10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine

The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 ...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Satoru Umezono [verfasserIn] Tsunehisa Okuno [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	crystal structure enamine

Übergeordnetes Werk:	In: IUCrData - International Union of Crystallography, 2016, 3(2018), 2, p x180232
Übergeordnetes Werk:	volume:3 ; year:2018 ; number:2, p x180232

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1107/S2414314618002328

Katalog-ID:	DOAJ044089961

Internformat


LEADER	01000caa a22002652 4500
001	DOAJ044089961
003	DE-627
005	20230308075820.0
007	cr uuu---uuuuu
008	230227s2018 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1107/S2414314618002328 \|2 doi
035			\|a (DE-627)DOAJ044089961
035			\|a (DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
050		0	\|a QD901-999
100	0		\|a Satoru Umezono \|e verfasserin \|4 aut
245	1	0	\|a 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine
264		1	\|c 2018
336			\|a Text \|b txt \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.
650		4	\|a crystal structure
650		4	\|a enamine
653		0	\|a Crystallography
700	0		\|a Tsunehisa Okuno \|e verfasserin \|4 aut
773	0	8	\|i In \|t IUCrData \|d International Union of Crystallography, 2016 \|g 3(2018), 2, p x180232 \|w (DE-627)848322010 \|w (DE-600)2847714-5 \|x 24143146 \|7 nnns
773	1	8	\|g volume:3 \|g year:2018 \|g number:2, p x180232
856	4	0	\|u https://doi.org/10.1107/S2414314618002328 \|z kostenfrei
856	4	0	\|u https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b \|z kostenfrei
856	4	0	\|u http://scripts.iucr.org/cgi-bin/paper?S2414314618002328 \|z kostenfrei
856	4	2	\|u https://doaj.org/toc/2414-3146 \|y Journal toc \|z kostenfrei
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_DOAJ
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_95
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_151
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_213
912			\|a GBV_ILN_230
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4367
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 3 \|j 2018 \|e 2, p x180232

