441 Roman Avetisov verfasserin aut Luminescent Hybrid Material Based on Boron Organic Phosphor and Silica Aerogel Matrix 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline. Using in situ luminescent measurements, the mechanisms of the formation of boron-based luminescent complexes in isopropanol and tetrahydrofuran media were established. Both hydrophilic and hydrophobic silica aerogels were tested as matrices for the hybrid material. The formation of a thin layer of a boron-containing coordination luminescent compound on the highly developed surface of the SiO<sub<2</sub< aerogel made it possible to strongly stabilize the aerogel structure and noticeably increase the thermal stability of the synthesized hybrid material. aerogel luminescence boron-based phosphor hybrid material Organic chemistry Artem Lebedev verfasserin aut Ekaterina Suslova verfasserin aut Ksenia Kazmina verfasserin aut Kristina Runina verfasserin aut Vlada Kovaleva verfasserin aut Andrew Khomyakov verfasserin aut Artem Barkanov verfasserin aut Marina Zykova verfasserin aut Olga Petrova verfasserin aut Alisa Mukhsinova verfasserin aut Denis Shepel verfasserin aut Artyom Astafiev verfasserin aut Natalia Menshutina verfasserin aut Igor Avetissov verfasserin aut In Molecules MDPI AG, 2003 27(2022), 16, p 5226 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:16, p 5226 https://doi.org/10.3390/molecules27165226 kostenfrei https://doaj.org/article/9789efaa0d4e45089d8852a6ba361dbb kostenfrei https://www.mdpi.com/1420-3049/27/16/5226 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 16, p 5226 |
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10.3390/molecules27165226 doi (DE-627)DOAJ024488259 (DE-599)DOAJ9789efaa0d4e45089d8852a6ba361dbb DE-627 ger DE-627 rakwb eng QD241-441 Roman Avetisov verfasserin aut Luminescent Hybrid Material Based on Boron Organic Phosphor and Silica Aerogel Matrix 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline. Using in situ luminescent measurements, the mechanisms of the formation of boron-based luminescent complexes in isopropanol and tetrahydrofuran media were established. Both hydrophilic and hydrophobic silica aerogels were tested as matrices for the hybrid material. The formation of a thin layer of a boron-containing coordination luminescent compound on the highly developed surface of the SiO<sub<2</sub< aerogel made it possible to strongly stabilize the aerogel structure and noticeably increase the thermal stability of the synthesized hybrid material. aerogel luminescence boron-based phosphor hybrid material Organic chemistry Artem Lebedev verfasserin aut Ekaterina Suslova verfasserin aut Ksenia Kazmina verfasserin aut Kristina Runina verfasserin aut Vlada Kovaleva verfasserin aut Andrew Khomyakov verfasserin aut Artem Barkanov verfasserin aut Marina Zykova verfasserin aut Olga Petrova verfasserin aut Alisa Mukhsinova verfasserin aut Denis Shepel verfasserin aut Artyom Astafiev verfasserin aut Natalia Menshutina verfasserin aut Igor Avetissov verfasserin aut In Molecules MDPI AG, 2003 27(2022), 16, p 5226 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:16, p 5226 https://doi.org/10.3390/molecules27165226 kostenfrei https://doaj.org/article/9789efaa0d4e45089d8852a6ba361dbb kostenfrei https://www.mdpi.com/1420-3049/27/16/5226 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 16, p 5226 |
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10.3390/molecules27165226 doi (DE-627)DOAJ024488259 (DE-599)DOAJ9789efaa0d4e45089d8852a6ba361dbb DE-627 ger DE-627 rakwb eng QD241-441 Roman Avetisov verfasserin aut Luminescent Hybrid Material Based on Boron Organic Phosphor and Silica Aerogel Matrix 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline. Using in situ luminescent measurements, the mechanisms of the formation of boron-based luminescent complexes in isopropanol and tetrahydrofuran media were established. Both hydrophilic and hydrophobic silica aerogels were tested as matrices for the hybrid material. The formation of a thin layer of a boron-containing coordination luminescent compound on the highly developed surface of the SiO<sub<2</sub< aerogel made it possible to strongly stabilize the aerogel structure and noticeably increase the thermal stability of the synthesized hybrid material. aerogel luminescence boron-based phosphor hybrid material Organic chemistry Artem Lebedev verfasserin aut Ekaterina Suslova verfasserin aut Ksenia Kazmina verfasserin aut Kristina Runina verfasserin aut Vlada Kovaleva verfasserin aut Andrew Khomyakov verfasserin aut Artem Barkanov verfasserin aut Marina Zykova verfasserin aut Olga Petrova verfasserin aut Alisa Mukhsinova verfasserin aut Denis Shepel verfasserin aut Artyom Astafiev verfasserin aut Natalia Menshutina verfasserin aut Igor Avetissov verfasserin aut In Molecules MDPI AG, 2003 27(2022), 16, p 5226 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:27 year:2022 number:16, p 5226 https://doi.org/10.3390/molecules27165226 kostenfrei https://doaj.org/article/9789efaa0d4e45089d8852a6ba361dbb kostenfrei https://www.mdpi.com/1420-3049/27/16/5226 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 27 2022 16, p 5226 |
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Roman Avetisov @@aut@@ Artem Lebedev @@aut@@ Ekaterina Suslova @@aut@@ Ksenia Kazmina @@aut@@ Kristina Runina @@aut@@ Vlada Kovaleva @@aut@@ Andrew Khomyakov @@aut@@ Artem Barkanov @@aut@@ Marina Zykova @@aut@@ Olga Petrova @@aut@@ Alisa Mukhsinova @@aut@@ Denis Shepel @@aut@@ Artyom Astafiev @@aut@@ Natalia Menshutina @@aut@@ Igor Avetissov @@aut@@ |
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Luminescent Hybrid Material Based on Boron Organic Phosphor and Silica Aerogel Matrix |
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A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline. Using in situ luminescent measurements, the mechanisms of the formation of boron-based luminescent complexes in isopropanol and tetrahydrofuran media were established. Both hydrophilic and hydrophobic silica aerogels were tested as matrices for the hybrid material. The formation of a thin layer of a boron-containing coordination luminescent compound on the highly developed surface of the SiO<sub<2</sub< aerogel made it possible to strongly stabilize the aerogel structure and noticeably increase the thermal stability of the synthesized hybrid material. |
abstractGer |
A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline. Using in situ luminescent measurements, the mechanisms of the formation of boron-based luminescent complexes in isopropanol and tetrahydrofuran media were established. Both hydrophilic and hydrophobic silica aerogels were tested as matrices for the hybrid material. The formation of a thin layer of a boron-containing coordination luminescent compound on the highly developed surface of the SiO<sub<2</sub< aerogel made it possible to strongly stabilize the aerogel structure and noticeably increase the thermal stability of the synthesized hybrid material. |
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A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline. Using in situ luminescent measurements, the mechanisms of the formation of boron-based luminescent complexes in isopropanol and tetrahydrofuran media were established. Both hydrophilic and hydrophobic silica aerogels were tested as matrices for the hybrid material. The formation of a thin layer of a boron-containing coordination luminescent compound on the highly developed surface of the SiO<sub<2</sub< aerogel made it possible to strongly stabilize the aerogel structure and noticeably increase the thermal stability of the synthesized hybrid material. |
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