Probing the Mechanical Properties of Porous Nanoshells by Nanoindentation
In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior...
Ausführliche Beschreibung
Autor*in: |
Felipe J. Valencia [verfasserIn] Viviana Aurora [verfasserIn] Max Ramírez [verfasserIn] Carlos J. Ruestes [verfasserIn] Alejandro Prada [verfasserIn] Alejandro Varas [verfasserIn] José Rogan [verfasserIn] |
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E-Artikel |
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Englisch |
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2022 |
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In: Nanomaterials - MDPI AG, 2012, 12(2022), 12, p 2000 |
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Übergeordnetes Werk: |
volume:12 ; year:2022 ; number:12, p 2000 |
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DOI / URN: |
10.3390/nano12122000 |
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Katalog-ID: |
DOAJ027509001 |
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10.3390/nano12122000 doi (DE-627)DOAJ027509001 (DE-599)DOAJ6f0e796e222d436eb2d498525283dccc DE-627 ger DE-627 rakwb eng QD1-999 Felipe J. Valencia verfasserin aut Probing the Mechanical Properties of Porous Nanoshells by Nanoindentation 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior of porous materials. Porous nanoshells display mechanical properties that are dependent on shell porosity. Our results show that, under smaller porosity values, deformation is closely related to the one observed for polycrystalline and single-crystalline nanoshells involving dislocation activity. When porosity in the nanoparticle is increased, plastic deformation was mediated by grain boundary sliding instead of dislocation activity. Additionally, porosity suppresses dislocation activity and decreases nanoparticle strength, but allows for significant strain hardening under strains as high as 0.4. On the other hand, Young’s modulus decreases with the increase in nanoshell porosity, in agreement with the established theories of porous materials. However, we found no quantitative agreement between conventional models applied to obtain the Young’s modulus of porous materials. porous nanoshells molecular dynamics porous materials nanoindentation plasticity Chemistry Viviana Aurora verfasserin aut Max Ramírez verfasserin aut Carlos J. Ruestes verfasserin aut Alejandro Prada verfasserin aut Alejandro Varas verfasserin aut José Rogan verfasserin aut In Nanomaterials MDPI AG, 2012 12(2022), 12, p 2000 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:12 year:2022 number:12, p 2000 https://doi.org/10.3390/nano12122000 kostenfrei https://doaj.org/article/6f0e796e222d436eb2d498525283dccc kostenfrei https://www.mdpi.com/2079-4991/12/12/2000 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2022 12, p 2000 |
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10.3390/nano12122000 doi (DE-627)DOAJ027509001 (DE-599)DOAJ6f0e796e222d436eb2d498525283dccc DE-627 ger DE-627 rakwb eng QD1-999 Felipe J. Valencia verfasserin aut Probing the Mechanical Properties of Porous Nanoshells by Nanoindentation 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior of porous materials. Porous nanoshells display mechanical properties that are dependent on shell porosity. Our results show that, under smaller porosity values, deformation is closely related to the one observed for polycrystalline and single-crystalline nanoshells involving dislocation activity. When porosity in the nanoparticle is increased, plastic deformation was mediated by grain boundary sliding instead of dislocation activity. Additionally, porosity suppresses dislocation activity and decreases nanoparticle strength, but allows for significant strain hardening under strains as high as 0.4. On the other hand, Young’s modulus decreases with the increase in nanoshell porosity, in agreement with the established theories of porous materials. However, we found no quantitative agreement between conventional models applied to obtain the Young’s modulus of porous materials. porous nanoshells molecular dynamics porous materials nanoindentation plasticity Chemistry Viviana Aurora verfasserin aut Max Ramírez verfasserin aut Carlos J. Ruestes verfasserin aut Alejandro Prada verfasserin aut Alejandro Varas verfasserin aut José Rogan verfasserin aut In Nanomaterials MDPI AG, 2012 12(2022), 12, p 2000 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:12 year:2022 number:12, p 2000 https://doi.org/10.3390/nano12122000 kostenfrei https://doaj.org/article/6f0e796e222d436eb2d498525283dccc kostenfrei https://www.mdpi.com/2079-4991/12/12/2000 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2022 12, p 2000 |
