Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell

Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functio...
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Autor*in:	Grayson S. Doucette [verfasserIn] Haw-Tyng Huang [verfasserIn] Jason M. Munro [verfasserIn] Kyle T. Munson [verfasserIn] Changyong Park [verfasserIn] John E. Anthony [verfasserIn] Timothy Strobel [verfasserIn] Ismaila Dabo [verfasserIn] John V. Badding [verfasserIn] John B. Asbury [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2020

Schlagwörter:	Singlet Fission Intermolecular Coupling Triplet Pair Separation High-Pressure Ultrafast Spectroscopy Pentacene

Übergeordnetes Werk:	In: Cell Reports Physical Science - Elsevier, 2020, 1(2020), 1, Seite 100005-
Übergeordnetes Werk:	volume:1 ; year:2020 ; number:1 ; pages:100005-

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1016/j.xcrp.2019.100005

Katalog-ID:	DOAJ043704077

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520			\|a Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers.
650		4	\|a Singlet Fission
650		4	\|a Intermolecular Coupling
650		4	\|a Triplet Pair Separation
650		4	\|a High-Pressure
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700	0		\|a John B. Asbury \|e verfasserin \|4 aut
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allfields	10.1016/j.xcrp.2019.100005 doi (DE-627)DOAJ043704077 (DE-599)DOAJ0a6e4f0c5abb4d77889b92f9822425f7 DE-627 ger DE-627 rakwb eng QC1-999 Grayson S. Doucette verfasserin aut Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers. Singlet Fission Intermolecular Coupling Triplet Pair Separation High-Pressure Ultrafast Spectroscopy Pentacene Physics Haw-Tyng Huang verfasserin aut Jason M. Munro verfasserin aut Kyle T. Munson verfasserin aut Changyong Park verfasserin aut John E. Anthony verfasserin aut Timothy Strobel verfasserin aut Ismaila Dabo verfasserin aut John V. Badding verfasserin aut John B. Asbury verfasserin aut In Cell Reports Physical Science Elsevier, 2020 1(2020), 1, Seite 100005- (DE-627)1694210766 26663864 nnns volume:1 year:2020 number:1 pages:100005- https://doi.org/10.1016/j.xcrp.2019.100005 kostenfrei https://doaj.org/article/0a6e4f0c5abb4d77889b92f9822425f7 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666386419300062 kostenfrei https://doaj.org/toc/2666-3864 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2020 1 100005-
spelling	10.1016/j.xcrp.2019.100005 doi (DE-627)DOAJ043704077 (DE-599)DOAJ0a6e4f0c5abb4d77889b92f9822425f7 DE-627 ger DE-627 rakwb eng QC1-999 Grayson S. Doucette verfasserin aut Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers. Singlet Fission Intermolecular Coupling Triplet Pair Separation High-Pressure Ultrafast Spectroscopy Pentacene Physics Haw-Tyng Huang verfasserin aut Jason M. Munro verfasserin aut Kyle T. Munson verfasserin aut Changyong Park verfasserin aut John E. Anthony verfasserin aut Timothy Strobel verfasserin aut Ismaila Dabo verfasserin aut John V. Badding verfasserin aut John B. Asbury verfasserin aut In Cell Reports Physical Science Elsevier, 2020 1(2020), 1, Seite 100005- (DE-627)1694210766 26663864 nnns volume:1 year:2020 number:1 pages:100005- https://doi.org/10.1016/j.xcrp.2019.100005 kostenfrei https://doaj.org/article/0a6e4f0c5abb4d77889b92f9822425f7 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666386419300062 kostenfrei https://doaj.org/toc/2666-3864 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2020 1 100005-
allfields_unstemmed	10.1016/j.xcrp.2019.100005 doi (DE-627)DOAJ043704077 (DE-599)DOAJ0a6e4f0c5abb4d77889b92f9822425f7 DE-627 ger DE-627 rakwb eng QC1-999 Grayson S. Doucette verfasserin aut Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers. Singlet Fission Intermolecular Coupling Triplet Pair Separation High-Pressure Ultrafast Spectroscopy Pentacene Physics Haw-Tyng Huang verfasserin aut Jason M. Munro verfasserin aut Kyle T. Munson verfasserin aut Changyong Park verfasserin aut John E. Anthony verfasserin aut Timothy Strobel verfasserin aut Ismaila Dabo verfasserin aut John V. Badding verfasserin aut John B. Asbury verfasserin aut In Cell Reports Physical Science Elsevier, 2020 1(2020), 1, Seite 100005- (DE-627)1694210766 26663864 nnns volume:1 year:2020 number:1 pages:100005- https://doi.org/10.1016/j.xcrp.2019.100005 kostenfrei https://doaj.org/article/0a6e4f0c5abb4d77889b92f9822425f7 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666386419300062 kostenfrei https://doaj.org/toc/2666-3864 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2020 1 100005-
allfieldsGer	10.1016/j.xcrp.2019.100005 doi (DE-627)DOAJ043704077 (DE-599)DOAJ0a6e4f0c5abb4d77889b92f9822425f7 DE-627 ger DE-627 rakwb eng QC1-999 Grayson S. Doucette verfasserin aut Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers. Singlet Fission Intermolecular Coupling Triplet Pair Separation High-Pressure Ultrafast Spectroscopy Pentacene Physics Haw-Tyng Huang verfasserin aut Jason M. Munro verfasserin aut Kyle T. Munson verfasserin aut Changyong Park verfasserin aut John E. Anthony verfasserin aut Timothy Strobel verfasserin aut Ismaila Dabo verfasserin aut John V. Badding verfasserin aut John B. Asbury verfasserin aut In Cell Reports Physical Science Elsevier, 2020 1(2020), 1, Seite 100005- (DE-627)1694210766 26663864 nnns volume:1 year:2020 number:1 pages:100005- https://doi.org/10.1016/j.xcrp.2019.100005 kostenfrei https://doaj.org/article/0a6e4f0c5abb4d77889b92f9822425f7 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666386419300062 kostenfrei https://doaj.org/toc/2666-3864 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2020 1 100005-