Indexfelder

author_variant	s u su t o to
matchkey_str	article:24143146:2018----::01ihootiehliybte3ny
hierarchy_sort_str	2018
callnumber-subject-code	QD
publishDate	2018
allfields	10.1107/S2414314618002328 doi (DE-627)DOAJ044089961 (DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b DE-627 ger DE-627 rakwb eng QD901-999 Satoru Umezono verfasserin aut 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units. crystal structure enamine Crystallography Tsunehisa Okuno verfasserin aut In IUCrData International Union of Crystallography, 2016 3(2018), 2, p x180232 (DE-627)848322010 (DE-600)2847714-5 24143146 nnns volume:3 year:2018 number:2, p x180232 https://doi.org/10.1107/S2414314618002328 kostenfrei https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2414314618002328 kostenfrei https://doaj.org/toc/2414-3146 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 3 2018 2, p x180232
spelling	10.1107/S2414314618002328 doi (DE-627)DOAJ044089961 (DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b DE-627 ger DE-627 rakwb eng QD901-999 Satoru Umezono verfasserin aut 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units. crystal structure enamine Crystallography Tsunehisa Okuno verfasserin aut In IUCrData International Union of Crystallography, 2016 3(2018), 2, p x180232 (DE-627)848322010 (DE-600)2847714-5 24143146 nnns volume:3 year:2018 number:2, p x180232 https://doi.org/10.1107/S2414314618002328 kostenfrei https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2414314618002328 kostenfrei https://doaj.org/toc/2414-3146 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 3 2018 2, p x180232
allfields_unstemmed	10.1107/S2414314618002328 doi (DE-627)DOAJ044089961 (DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b DE-627 ger DE-627 rakwb eng QD901-999 Satoru Umezono verfasserin aut 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units. crystal structure enamine Crystallography Tsunehisa Okuno verfasserin aut In IUCrData International Union of Crystallography, 2016 3(2018), 2, p x180232 (DE-627)848322010 (DE-600)2847714-5 24143146 nnns volume:3 year:2018 number:2, p x180232 https://doi.org/10.1107/S2414314618002328 kostenfrei https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2414314618002328 kostenfrei https://doaj.org/toc/2414-3146 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 3 2018 2, p x180232
allfieldsGer	10.1107/S2414314618002328 doi (DE-627)DOAJ044089961 (DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b DE-627 ger DE-627 rakwb eng QD901-999 Satoru Umezono verfasserin aut 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units. crystal structure enamine Crystallography Tsunehisa Okuno verfasserin aut In IUCrData International Union of Crystallography, 2016 3(2018), 2, p x180232 (DE-627)848322010 (DE-600)2847714-5 24143146 nnns volume:3 year:2018 number:2, p x180232 https://doi.org/10.1107/S2414314618002328 kostenfrei https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2414314618002328 kostenfrei https://doaj.org/toc/2414-3146 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 3 2018 2, p x180232
allfieldsSound	10.1107/S2414314618002328 doi (DE-627)DOAJ044089961 (DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b DE-627 ger DE-627 rakwb eng QD901-999 Satoru Umezono verfasserin aut 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units. crystal structure enamine Crystallography Tsunehisa Okuno verfasserin aut In IUCrData International Union of Crystallography, 2016 3(2018), 2, p x180232 (DE-627)848322010 (DE-600)2847714-5 24143146 nnns volume:3 year:2018 number:2, p x180232 https://doi.org/10.1107/S2414314618002328 kostenfrei https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b kostenfrei http://scripts.iucr.org/cgi-bin/paper?S2414314618002328 kostenfrei https://doaj.org/toc/2414-3146 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 3 2018 2, p x180232
language	English
source	In IUCrData 3(2018), 2, p x180232 volume:3 year:2018 number:2, p x180232
sourceStr	In IUCrData 3(2018), 2, p x180232 volume:3 year:2018 number:2, p x180232
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	crystal structure enamine Crystallography
isfreeaccess_bool	true
container_title	IUCrData
authorswithroles_txt_mv	Satoru Umezono @@aut@@ Tsunehisa Okuno @@aut@@
publishDateDaySort_date	2018-01-01T00:00:00Z
hierarchy_top_id	848322010
id	DOAJ044089961
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">DOAJ044089961</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230308075820.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230227s2018 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1107/S2414314618002328</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ044089961</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD901-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Satoru Umezono</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2018</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">crystal structure</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">enamine</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Crystallography</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Tsunehisa Okuno</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">IUCrData</subfield><subfield code="d">International Union of Crystallography, 2016</subfield><subfield code="g">3(2018), 2, p x180232</subfield><subfield code="w">(DE-627)848322010</subfield><subfield code="w">(DE-600)2847714-5</subfield><subfield code="x">24143146</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:3</subfield><subfield code="g">year:2018</subfield><subfield code="g">number:2, p x180232</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1107/S2414314618002328</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://scripts.iucr.org/cgi-bin/paper?S2414314618002328</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://doaj.org/toc/2414-3146</subfield><subfield code="y">Journal toc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_DOAJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4367</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">3</subfield><subfield code="j">2018</subfield><subfield code="e">2, p x180232</subfield></datafield></record></collection>
callnumber-first	Q - Science
author	Satoru Umezono
spellingShingle	Satoru Umezono misc QD901-999 misc crystal structure misc enamine misc Crystallography 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine
authorStr	Satoru Umezono
ppnlink_with_tag_str_mv	@@773@@(DE-627)848322010
format	electronic Article
delete_txt_mv	keep
author_role	aut aut
collection	DOAJ
remote_str	true
callnumber-label	QD901-999
illustrated	Not Illustrated
issn	24143146
topic_title	QD901-999 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine crystal structure enamine
topic	misc QD901-999 misc crystal structure misc enamine misc Crystallography
topic_unstemmed	misc QD901-999 misc crystal structure misc enamine misc Crystallography
topic_browse	misc QD901-999 misc crystal structure misc enamine misc Crystallography
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	IUCrData
hierarchy_parent_id	848322010
hierarchy_top_title	IUCrData
isfreeaccess_txt	true
familylinks_str_mv	(DE-627)848322010 (DE-600)2847714-5
title	10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine
ctrlnum	(DE-627)DOAJ044089961 (DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b
title_full	10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine
author_sort	Satoru Umezono
journal	IUCrData
journalStr	IUCrData
callnumber-first-code	Q
lang_code	eng
isOA_bool	true
recordtype	marc
publishDateSort	2018
contenttype_str_mv	txt
author_browse	Satoru Umezono Tsunehisa Okuno
container_volume	3
class	QD901-999
format_se	Elektronische Aufsätze
author-letter	Satoru Umezono
doi_str_mv	10.1107/S2414314618002328
author2-role	verfasserin
title_sort	10-[1,1-dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10h-phenothiazine
callnumber	QD901-999
title_auth	10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine
abstract	The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.
abstractGer	The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.
abstract_unstemmed	The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700
container_issue	2, p x180232
title_short	10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine
url	https://doi.org/10.1107/S2414314618002328 https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b http://scripts.iucr.org/cgi-bin/paper?S2414314618002328 https://doaj.org/toc/2414-3146
remote_bool	true
author2	Tsunehisa Okuno
author2Str	Tsunehisa Okuno
ppnlink	848322010
callnumber-subject	QD - Chemistry
mediatype_str_mv	c
isOA_txt	true
hochschulschrift_bool	false
doi_str	10.1107/S2414314618002328
callnumber-a	QD901-999
up_date	2024-07-03T21:09:57.791Z
_version_	1803593709299695616
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">DOAJ044089961</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230308075820.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">230227s2018 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1107/S2414314618002328</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)DOAJ044089961</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DOAJ04a230162e6e4f2b9b2cc54b3ff65c1b</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD901-999</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Satoru Umezono</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2018</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">crystal structure</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">enamine</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Crystallography</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Tsunehisa Okuno</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">IUCrData</subfield><subfield code="d">International Union of Crystallography, 2016</subfield><subfield code="g">3(2018), 2, p x180232</subfield><subfield code="w">(DE-627)848322010</subfield><subfield code="w">(DE-600)2847714-5</subfield><subfield code="x">24143146</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:3</subfield><subfield code="g">year:2018</subfield><subfield code="g">number:2, p x180232</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doi.org/10.1107/S2414314618002328</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://doaj.org/article/04a230162e6e4f2b9b2cc54b3ff65c1b</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://scripts.iucr.org/cgi-bin/paper?S2414314618002328</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://doaj.org/toc/2414-3146</subfield><subfield code="y">Journal toc</subfield><subfield code="z">kostenfrei</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_DOAJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4367</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">3</subfield><subfield code="j">2018</subfield><subfield code="e">2, p x180232</subfield></datafield></record></collection>
score	7.3999224

Nicht das Richtige dabei?

Schreiben Sie uns!

10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10H-phenothiazine

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?