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10.3390/nano12122000 doi (DE-627)DOAJ027509001 (DE-599)DOAJ6f0e796e222d436eb2d498525283dccc DE-627 ger DE-627 rakwb eng QD1-999 Felipe J. Valencia verfasserin aut Probing the Mechanical Properties of Porous Nanoshells by Nanoindentation 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior of porous materials. Porous nanoshells display mechanical properties that are dependent on shell porosity. Our results show that, under smaller porosity values, deformation is closely related to the one observed for polycrystalline and single-crystalline nanoshells involving dislocation activity. When porosity in the nanoparticle is increased, plastic deformation was mediated by grain boundary sliding instead of dislocation activity. Additionally, porosity suppresses dislocation activity and decreases nanoparticle strength, but allows for significant strain hardening under strains as high as 0.4. On the other hand, Young’s modulus decreases with the increase in nanoshell porosity, in agreement with the established theories of porous materials. However, we found no quantitative agreement between conventional models applied to obtain the Young’s modulus of porous materials. porous nanoshells molecular dynamics porous materials nanoindentation plasticity Chemistry Viviana Aurora verfasserin aut Max Ramírez verfasserin aut Carlos J. Ruestes verfasserin aut Alejandro Prada verfasserin aut Alejandro Varas verfasserin aut José Rogan verfasserin aut In Nanomaterials MDPI AG, 2012 12(2022), 12, p 2000 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:12 year:2022 number:12, p 2000 https://doi.org/10.3390/nano12122000 kostenfrei https://doaj.org/article/6f0e796e222d436eb2d498525283dccc kostenfrei https://www.mdpi.com/2079-4991/12/12/2000 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2022 12, p 2000 |
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10.3390/nano12122000 doi (DE-627)DOAJ027509001 (DE-599)DOAJ6f0e796e222d436eb2d498525283dccc DE-627 ger DE-627 rakwb eng QD1-999 Felipe J. Valencia verfasserin aut Probing the Mechanical Properties of Porous Nanoshells by Nanoindentation 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior of porous materials. Porous nanoshells display mechanical properties that are dependent on shell porosity. Our results show that, under smaller porosity values, deformation is closely related to the one observed for polycrystalline and single-crystalline nanoshells involving dislocation activity. When porosity in the nanoparticle is increased, plastic deformation was mediated by grain boundary sliding instead of dislocation activity. Additionally, porosity suppresses dislocation activity and decreases nanoparticle strength, but allows for significant strain hardening under strains as high as 0.4. On the other hand, Young’s modulus decreases with the increase in nanoshell porosity, in agreement with the established theories of porous materials. However, we found no quantitative agreement between conventional models applied to obtain the Young’s modulus of porous materials. porous nanoshells molecular dynamics porous materials nanoindentation plasticity Chemistry Viviana Aurora verfasserin aut Max Ramírez verfasserin aut Carlos J. Ruestes verfasserin aut Alejandro Prada verfasserin aut Alejandro Varas verfasserin aut José Rogan verfasserin aut In Nanomaterials MDPI AG, 2012 12(2022), 12, p 2000 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:12 year:2022 number:12, p 2000 https://doi.org/10.3390/nano12122000 kostenfrei https://doaj.org/article/6f0e796e222d436eb2d498525283dccc kostenfrei https://www.mdpi.com/2079-4991/12/12/2000 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2022 12, p 2000 |
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10.3390/nano12122000 doi (DE-627)DOAJ027509001 (DE-599)DOAJ6f0e796e222d436eb2d498525283dccc DE-627 ger DE-627 rakwb eng QD1-999 Felipe J. Valencia verfasserin aut Probing the Mechanical Properties of Porous Nanoshells by Nanoindentation 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior of porous materials. Porous nanoshells display mechanical properties that are dependent on shell porosity. Our results show that, under smaller porosity values, deformation is closely related to the one observed for polycrystalline and single-crystalline nanoshells involving dislocation activity. When porosity in the nanoparticle is increased, plastic