Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP

Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corres...
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Autor*in:	Chen Cheng [verfasserIn] Su Shuqian [verfasserIn] Sun Mingmei [verfasserIn] Wang Zhengwen [verfasserIn] Zhang Xingrong [verfasserIn] Tang Linsheng [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Thermoplastic resin Flame retardancy Thermal analysis Microstructural analysis

Übergeordnetes Werk:	In: Polymer Testing - Elsevier, 2021, 117(2023), Seite 107878-
Übergeordnetes Werk:	volume:117 ; year:2023 ; pages:107878-

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1016/j.polymertesting.2022.107878

Katalog-ID:	DOAJ026489597

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520			\|a Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP).
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allfields	10.1016/j.polymertesting.2022.107878 doi (DE-627)DOAJ026489597 (DE-599)DOAJb8792fcb189f486abe311d4ace60f045 DE-627 ger DE-627 rakwb eng TP1080-1185 Chen Cheng verfasserin aut Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP). Thermoplastic resin Flame retardancy Thermal analysis Microstructural analysis Polymers and polymer manufacture Su Shuqian verfasserin aut Sun Mingmei verfasserin aut Wang Zhengwen verfasserin aut Zhang Xingrong verfasserin aut Tang Linsheng verfasserin aut In Polymer Testing Elsevier, 2021 117(2023), Seite 107878- (DE-627)320530280 (DE-600)2015673-X 18732348 nnns volume:117 year:2023 pages:107878- https://doi.org/10.1016/j.polymertesting.2022.107878 kostenfrei https://doaj.org/article/b8792fcb189f486abe311d4ace60f045 kostenfrei http://www.sciencedirect.com/science/article/pii/S0142941822003993 kostenfrei https://doaj.org/toc/0142-9418 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 117 2023 107878-
spelling	10.1016/j.polymertesting.2022.107878 doi (DE-627)DOAJ026489597 (DE-599)DOAJb8792fcb189f486abe311d4ace60f045 DE-627 ger DE-627 rakwb eng TP1080-1185 Chen Cheng verfasserin aut Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP). Thermoplastic resin Flame retardancy Thermal analysis Microstructural analysis Polymers and polymer manufacture Su Shuqian verfasserin aut Sun Mingmei verfasserin aut Wang Zhengwen verfasserin aut Zhang Xingrong verfasserin aut Tang Linsheng verfasserin aut In Polymer Testing Elsevier, 2021 117(2023), Seite 107878- (DE-627)320530280 (DE-600)2015673-X 18732348 nnns volume:117 year:2023 pages:107878- https://doi.org/10.1016/j.polymertesting.2022.107878 kostenfrei https://doaj.org/article/b8792fcb189f486abe311d4ace60f045 kostenfrei http://www.sciencedirect.com/science/article/pii/S0142941822003993 kostenfrei https://doaj.org/toc/0142-9418 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 117 2023 107878-
allfields_unstemmed	10.1016/j.polymertesting.2022.107878 doi (DE-627)DOAJ026489597 (DE-599)DOAJb8792fcb189f486abe311d4ace60f045 DE-627 ger DE-627 rakwb eng TP1080-1185 Chen Cheng verfasserin aut Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP). Thermoplastic resin Flame retardancy Thermal analysis Microstructural analysis Polymers and polymer manufacture Su Shuqian verfasserin aut Sun Mingmei verfasserin aut Wang Zhengwen verfasserin aut Zhang Xingrong verfasserin aut Tang Linsheng verfasserin aut In Polymer Testing Elsevier, 2021 117(2023), Seite 107878- (DE-627)320530280 (DE-600)2015673-X 18732348 nnns volume:117 year:2023 pages:107878- https://doi.org/10.1016/j.polymertesting.2022.107878 kostenfrei https://doaj.org/article/b8792fcb189f486abe311d4ace60f045 kostenfrei http://www.sciencedirect.com/science/article/pii/S0142941822003993 kostenfrei https://doaj.org/toc/0142-9418 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 117 2023 107878-
allfieldsGer	10.1016/j.polymertesting.2022.107878 doi (DE-627)DOAJ026489597 (DE-599)DOAJb8792fcb189f486abe311d4ace60f045 DE-627 ger DE-627 rakwb eng TP1080-1185 Chen Cheng verfasserin aut Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP). Thermoplastic resin Flame retardancy Thermal analysis Microstructural analysis Polymers and polymer manufacture Su Shuqian verfasserin aut Sun Mingmei verfasserin aut Wang Zhengwen verfasserin aut Zhang Xingrong verfasserin aut Tang Linsheng verfasserin aut In Polymer Testing Elsevier, 2021 117(2023), Seite 107878- (DE-627)320530280 (DE-600)2015673-X 18732348 nnns volume:117 year:2023 pages:107878- https://doi.org/10.1016/j.polymertesting.2022.107878 kostenfrei https://doaj.org/article/b8792fcb189f486abe311d4ace60f045 kostenfrei http://www.sciencedirect.com/science/article/pii/S0142941822003993 kostenfrei https://doaj.org/toc/0142-9418 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 117 2023 107878-
