Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators

Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal hal...
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Autor*in:	Tan Zhifang [verfasserIn] Pang Jincong [verfasserIn] Niu Guangda [verfasserIn] Yuan Jun-Hui [verfasserIn] Xue Kan-Hao [verfasserIn] Miao Xiangshui [verfasserIn] Tao Weijian [verfasserIn] Zhu Haiming [verfasserIn] Li Zhigang [verfasserIn] Zhao Hongtao [verfasserIn] Du Xinyuan [verfasserIn] Tang Jiang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	electron and hole dimensionality metal halide perovskite scintillators stable tailoring

Übergeordnetes Werk:	In: Nanophotonics - De Gruyter, 2016, 10(2021), 8, Seite 2249-2256
Übergeordnetes Werk:	volume:10 ; year:2021 ; number:8 ; pages:2249-2256

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1515/nanoph-2020-0624

Katalog-ID:	DOAJ026766930

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spelling	10.1515/nanoph-2020-0624 doi (DE-627)DOAJ026766930 (DE-599)DOAJ2fffd0c275824b449b340b98d8953374 DE-627 ger DE-627 rakwb eng QC1-999 Tan Zhifang verfasserin aut Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x TexCl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators. electron and hole dimensionality metal halide perovskite scintillators stable tailoring Physics Pang Jincong verfasserin aut Niu Guangda verfasserin aut Yuan Jun-Hui verfasserin aut Xue Kan-Hao verfasserin aut Miao Xiangshui verfasserin aut Tao Weijian verfasserin aut Zhu Haiming verfasserin aut Li Zhigang verfasserin aut Zhao Hongtao verfasserin aut Du Xinyuan verfasserin aut Tang Jiang verfasserin aut In Nanophotonics De Gruyter, 2016 10(2021), 8, Seite 2249-2256 (DE-627)720169909 (DE-600)2674162-3 21928614 nnns volume:10 year:2021 number:8 pages:2249-2256 https://doi.org/10.1515/nanoph-2020-0624 kostenfrei https://doaj.org/article/2fffd0c275824b449b340b98d8953374 kostenfrei https://doi.org/10.1515/nanoph-2020-0624 kostenfrei https://doaj.org/toc/2192-8614 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2021 8 2249-2256
allfields_unstemmed	10.1515/nanoph-2020-0624 doi (DE-627)DOAJ026766930 (DE-599)DOAJ2fffd0c275824b449b340b98d8953374 DE-627 ger DE-627 rakwb eng QC1-999 Tan Zhifang verfasserin aut Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x TexCl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators. electron and hole dimensionality metal halide perovskite scintillators stable tailoring Physics Pang Jincong verfasserin aut Niu Guangda verfasserin aut Yuan Jun-Hui verfasserin aut Xue Kan-Hao verfasserin aut Miao Xiangshui verfasserin aut Tao Weijian verfasserin aut Zhu Haiming verfasserin aut Li Zhigang verfasserin aut Zhao Hongtao verfasserin aut Du Xinyuan verfasserin aut Tang Jiang verfasserin aut In Nanophotonics De Gruyter, 2016 10(2021), 8, Seite 2249-2256 (DE-627)720169909 (DE-600)2674162-3 21928614 nnns volume:10 year:2021 number:8 pages:2249-2256 https://doi.org/10.1515/nanoph-2020-0624 kostenfrei https://doaj.org/article/2fffd0c275824b449b340b98d8953374 kostenfrei https://doi.org/10.1515/nanoph-2020-0624 kostenfrei https://doaj.org/toc/2192-8614 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2021 8 2249-2256
allfieldsGer	10.1515/nanoph-2020-0624 doi (DE-627)DOAJ026766930 (DE-599)DOAJ2fffd0c275824b449b340b98d8953374 DE-627 ger DE-627 rakwb eng QC1-999 Tan Zhifang verfasserin aut Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x TexCl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators. electron and hole dimensionality metal halide perovskite scintillators stable tailoring Physics Pang Jincong verfasserin aut Niu Guangda verfasserin aut Yuan Jun-Hui verfasserin aut Xue Kan-Hao verfasserin aut Miao Xiangshui verfasserin aut Tao Weijian verfasserin aut Zhu Haiming verfasserin aut Li Zhigang verfasserin aut Zhao Hongtao verfasserin aut Du Xinyuan verfasserin aut Tang Jiang verfasserin aut In Nanophotonics De Gruyter, 2016 10(2021), 8, Seite 2249-2256 (DE-627)720169909 (DE-600)2674162-3 21928614 nnns volume:10 year:2021 number:8 pages:2249-2256 https://doi.org/10.1515/nanoph-2020-0624 kostenfrei https://doaj.org/article/2fffd0c275824b449b340b98d8953374 kostenfrei https://doi.org/10.1515/nanoph-2020-0624 kostenfrei https://doaj.org/toc/2192-8614 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2021 8 2249-2256
