In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries

Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, in...
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Autor*in:	Dechao Zhang [verfasserIn] Zhengbo Liu [verfasserIn] Yiwen Wu [verfasserIn] Shaomin Ji [verfasserIn] Zhanxiang Yuan [verfasserIn] Jun Liu [verfasserIn] Min Zhu [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	dendrite‐free interface construction long lifespan solid electrolyte interface solid‐state lithium metal batteries

Übergeordnetes Werk:	In: Advanced Science - Wiley, 2015, 9(2022), 12, Seite n/a-n/a
Übergeordnetes Werk:	volume:9 ; year:2022 ; number:12 ; pages:n/a-n/a

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1002/advs.202104277

Katalog-ID:	DOAJ029721830

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520			\|a Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs.
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700	0		\|a Min Zhu \|e verfasserin \|4 aut
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allfields	10.1002/advs.202104277 doi (DE-627)DOAJ029721830 (DE-599)DOAJd231c6922de7465babc42ea46291206f DE-627 ger DE-627 rakwb eng Dechao Zhang verfasserin aut In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs. dendrite‐free interface construction long lifespan solid electrolyte interface solid‐state lithium metal batteries Science Q Zhengbo Liu verfasserin aut Yiwen Wu verfasserin aut Shaomin Ji verfasserin aut Zhanxiang Yuan verfasserin aut Jun Liu verfasserin aut Min Zhu verfasserin aut In Advanced Science Wiley, 2015 9(2022), 12, Seite n/a-n/a (DE-627)817357777 (DE-600)2808093-2 21983844 nnns volume:9 year:2022 number:12 pages:n/a-n/a https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/article/d231c6922de7465babc42ea46291206f kostenfrei https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/toc/2198-3844 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2022 12 n/a-n/a
spelling	10.1002/advs.202104277 doi (DE-627)DOAJ029721830 (DE-599)DOAJd231c6922de7465babc42ea46291206f DE-627 ger DE-627 rakwb eng Dechao Zhang verfasserin aut In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs. dendrite‐free interface construction long lifespan solid electrolyte interface solid‐state lithium metal batteries Science Q Zhengbo Liu verfasserin aut Yiwen Wu verfasserin aut Shaomin Ji verfasserin aut Zhanxiang Yuan verfasserin aut Jun Liu verfasserin aut Min Zhu verfasserin aut In Advanced Science Wiley, 2015 9(2022), 12, Seite n/a-n/a (DE-627)817357777 (DE-600)2808093-2 21983844 nnns volume:9 year:2022 number:12 pages:n/a-n/a https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/article/d231c6922de7465babc42ea46291206f kostenfrei https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/toc/2198-3844 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2022 12 n/a-n/a
allfields_unstemmed	10.1002/advs.202104277 doi (DE-627)DOAJ029721830 (DE-599)DOAJd231c6922de7465babc42ea46291206f DE-627 ger DE-627 rakwb eng Dechao Zhang verfasserin aut In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs. dendrite‐free interface construction long lifespan solid electrolyte interface solid‐state lithium metal batteries Science Q Zhengbo Liu verfasserin aut Yiwen Wu verfasserin aut Shaomin Ji verfasserin aut Zhanxiang Yuan verfasserin aut Jun Liu verfasserin aut Min Zhu verfasserin aut In Advanced Science Wiley, 2015 9(2022), 12, Seite n/a-n/a (DE-627)817357777 (DE-600)2808093-2 21983844 nnns volume:9 year:2022 number:12 pages:n/a-n/a https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/article/d231c6922de7465babc42ea46291206f kostenfrei https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/toc/2198-3844 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2022 12 n/a-n/a
allfieldsGer	10.1002/advs.202104277 doi (DE-627)DOAJ029721830 (DE-599)DOAJd231c6922de7465babc42ea46291206f DE-627 ger DE-627 rakwb eng Dechao Zhang verfasserin aut In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs. dendrite‐free interface construction long lifespan solid electrolyte interface solid‐state lithium metal batteries Science Q Zhengbo Liu verfasserin aut Yiwen Wu verfasserin aut Shaomin Ji verfasserin aut Zhanxiang Yuan verfasserin aut Jun Liu verfasserin aut Min Zhu verfasserin aut In Advanced Science Wiley, 2015 9(2022), 12, Seite n/a-n/a (DE-627)817357777 (DE-600)2808093-2 21983844 nnns volume:9 year:2022 number:12 pages:n/a-n/a https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/article/d231c6922de7465babc42ea46291206f kostenfrei https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/toc/2198-3844 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2022 12 n/a-n/a