allfieldsSound	10.1016/j.xcrp.2019.100005 doi (DE-627)DOAJ043704077 (DE-599)DOAJ0a6e4f0c5abb4d77889b92f9822425f7 DE-627 ger DE-627 rakwb eng QC1-999 Grayson S. Doucette verfasserin aut Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell 2020 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers. Singlet Fission Intermolecular Coupling Triplet Pair Separation High-Pressure Ultrafast Spectroscopy Pentacene Physics Haw-Tyng Huang verfasserin aut Jason M. Munro verfasserin aut Kyle T. Munson verfasserin aut Changyong Park verfasserin aut John E. Anthony verfasserin aut Timothy Strobel verfasserin aut Ismaila Dabo verfasserin aut John V. Badding verfasserin aut John B. Asbury verfasserin aut In Cell Reports Physical Science Elsevier, 2020 1(2020), 1, Seite 100005- (DE-627)1694210766 26663864 nnns volume:1 year:2020 number:1 pages:100005- https://doi.org/10.1016/j.xcrp.2019.100005 kostenfrei https://doaj.org/article/0a6e4f0c5abb4d77889b92f9822425f7 kostenfrei http://www.sciencedirect.com/science/article/pii/S2666386419300062 kostenfrei https://doaj.org/toc/2666-3864 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2110 GBV_ILN_2112 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 AR 1 2020 1 100005-
language	English
source	In Cell Reports Physical Science 1(2020), 1, Seite 100005- volume:1 year:2020 number:1 pages:100005-
sourceStr	In Cell Reports Physical Science 1(2020), 1, Seite 100005- volume:1 year:2020 number:1 pages:100005-
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Singlet Fission Intermolecular Coupling Triplet Pair Separation High-Pressure Ultrafast Spectroscopy Pentacene Physics
isfreeaccess_bool	true
container_title	Cell Reports Physical Science
authorswithroles_txt_mv	Grayson S. Doucette @@aut@@ Haw-Tyng Huang @@aut@@ Jason M. Munro @@aut@@ Kyle T. Munson @@aut@@ Changyong Park @@aut@@ John E. Anthony @@aut@@ Timothy Strobel @@aut@@ Ismaila Dabo @@aut@@ John V. Badding @@aut@@ John B. Asbury @@aut@@
publishDateDaySort_date	2020-01-01T00:00:00Z
hierarchy_top_id	1694210766
id	DOAJ043704077
language_de	englisch
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callnumber-first	Q - Science
author	Grayson S. Doucette
spellingShingle	Grayson S. Doucette misc QC1-999 misc Singlet Fission misc Intermolecular Coupling misc Triplet Pair Separation misc High-Pressure misc Ultrafast Spectroscopy misc Pentacene misc Physics Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell
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topic_title	QC1-999 Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell Singlet Fission Intermolecular Coupling Triplet Pair Separation High-Pressure Ultrafast Spectroscopy Pentacene
topic	misc QC1-999 misc Singlet Fission misc Intermolecular Coupling misc Triplet Pair Separation misc High-Pressure misc Ultrafast Spectroscopy misc Pentacene misc Physics
topic_unstemmed	misc QC1-999 misc Singlet Fission misc Intermolecular Coupling misc Triplet Pair Separation misc High-Pressure misc Ultrafast Spectroscopy misc Pentacene misc Physics
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title	Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell
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title_full	Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell
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title_sort	tuning triplet-pair separation versus relaxation using a diamond anvil cell
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title_auth	Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell
abstract	Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers.
abstractGer	Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers.
abstract_unstemmed	Summary: A tradeoff exists between triplet-pair separation versus relaxation that can limit the ability to utilize singlet fission for enhancing solar cell efficiency beyond the Shockley-Queisser limit. Here, we show that this tradeoff can be avoided in crystalline environments by studying a functionalized pentacene compressed in a diamond anvil cell. We demonstrate, using ultrafast transient absorption spectroscopy, that there is a “sweet spot” where the rate of triplet-pair separation can be accelerated by nearly an order of magnitude without causing fast excited state relaxation. X-ray diffraction and computational modeling allow us to quantify the corresponding increase of intermolecular coupling. Our findings suggest that increased coupling enhances excited state relaxation but that crystalline environments can suppress these relaxation processes in pentacene derivatives. The combination of these effects leads to the sweet spot and informs efforts to enhance triplet-pair separation rates in amorphous systems such as polymers.
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title_short	Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell
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Tuning Triplet-Pair Separation versus Relaxation Using a Diamond Anvil Cell

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