allfieldsSound	10.1515/nanoph-2020-0624 doi (DE-627)DOAJ026766930 (DE-599)DOAJ2fffd0c275824b449b340b98d8953374 DE-627 ger DE-627 rakwb eng QC1-999 Tan Zhifang verfasserin aut Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x TexCl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators. electron and hole dimensionality metal halide perovskite scintillators stable tailoring Physics Pang Jincong verfasserin aut Niu Guangda verfasserin aut Yuan Jun-Hui verfasserin aut Xue Kan-Hao verfasserin aut Miao Xiangshui verfasserin aut Tao Weijian verfasserin aut Zhu Haiming verfasserin aut Li Zhigang verfasserin aut Zhao Hongtao verfasserin aut Du Xinyuan verfasserin aut Tang Jiang verfasserin aut In Nanophotonics De Gruyter, 2016 10(2021), 8, Seite 2249-2256 (DE-627)720169909 (DE-600)2674162-3 21928614 nnns volume:10 year:2021 number:8 pages:2249-2256 https://doi.org/10.1515/nanoph-2020-0624 kostenfrei https://doaj.org/article/2fffd0c275824b449b340b98d8953374 kostenfrei https://doi.org/10.1515/nanoph-2020-0624 kostenfrei https://doaj.org/toc/2192-8614 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2021 8 2249-2256
language	English
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topic_facet	electron and hole dimensionality metal halide perovskite scintillators stable tailoring Physics
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callnumber-first	Q - Science
author	Tan Zhifang
spellingShingle	Tan Zhifang misc QC1-999 misc electron and hole dimensionality misc metal halide perovskite misc scintillators misc stable misc tailoring misc Physics Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators
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topic_title	QC1-999 Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators electron and hole dimensionality metal halide perovskite scintillators stable tailoring
topic	misc QC1-999 misc electron and hole dimensionality misc metal halide perovskite misc scintillators misc stable misc tailoring misc Physics
topic_unstemmed	misc QC1-999 misc electron and hole dimensionality misc metal halide perovskite misc scintillators misc stable misc tailoring misc Physics
topic_browse	misc QC1-999 misc electron and hole dimensionality misc metal halide perovskite misc scintillators misc stable misc tailoring misc Physics
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title	Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators
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title_full	Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators
author_sort	Tan Zhifang
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author_browse	Tan Zhifang Pang Jincong Niu Guangda Yuan Jun-Hui Xue Kan-Hao Miao Xiangshui Tao Weijian Zhu Haiming Li Zhigang Zhao Hongtao Du Xinyuan Tang Jiang
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title_sort	tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators
callnumber	QC1-999
title_auth	Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators
abstract	Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x TexCl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators.
abstractGer	Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x TexCl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators.
abstract_unstemmed	Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x TexCl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators.
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container_issue	8
title_short	Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators
url	https://doi.org/10.1515/nanoph-2020-0624 https://doaj.org/article/2fffd0c275824b449b340b98d8953374 https://doaj.org/toc/2192-8614
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author2	Pang Jincong Niu Guangda Yuan Jun-Hui Xue Kan-Hao Miao Xiangshui Tao Weijian Zhu Haiming Li Zhigang Zhao Hongtao Du Xinyuan Tang Jiang
author2Str	Pang Jincong Niu Guangda Yuan Jun-Hui Xue Kan-Hao Miao Xiangshui Tao Weijian Zhu Haiming Li Zhigang Zhao Hongtao Du Xinyuan Tang Jiang
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doi_str	10.1515/nanoph-2020-0624
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up_date	2024-07-03T22:49:45.822Z
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Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators

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