Novel negatively-charged membrane adsorbers made using combination of photopolymerization and immersion precipitation
A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl meth...
Ausführliche Beschreibung
Autor*in: |
Tomković Tanja [verfasserIn] Radovanović Filip [verfasserIn] Grgur Branimir [verfasserIn] Nastasović Aleksandra [verfasserIn] Vasiljević-Radović Dana [verfasserIn] Onjia Antonije [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2016 |
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Übergeordnetes Werk: |
In: Journal of the Serbian Chemical Society - Serbian Chemical Society, 2017, 81(2016), 4, Seite 419-431 |
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Übergeordnetes Werk: |
volume:81 ; year:2016 ; number:4 ; pages:419-431 |
Links: |
Link aufrufen |
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DOI / URN: |
10.2298/JSC150805083T |
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Katalog-ID: |
DOAJ039145220 |
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10.2298/JSC150805083T doi (DE-627)DOAJ039145220 (DE-599)DOAJ5f96250f0db649a3878774b0e13aab8d DE-627 ger DE-627 rakwb eng QD1-999 Tomković Tanja verfasserin aut Novel negatively-charged membrane adsorbers made using combination of photopolymerization and immersion precipitation 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second method was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of membrane. Dynamic adsorption of Rhodamine B as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for both functionalized membrane with sodium sulfite and grafted membrane with 2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III 43009] membrane formation grafting sulfonic acid epoxide opening polyethersulfone glycidyl methacrylate Chemistry Radovanović Filip verfasserin aut Grgur Branimir verfasserin aut Nastasović Aleksandra verfasserin aut Vasiljević-Radović Dana verfasserin aut Onjia Antonije verfasserin aut In Journal of the Serbian Chemical Society Serbian Chemical Society, 2017 81(2016), 4, Seite 419-431 (DE-627)324742363 (DE-600)2030173-X 18207421 nnns volume:81 year:2016 number:4 pages:419-431 https://doi.org/10.2298/JSC150805083T kostenfrei https://doaj.org/article/5f96250f0db649a3878774b0e13aab8d kostenfrei http://www.doiserbia.nb.rs/img/doi/0352-5139/2016/0352-51391500083T.pdf kostenfrei https://doaj.org/toc/0352-5139 Journal toc kostenfrei https://doaj.org/toc/1820-7421 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 81 2016 4 419-431 |
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10.2298/JSC150805083T doi (DE-627)DOAJ039145220 (DE-599)DOAJ5f96250f0db649a3878774b0e13aab8d DE-627 ger DE-627 rakwb eng QD1-999 Tomković Tanja verfasserin aut Novel negatively-charged membrane adsorbers made using combination of photopolymerization and immersion precipitation 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second method was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of membrane. Dynamic adsorption of Rhodamine B as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for both functionalized membrane with sodium sulfite and grafted membrane with 2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III 43009] membrane formation grafting sulfonic acid epoxide opening polyethersulfone glycidyl methacrylate Chemistry Radovanović Filip verfasserin aut Grgur Branimir verfasserin aut Nastasović Aleksandra verfasserin aut Vasiljević-Radović Dana verfasserin aut Onjia Antonije verfasserin aut In Journal of the Serbian Chemical Society Serbian Chemical Society, 2017 81(2016), 4, Seite 419-431 (DE-627)324742363 (DE-600)2030173-X 18207421 nnns volume:81 year:2016 number:4 pages:419-431 https://doi.org/10.2298/JSC150805083T kostenfrei https://doaj.org/article/5f96250f0db649a3878774b0e13aab8d kostenfrei http://www.doiserbia.nb.rs/img/doi/0352-5139/2016/0352-51391500083T.pdf kostenfrei https://doaj.org/toc/0352-5139 Journal toc kostenfrei https://doaj.org/toc/1820-7421 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 81 2016 4 419-431 |
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10.2298/JSC150805083T doi (DE-627)DOAJ039145220 (DE-599)DOAJ5f96250f0db649a3878774b0e13aab8d DE-627 ger DE-627 rakwb eng QD1-999 Tomković Tanja verfasserin aut Novel negatively-charged membrane adsorbers made using combination of photopolymerization and immersion precipitation 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second method was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of membrane. Dynamic adsorption of Rhodamine B as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for both functionalized membrane with sodium sulfite and grafted membrane with 2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III 43009] membrane formation grafting sulfonic acid epoxide opening polyethersulfone glycidyl methacrylate Chemistry Radovanović Filip verfasserin aut Grgur Branimir verfasserin aut Nastasović Aleksandra verfasserin aut Vasiljević-Radović Dana verfasserin aut Onjia Antonije verfasserin aut In Journal of the Serbian Chemical Society Serbian Chemical Society, 2017 81(2016), 4, Seite 419-431 (DE-627)324742363 (DE-600)2030173-X 18207421 nnns volume:81 year:2016 number:4 pages:419-431 https://doi.org/10.2298/JSC150805083T kostenfrei https://doaj.org/article/5f96250f0db649a3878774b0e13aab8d kostenfrei http://www.doiserbia.nb.rs/img/doi/0352-5139/2016/0352-51391500083T.pdf kostenfrei https://doaj.org/toc/0352-5139 Journal toc kostenfrei https://doaj.org/toc/1820-7421 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 81 2016 4 419-431 |
