Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity

Nanoscale FeS2 was synthesized via a simple hydrothermal method and was decorated by hydrothermal carbonization (FeS2C). The structural properties of the synthesized materials detected by X-ray diffraction (XRD), together with the morphologies characterized by scanning electron microscopy (SEM) and...
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Autor*in:	Shengping Wang [verfasserIn] Jingxian Yu [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2016

Schlagwörter:	composites electrochemical measurements electrochemical properties

Übergeordnetes Werk:	In: Energies - MDPI AG, 2008, 9(2016), 4, p 225
Übergeordnetes Werk:	volume:9 ; year:2016 ; number:4, p 225

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DOI / URN:	10.3390/en9040225

Katalog-ID:	DOAJ030061962

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spelling	10.3390/en9040225 doi (DE-627)DOAJ030061962 (DE-599)DOAJd990f00a620a40d28166bf1926146135 DE-627 ger DE-627 rakwb eng Shengping Wang verfasserin aut Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nanoscale FeS2 was synthesized via a simple hydrothermal method and was decorated by hydrothermal carbonization (FeS2C). The structural properties of the synthesized materials detected by X-ray diffraction (XRD), together with the morphologies characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the hydrothermal carbonization only had an impact on the morphology of pyrite. Additionally, the electrochemical performance of the coated pyrite in Li/FeS2 batteries was evaluated by galvanostatic discharge-charge tests and electrochemical impedance spectroscopy (EIS). The results showed that the initial capacity of FeS2@C was 799.2 mAh·g−1 (90% of theoretical capacity of FeS2) and that of uncoated FeS2 was only 574.6 mAh·g−1. XRD and ultraviolet (UV) visible spectroscopy results at different depths of discharge-charge for FeS2 were discussed to clarify the electrochemical mechanism, which play an important part in Li/FeS2 batteries. composites electrochemical measurements electrochemical properties Technology T Jingxian Yu verfasserin aut In Energies MDPI AG, 2008 9(2016), 4, p 225 (DE-627)572083742 (DE-600)2437446-5 19961073 nnns volume:9 year:2016 number:4, p 225 https://doi.org/10.3390/en9040225 kostenfrei https://doaj.org/article/d990f00a620a40d28166bf1926146135 kostenfrei http://www.mdpi.com/1996-1073/9/4/225 kostenfrei https://doaj.org/toc/1996-1073 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2016 4, p 225
allfields_unstemmed	10.3390/en9040225 doi (DE-627)DOAJ030061962 (DE-599)DOAJd990f00a620a40d28166bf1926146135 DE-627 ger DE-627 rakwb eng Shengping Wang verfasserin aut Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nanoscale FeS2 was synthesized via a simple hydrothermal method and was decorated by hydrothermal carbonization (FeS2C). The structural properties of the synthesized materials detected by X-ray diffraction (XRD), together with the morphologies characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the hydrothermal carbonization only had an impact on the morphology of pyrite. Additionally, the electrochemical performance of the coated pyrite in Li/FeS2 batteries was evaluated by galvanostatic discharge-charge tests and electrochemical impedance spectroscopy (EIS). The results showed that the initial capacity of FeS2@C was 799.2 mAh·g−1 (90% of theoretical capacity of FeS2) and that of uncoated FeS2 was only 574.6 mAh·g−1. XRD and ultraviolet (UV) visible spectroscopy results at different depths of discharge-charge for FeS2 were discussed to clarify the electrochemical mechanism, which play an important part in Li/FeS2 batteries. composites electrochemical measurements electrochemical properties Technology T Jingxian Yu verfasserin aut In Energies MDPI AG, 2008 9(2016), 4, p 225 (DE-627)572083742 (DE-600)2437446-5 19961073 nnns volume:9 year:2016 number:4, p 225 https://doi.org/10.3390/en9040225 kostenfrei https://doaj.org/article/d990f00a620a40d28166bf1926146135 kostenfrei http://www.mdpi.com/1996-1073/9/4/225 kostenfrei https://doaj.org/toc/1996-1073 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2016 4, p 225
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author	Shengping Wang
spellingShingle	Shengping Wang misc composites misc electrochemical measurements misc electrochemical properties misc Technology misc T Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity
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topic_title	Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity composites electrochemical measurements electrochemical properties
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title	Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity
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title_full	Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity
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title_sort	electrochemical mechanism for fes2/c composite in lithium ion batteries with enhanced reversible capacity
title_auth	Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity
abstract	Nanoscale FeS2 was synthesized via a simple hydrothermal method and was decorated by hydrothermal carbonization (FeS2C). The structural properties of the synthesized materials detected by X-ray diffraction (XRD), together with the morphologies characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the hydrothermal carbonization only had an impact on the morphology of pyrite. Additionally, the electrochemical performance of the coated pyrite in Li/FeS2 batteries was evaluated by galvanostatic discharge-charge tests and electrochemical impedance spectroscopy (EIS). The results showed that the initial capacity of FeS2@C was 799.2 mAh·g−1 (90% of theoretical capacity of FeS2) and that of uncoated FeS2 was only 574.6 mAh·g−1. XRD and ultraviolet (UV) visible spectroscopy results at different depths of discharge-charge for FeS2 were discussed to clarify the electrochemical mechanism, which play an important part in Li/FeS2 batteries.
abstractGer	Nanoscale FeS2 was synthesized via a simple hydrothermal method and was decorated by hydrothermal carbonization (FeS2C). The structural properties of the synthesized materials detected by X-ray diffraction (XRD), together with the morphologies characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the hydrothermal carbonization only had an impact on the morphology of pyrite. Additionally, the electrochemical performance of the coated pyrite in Li/FeS2 batteries was evaluated by galvanostatic discharge-charge tests and electrochemical impedance spectroscopy (EIS). The results showed that the initial capacity of FeS2@C was 799.2 mAh·g−1 (90% of theoretical capacity of FeS2) and that of uncoated FeS2 was only 574.6 mAh·g−1. XRD and ultraviolet (UV) visible spectroscopy results at different depths of discharge-charge for FeS2 were discussed to clarify the electrochemical mechanism, which play an important part in Li/FeS2 batteries.
abstract_unstemmed	Nanoscale FeS2 was synthesized via a simple hydrothermal method and was decorated by hydrothermal carbonization (FeS2C). The structural properties of the synthesized materials detected by X-ray diffraction (XRD), together with the morphologies characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the hydrothermal carbonization only had an impact on the morphology of pyrite. Additionally, the electrochemical performance of the coated pyrite in Li/FeS2 batteries was evaluated by galvanostatic discharge-charge tests and electrochemical impedance spectroscopy (EIS). The results showed that the initial capacity of FeS2@C was 799.2 mAh·g−1 (90% of theoretical capacity of FeS2) and that of uncoated FeS2 was only 574.6 mAh·g−1. XRD and ultraviolet (UV) visible spectroscopy results at different depths of discharge-charge for FeS2 were discussed to clarify the electrochemical mechanism, which play an important part in Li/FeS2 batteries.
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title_short	Electrochemical Mechanism for FeS2/C Composite in Lithium Ion Batteries with Enhanced Reversible Capacity
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