deformation was mediated by grain boundary sliding instead of dislocation activity. Additionally, porosity suppresses dislocation activity and decreases nanoparticle strength, but allows for significant strain hardening under strains as high as 0.4. On the other hand, Young’s modulus decreases with the increase in nanoshell porosity, in agreement with the established theories of porous materials. However, we found no quantitative agreement between conventional models applied to obtain the Young’s modulus of porous materials. porous nanoshells molecular dynamics porous materials nanoindentation plasticity Chemistry Viviana Aurora verfasserin aut Max Ramírez verfasserin aut Carlos J. Ruestes verfasserin aut Alejandro Prada verfasserin aut Alejandro Varas verfasserin aut José Rogan verfasserin aut In Nanomaterials MDPI AG, 2012 12(2022), 12, p 2000 (DE-627)718627199 (DE-600)2662255-5 20794991 nnns volume:12 year:2022 number:12, p 2000 https://doi.org/10.3390/nano12122000 kostenfrei https://doaj.org/article/6f0e796e222d436eb2d498525283dccc kostenfrei https://www.mdpi.com/2079-4991/12/12/2000 kostenfrei https://doaj.org/toc/2079-4991 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 12 2022 12, p 2000 |
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Probing the Mechanical Properties of Porous Nanoshells by Nanoindentation |
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In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior of porous materials. Porous nanoshells display mechanical properties that are dependent on shell porosity. Our results show that, under smaller porosity values, deformation is closely related to the one observed for polycrystalline and single-crystalline nanoshells involving dislocation activity. When porosity in the nanoparticle is increased, plastic deformation was mediated by grain boundary sliding instead of dislocation activity. Additionally, porosity suppresses dislocation activity and decreases nanoparticle strength, but allows for significant strain hardening under strains as high as 0.4. On the other hand, Young’s modulus decreases with the increase in nanoshell porosity, in agreement with the established theories of porous materials. However, we found no quantitative agreement between conventional models applied to obtain the Young’s modulus of porous materials. |
abstractGer |
In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior of porous materials. Porous nanoshells display mechanical properties that are dependent on shell porosity. Our results show that, under smaller porosity values, deformation is closely related to the one observed for polycrystalline and single-crystalline nanoshells involving dislocation activity. When porosity in the nanoparticle is increased, plastic deformation was mediated by grain boundary sliding instead of dislocation activity. Additionally, porosity suppresses dislocation activity and decreases nanoparticle strength, but allows for significant strain hardening under strains as high as 0.4. On the other hand, Young’s modulus decreases with the increase in nanoshell porosity, in agreement with the established theories of porous materials. However, we found no quantitative agreement between conventional models applied to obtain the Young’s modulus of porous materials. |
abstract_unstemmed |
In this contribution, we present a study of the mechanical properties of porous nanoshells measured with a nanoindentation technique. Porous nanoshells with hollow designs can present attractive mechanical properties, as observed in hollow nanoshells, but coupled with the unique mechanical behavior of porous materials. Porous nanoshells display mechanical properties that are dependent on shell porosity. Our results show that, under smaller porosity values, deformation is closely related to the one observed for polycrystalline and single-crystalline nanoshells involving dislocation activity. When porosity in the nanoparticle is increased, plastic deformation was mediated by grain boundary sliding instead of dislocation activity. Additionally, porosity suppresses dislocation activity and decreases nanoparticle strength, but allows for significant strain hardening under strains as high as 0.4. On the other hand, Young’s modulus decreases with the increase in nanoshell porosity, in agreement with the established theories of porous materials. However, we found no quantitative agreement between conventional models applied to obtain the Young’s modulus of porous materials. |
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