allfieldsSound	10.1016/j.polymertesting.2022.107878 doi (DE-627)DOAJ026489597 (DE-599)DOAJb8792fcb189f486abe311d4ace60f045 DE-627 ger DE-627 rakwb eng TP1080-1185 Chen Cheng verfasserin aut Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP 2023 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP). Thermoplastic resin Flame retardancy Thermal analysis Microstructural analysis Polymers and polymer manufacture Su Shuqian verfasserin aut Sun Mingmei verfasserin aut Wang Zhengwen verfasserin aut Zhang Xingrong verfasserin aut Tang Linsheng verfasserin aut In Polymer Testing Elsevier, 2021 117(2023), Seite 107878- (DE-627)320530280 (DE-600)2015673-X 18732348 nnns volume:117 year:2023 pages:107878- https://doi.org/10.1016/j.polymertesting.2022.107878 kostenfrei https://doaj.org/article/b8792fcb189f486abe311d4ace60f045 kostenfrei http://www.sciencedirect.com/science/article/pii/S0142941822003993 kostenfrei https://doaj.org/toc/0142-9418 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 117 2023 107878-
language	English
source	In Polymer Testing 117(2023), Seite 107878- volume:117 year:2023 pages:107878-
sourceStr	In Polymer Testing 117(2023), Seite 107878- volume:117 year:2023 pages:107878-
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Thermoplastic resin Flame retardancy Thermal analysis Microstructural analysis Polymers and polymer manufacture
isfreeaccess_bool	true
container_title	Polymer Testing
authorswithroles_txt_mv	Chen Cheng @@aut@@ Su Shuqian @@aut@@ Sun Mingmei @@aut@@ Wang Zhengwen @@aut@@ Zhang Xingrong @@aut@@ Tang Linsheng @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	320530280
id	DOAJ026489597
language_de	englisch
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callnumber-first	T - Technology
author	Chen Cheng
spellingShingle	Chen Cheng misc TP1080-1185 misc Thermoplastic resin misc Flame retardancy misc Thermal analysis misc Microstructural analysis misc Polymers and polymer manufacture Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP
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topic_title	TP1080-1185 Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP Thermoplastic resin Flame retardancy Thermal analysis Microstructural analysis
topic	misc TP1080-1185 misc Thermoplastic resin misc Flame retardancy misc Thermal analysis misc Microstructural analysis misc Polymers and polymer manufacture
topic_unstemmed	misc TP1080-1185 misc Thermoplastic resin misc Flame retardancy misc Thermal analysis misc Microstructural analysis misc Polymers and polymer manufacture
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title	Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP
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title_full	Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP
author_sort	Chen Cheng
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title_sort	synergistic flame retardancy of zno with piperazine pyrophosphate/melamine polyphosphate in pp
callnumber	TP1080-1185
title_auth	Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP
abstract	Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP).
abstractGer	Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP).
abstract_unstemmed	Common ZnO particles was used to improve the flame retardancy of piperazine pyrophosphate/melamine polyphosphate (PPAP/MPP) in PP composites. 0.5 wt% ZnO exhibited an exceptional synergism by analyzing LOI determination, UL-94 test, and CCT. The LOI increased from 29.9% (no ZnO) to 32.3%. The corresponding flame-retardant rating was improved from UL-94 V-2 to V-0. Additionally, ZnO significantly inhibited the formation of the smoke and CO during the combustion process. The TGA, the component and the structure of the heated FRPP and CCT residues were studied by FTIR, EDS, SEM, Raman spectra and 31P Nuclear Magnetic Resonance, revealing that PPAP/MPP was dominant in the flame retardant process by condensed phase actions. Furthermore, ZnO obviously promoted the formation of the char layer and increased its graphitization degree. Thus, the thermal stability and the strength of the intumescent char layer were improved and then to reinforce the flame retardancy of flame retardant PP (FRPP).
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title_short	Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP
url	https://doi.org/10.1016/j.polymertesting.2022.107878 https://doaj.org/article/b8792fcb189f486abe311d4ace60f045 http://www.sciencedirect.com/science/article/pii/S0142941822003993 https://doaj.org/toc/0142-9418
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up_date	2024-07-03T21:18:44.455Z
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Synergistic flame retardancy of ZnO with piperazine pyrophosphate/melamine polyphosphate in PP

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