allfieldsSound	10.1002/advs.202104277 doi (DE-627)DOAJ029721830 (DE-599)DOAJd231c6922de7465babc42ea46291206f DE-627 ger DE-627 rakwb eng Dechao Zhang verfasserin aut In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs. dendrite‐free interface construction long lifespan solid electrolyte interface solid‐state lithium metal batteries Science Q Zhengbo Liu verfasserin aut Yiwen Wu verfasserin aut Shaomin Ji verfasserin aut Zhanxiang Yuan verfasserin aut Jun Liu verfasserin aut Min Zhu verfasserin aut In Advanced Science Wiley, 2015 9(2022), 12, Seite n/a-n/a (DE-627)817357777 (DE-600)2808093-2 21983844 nnns volume:9 year:2022 number:12 pages:n/a-n/a https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/article/d231c6922de7465babc42ea46291206f kostenfrei https://doi.org/10.1002/advs.202104277 kostenfrei https://doaj.org/toc/2198-3844 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2022 12 n/a-n/a
language	English
source	In Advanced Science 9(2022), 12, Seite n/a-n/a volume:9 year:2022 number:12 pages:n/a-n/a
sourceStr	In Advanced Science 9(2022), 12, Seite n/a-n/a volume:9 year:2022 number:12 pages:n/a-n/a
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	dendrite‐free interface construction long lifespan solid electrolyte interface solid‐state lithium metal batteries Science Q
isfreeaccess_bool	true
container_title	Advanced Science
authorswithroles_txt_mv	Dechao Zhang @@aut@@ Zhengbo Liu @@aut@@ Yiwen Wu @@aut@@ Shaomin Ji @@aut@@ Zhanxiang Yuan @@aut@@ Jun Liu @@aut@@ Min Zhu @@aut@@
publishDateDaySort_date	2022-01-01T00:00:00Z
hierarchy_top_id	817357777
id	DOAJ029721830
language_de	englisch
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author	Dechao Zhang
spellingShingle	Dechao Zhang misc dendrite‐free misc interface construction misc long lifespan misc solid electrolyte interface misc solid‐state lithium metal batteries misc Science misc Q In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries
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topic_title	In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries dendrite‐free interface construction long lifespan solid electrolyte interface solid‐state lithium metal batteries
topic	misc dendrite‐free misc interface construction misc long lifespan misc solid electrolyte interface misc solid‐state lithium metal batteries misc Science misc Q
topic_unstemmed	misc dendrite‐free misc interface construction misc long lifespan misc solid electrolyte interface misc solid‐state lithium metal batteries misc Science misc Q
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title	In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries
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title_full	In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries
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author_browse	Dechao Zhang Zhengbo Liu Yiwen Wu Shaomin Ji Zhanxiang Yuan Jun Liu Min Zhu
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author-letter	Dechao Zhang
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title_sort	in situ construction a stable protective layer in polymer electrolyte for ultralong lifespan solid‐state lithium metal batteries
title_auth	In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries
abstract	Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs.
abstractGer	Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs.
abstract_unstemmed	Abstract Solid‐state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs.
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title_short	In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid‐State Lithium Metal Batteries
url	https://doi.org/10.1002/advs.202104277 https://doaj.org/article/d231c6922de7465babc42ea46291206f https://doaj.org/toc/2198-3844
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However, the alkali lithium with high reducibility can react with the solid‐state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time‐of‐flight secondary ion mass spectrometry and X‐ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong‐term for over 4500 h. Moreover, the as‐prepared LiFePO4/Li SLMBs exhibit an impressive ultra‐long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. 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