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10.2298/JSC150805083T doi (DE-627)DOAJ039145220 (DE-599)DOAJ5f96250f0db649a3878774b0e13aab8d DE-627 ger DE-627 rakwb eng QD1-999 Tomković Tanja verfasserin aut Novel negatively-charged membrane adsorbers made using combination of photopolymerization and immersion precipitation 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second method was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of membrane. Dynamic adsorption of Rhodamine B as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for both functionalized membrane with sodium sulfite and grafted membrane with 2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III 43009] membrane formation grafting sulfonic acid epoxide opening polyethersulfone glycidyl methacrylate Chemistry Radovanović Filip verfasserin aut Grgur Branimir verfasserin aut Nastasović Aleksandra verfasserin aut Vasiljević-Radović Dana verfasserin aut Onjia Antonije verfasserin aut In Journal of the Serbian Chemical Society Serbian Chemical Society, 2017 81(2016), 4, Seite 419-431 (DE-627)324742363 (DE-600)2030173-X 18207421 nnns volume:81 year:2016 number:4 pages:419-431 https://doi.org/10.2298/JSC150805083T kostenfrei https://doaj.org/article/5f96250f0db649a3878774b0e13aab8d kostenfrei http://www.doiserbia.nb.rs/img/doi/0352-5139/2016/0352-51391500083T.pdf kostenfrei https://doaj.org/toc/0352-5139 Journal toc kostenfrei https://doaj.org/toc/1820-7421 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 81 2016 4 419-431 |
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10.2298/JSC150805083T doi (DE-627)DOAJ039145220 (DE-599)DOAJ5f96250f0db649a3878774b0e13aab8d DE-627 ger DE-627 rakwb eng QD1-999 Tomković Tanja verfasserin aut Novel negatively-charged membrane adsorbers made using combination of photopolymerization and immersion precipitation 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second method was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of membrane. Dynamic adsorption of Rhodamine B as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for both functionalized membrane with sodium sulfite and grafted membrane with 2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III 43009] membrane formation grafting sulfonic acid epoxide opening polyethersulfone glycidyl methacrylate Chemistry Radovanović Filip verfasserin aut Grgur Branimir verfasserin aut Nastasović Aleksandra verfasserin aut Vasiljević-Radović Dana verfasserin aut Onjia Antonije verfasserin aut In Journal of the Serbian Chemical Society Serbian Chemical Society, 2017 81(2016), 4, Seite 419-431 (DE-627)324742363 (DE-600)2030173-X 18207421 nnns volume:81 year:2016 number:4 pages:419-431 https://doi.org/10.2298/JSC150805083T kostenfrei https://doaj.org/article/5f96250f0db649a3878774b0e13aab8d kostenfrei http://www.doiserbia.nb.rs/img/doi/0352-5139/2016/0352-51391500083T.pdf kostenfrei https://doaj.org/toc/0352-5139 Journal toc kostenfrei https://doaj.org/toc/1820-7421 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2027 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 81 2016 4 419-431 |
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Novel negatively-charged membrane adsorbers made using combination of photopolymerization and immersion precipitation |
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A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second method was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of membrane. Dynamic adsorption of Rhodamine B as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for both functionalized membrane with sodium sulfite and grafted membrane with 2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III 43009] |
abstractGer |
A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second method was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of membrane. Dynamic adsorption of Rhodamine B as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for both functionalized membrane with sodium sulfite and grafted membrane with 2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III 43009] |
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A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second method was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropane sulfonic acid. Obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of membrane. Dynamic adsorption of Rhodamine B as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for both functionalized membrane with sodium sulfite and grafted membrane with 2-acrylamido-2-methylpropane sulfonic acid compared to the nonfunctionalized membrane. [Projekat Ministarstva nauke Republike Srbije, br. TR32008 and III 43009] |
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