Thermal Safety Evaluation of Silane Polymer Compounds as Electrolyte Additives for Silicon-Based Anode Lithium-Ion Batteries

The capacity fading and thermal safety issues caused by the volume effect of Si-based anodes and unstable solid electrolyte interphase (SEI) films during long-term cycling limit its large-scale application. In this study, silane polymer compound (2-cyanoethyl) triethoxysilane (TCN) was selected as a...
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Autor*in:	Chuan-Zhu Zhang [verfasserIn] Lin-Jie Xie [verfasserIn] Yan Tang [verfasserIn] You Li [verfasserIn] Jun-Cheng Jiang [verfasserIn] An-Chi Huang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	silicon-based anode thermogravimetric analyzer thermokinetic model electrolyte additive lithium-ion battery

Übergeordnetes Werk:	In: Processes - MDPI AG, 2013, 10(2022), 1581, p 1581
Übergeordnetes Werk:	volume:10 ; year:2022 ; number:1581, p 1581

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/pr10081581

Katalog-ID:	DOAJ036297550

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callnumber-first	T - Technology
author	Chuan-Zhu Zhang
spellingShingle	Chuan-Zhu Zhang misc TP1-1185 misc QD1-999 misc silicon-based anode misc thermogravimetric analyzer misc thermokinetic model misc electrolyte additive misc lithium-ion battery misc Chemical technology misc Chemistry Thermal Safety Evaluation of Silane Polymer Compounds as Electrolyte Additives for Silicon-Based Anode Lithium-Ion Batteries
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topic_title	TP1-1185 QD1-999 Thermal Safety Evaluation of Silane Polymer Compounds as Electrolyte Additives for Silicon-Based Anode Lithium-Ion Batteries silicon-based anode thermogravimetric analyzer thermokinetic model electrolyte additive lithium-ion battery
topic	misc TP1-1185 misc QD1-999 misc silicon-based anode misc thermogravimetric analyzer misc thermokinetic model misc electrolyte additive misc lithium-ion battery misc Chemical technology misc Chemistry
topic_unstemmed	misc TP1-1185 misc QD1-999 misc silicon-based anode misc thermogravimetric analyzer misc thermokinetic model misc electrolyte additive misc lithium-ion battery misc Chemical technology misc Chemistry
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title	Thermal Safety Evaluation of Silane Polymer Compounds as Electrolyte Additives for Silicon-Based Anode Lithium-Ion Batteries
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title_full	Thermal Safety Evaluation of Silane Polymer Compounds as Electrolyte Additives for Silicon-Based Anode Lithium-Ion Batteries
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author_browse	Chuan-Zhu Zhang Lin-Jie Xie Yan Tang You Li Jun-Cheng Jiang An-Chi Huang
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title_sort	thermal safety evaluation of silane polymer compounds as electrolyte additives for silicon-based anode lithium-ion batteries
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title_auth	Thermal Safety Evaluation of Silane Polymer Compounds as Electrolyte Additives for Silicon-Based Anode Lithium-Ion Batteries
abstract	The capacity fading and thermal safety issues caused by the volume effect of Si-based anodes and unstable solid electrolyte interphase (SEI) films during long-term cycling limit its large-scale application. In this study, silane polymer compound (2-cyanoethyl) triethoxysilane (TCN) was selected as an electrolyte additive to improve the reversibility and thermal safety of Si-based anode lithium-ion batteries (LIBs). TCN prevented the thermal interaction between the vitiated anode and electrolyte, and the onset temperature of the thermal reaction increased from 122.22 to 127.07 °C, as demonstrated by the results of thermogravimetric analysis and differential scanning calorimetry. The thermal stability of lithiated anodes containing various electrolytes was then assessed using a range of thermo-kinetic models. The results revealed that the activation energy of Si-based lithiated anodes increased from 68.46 to 91.32 kJ/mol, while the thermal hazard greatly decreased. Additionally, the electrochemical test and characterization results showed that TCN helped generate a stable SEI coating with more Li<sub<2</sub<CO<sub<3</sub< components, which improved the cells’ cycle stability. This study provides a new reference for the growth of LIBs with high security and energy density.
abstractGer	The capacity fading and thermal safety issues caused by the volume effect of Si-based anodes and unstable solid electrolyte interphase (SEI) films during long-term cycling limit its large-scale application. In this study, silane polymer compound (2-cyanoethyl) triethoxysilane (TCN) was selected as an electrolyte additive to improve the reversibility and thermal safety of Si-based anode lithium-ion batteries (LIBs). TCN prevented the thermal interaction between the vitiated anode and electrolyte, and the onset temperature of the thermal reaction increased from 122.22 to 127.07 °C, as demonstrated by the results of thermogravimetric analysis and differential scanning calorimetry. The thermal stability of lithiated anodes containing various electrolytes was then assessed using a range of thermo-kinetic models. The results revealed that the activation energy of Si-based lithiated anodes increased from 68.46 to 91.32 kJ/mol, while the thermal hazard greatly decreased. Additionally, the electrochemical test and characterization results showed that TCN helped generate a stable SEI coating with more Li<sub<2</sub<CO<sub<3</sub< components, which improved the cells’ cycle stability. This study provides a new reference for the growth of LIBs with high security and energy density.
abstract_unstemmed	The capacity fading and thermal safety issues caused by the volume effect of Si-based anodes and unstable solid electrolyte interphase (SEI) films during long-term cycling limit its large-scale application. In this study, silane polymer compound (2-cyanoethyl) triethoxysilane (TCN) was selected as an electrolyte additive to improve the reversibility and thermal safety of Si-based anode lithium-ion batteries (LIBs). TCN prevented the thermal interaction between the vitiated anode and electrolyte, and the onset temperature of the thermal reaction increased from 122.22 to 127.07 °C, as demonstrated by the results of thermogravimetric analysis and differential scanning calorimetry. The thermal stability of lithiated anodes containing various electrolytes was then assessed using a range of thermo-kinetic models. The results revealed that the activation energy of Si-based lithiated anodes increased from 68.46 to 91.32 kJ/mol, while the thermal hazard greatly decreased. Additionally, the electrochemical test and characterization results showed that TCN helped generate a stable SEI coating with more Li<sub<2</sub<CO<sub<3</sub< components, which improved the cells’ cycle stability. This study provides a new reference for the growth of LIBs with high security and energy density.
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title_short	Thermal Safety Evaluation of Silane Polymer Compounds as Electrolyte Additives for Silicon-Based Anode Lithium-Ion Batteries
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Thermal Safety Evaluation of Silane Polymer Compounds as Electrolyte Additives for Silicon-Based Anode Lithium-Ion Batteries

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