Oxidative Degradations of the Side Chain of Unsaturated Ent-labdanes. Part I.
A selective route for the degradation of the unsaturated side chain of ent-labdanes has been devised, giving two useful synthons: 2β-acetoxy-14,15,17-trinor-ent-labdane-8,13- dione (5) and 2β-acetoxy-14,15-dinor-ent-labd-8(17)-en-13-one (7), the use of which for the preparation of terpenylquin...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Karen Catalán MarÃÂn [verfasserIn] Claudio Gallardo Araya [verfasserIn] Mauricio Cuellar Fritis [verfasserIn] Héctor Carrasco Altamirano [verfasserIn] Luis Espinoza Catalán [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2007 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
In: Molecules - MDPI AG, 2003, 12(2007), 3, Seite 318-327 |
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| Übergeordnetes Werk: |
volume:12 ; year:2007 ; number:3 ; pages:318-327 |
| Links: |
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| DOI / URN: |
10.3390/12030318 |
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| Katalog-ID: |
DOAJ043238734 |
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Oxidative Degradations of the Side Chain of Unsaturated Ent-labdanes. Part I. |
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A selective route for the degradation of the unsaturated side chain of ent-labdanes has been devised, giving two useful synthons: 2β-acetoxy-14,15,17-trinor-ent-labdane-8,13- dione (5) and 2β-acetoxy-14,15-dinor-ent-labd-8(17)-en-13-one (7), the use of which for the preparation of terpenylquinone derivatives shall be reported elsewhere. |
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A selective route for the degradation of the unsaturated side chain of ent-labdanes has been devised, giving two useful synthons: 2β-acetoxy-14,15,17-trinor-ent-labdane-8,13- dione (5) and 2β-acetoxy-14,15-dinor-ent-labd-8(17)-en-13-one (7), the use of which for the preparation of terpenylquinone derivatives shall be reported elsewhere. |
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A selective route for the degradation of the unsaturated side chain of ent-labdanes has been devised, giving two useful synthons: 2β-acetoxy-14,15,17-trinor-ent-labdane-8,13- dione (5) and 2β-acetoxy-14,15-dinor-ent-labd-8(17)-en-13-one (7), the use of which for the preparation of terpenylquinone derivatives shall be reported elsewhere. |
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