Expanding the Range: AuCu Metal Aerogels from H<sub<2</sub<O and EtOH
Due to their self-supporting and nanoparticulate structure, metal aerogels have emerged as excellent electrocatalysts, especially in the light of the shift to renewable energy cycles. While a large number of synthesis parameters have already been studied in depth, only superficial attention has been...
Ausführliche Beschreibung
Autor*in: |
Maximilian Georgi [verfasserIn] Johannes Kresse [verfasserIn] Karl Hiekel [verfasserIn] René Hübner [verfasserIn] Alexander Eychmüller [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2022 |
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Übergeordnetes Werk: |
In: Catalysts - MDPI AG, 2012, 12(2022), 4, p 441 |
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Übergeordnetes Werk: |
volume:12 ; year:2022 ; number:4, p 441 |
Links: |
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DOI / URN: |
10.3390/catal12040441 |
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Katalog-ID: |
DOAJ04442633X |
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TP1-1185 QD1-999 Expanding the Range: AuCu Metal Aerogels from H<sub<2</sub<O and EtOH metal aerogel gold copper ethanol water |
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Expanding the Range: AuCu Metal Aerogels from H<sub<2</sub<O and EtOH |
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Due to their self-supporting and nanoparticulate structure, metal aerogels have emerged as excellent electrocatalysts, especially in the light of the shift to renewable energy cycles. While a large number of synthesis parameters have already been studied in depth, only superficial attention has been paid to the solvent. In order to investigate the influence of this parameter with respect to the gelation time, crystallinity, morphology, or porosity of metal gels, Au<sub<x</sub<Cu<sub<y</sub< aerogels were prepared in water and ethanol. It was shown that although gelation in water leads to highly porous gels (60 m<sup<2</sup<g<sup<−1</sup<), a CuO phase forms during this process. The undesired oxide could be selectively removed using a post-washing step with formic acid. In contrast, the solvent change to EtOH led to a halving of the gelation time and the suppression of Cu oxidation. Thus, pure Cu aerogels were synthesized in addition to various bimetallic Au<sub<3</sub<X (X = Ni, Fe, Co) gels. The faster gelation, caused by the lower permittivity of EtOH, led to the formation of thicker gel strands, which resulted in a lower porosity of the Au<sub<x</sub<Cu<sub<y</sub< aerogels. The advantage given by the solvent choice simplifies the preparation of metal aerogels and provides deeper knowledge about their gelation. |
abstractGer |
Due to their self-supporting and nanoparticulate structure, metal aerogels have emerged as excellent electrocatalysts, especially in the light of the shift to renewable energy cycles. While a large number of synthesis parameters have already been studied in depth, only superficial attention has been paid to the solvent. In order to investigate the influence of this parameter with respect to the gelation time, crystallinity, morphology, or porosity of metal gels, Au<sub<x</sub<Cu<sub<y</sub< aerogels were prepared in water and ethanol. It was shown that although gelation in water leads to highly porous gels (60 m<sup<2</sup<g<sup<−1</sup<), a CuO phase forms during this process. The undesired oxide could be selectively removed using a post-washing step with formic acid. In contrast, the solvent change to EtOH led to a halving of the gelation time and the suppression of Cu oxidation. Thus, pure Cu aerogels were synthesized in addition to various bimetallic Au<sub<3</sub<X (X = Ni, Fe, Co) gels. The faster gelation, caused by the lower permittivity of EtOH, led to the formation of thicker gel strands, which resulted in a lower porosity of the Au<sub<x</sub<Cu<sub<y</sub< aerogels. The advantage given by the solvent choice simplifies the preparation of metal aerogels and provides deeper knowledge about their gelation. |
abstract_unstemmed |
Due to their self-supporting and nanoparticulate structure, metal aerogels have emerged as excellent electrocatalysts, especially in the light of the shift to renewable energy cycles. While a large number of synthesis parameters have already been studied in depth, only superficial attention has been paid to the solvent. In order to investigate the influence of this parameter with respect to the gelation time, crystallinity, morphology, or porosity of metal gels, Au<sub<x</sub<Cu<sub<y</sub< aerogels were prepared in water and ethanol. It was shown that although gelation in water leads to highly porous gels (60 m<sup<2</sup<g<sup<−1</sup<), a CuO phase forms during this process. The undesired oxide could be selectively removed using a post-washing step with formic acid. In contrast, the solvent change to EtOH led to a halving of the gelation time and the suppression of Cu oxidation. Thus, pure Cu aerogels were synthesized in addition to various bimetallic Au<sub<3</sub<X (X = Ni, Fe, Co) gels. The faster gelation, caused by the lower permittivity of EtOH, led to the formation of thicker gel strands, which resulted in a lower porosity of the Au<sub<x</sub<Cu<sub<y</sub< aerogels. The advantage given by the solvent choice simplifies the preparation of metal aerogels and provides deeper knowledge about their gelation. |
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