Influence of Bi nonstoichiometry on the energy storage properties of 0.93KNN–0.07BixMN relaxor ferroelectrics
Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results show...
Ausführliche Beschreibung
Autor*in: |
Xiaoshuang Qiao [verfasserIn] Xiaoshuai Zhang [verfasserIn] Di Wu [verfasserIn] Xiaolian Chao [verfasserIn] Zupei Yang [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2018 |
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Übergeordnetes Werk: |
In: Journal of Advanced Dielectrics - World Scientific Publishing, 2018, 8(2018), 6, Seite 1830006-1-1830006-9 |
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Übergeordnetes Werk: |
volume:8 ; year:2018 ; number:6 ; pages:1830006-1-1830006-9 |
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DOI / URN: |
10.1142/S2010135X18300062 |
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Katalog-ID: |
DOAJ044634579 |
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10.1142/S2010135X18300062 doi (DE-627)DOAJ044634579 (DE-599)DOAJacba23f58765485dac4598e3c38c3941 DE-627 ger DE-627 rakwb eng QC501-721 Xiaoshuang Qiao verfasserin aut Influence of Bi nonstoichiometry on the energy storage properties of 0.93KNN–0.07BixMN relaxor ferroelectrics 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties. Oxygen vacancy nonstoichiometry energy storage Electricity Xiaoshuai Zhang verfasserin aut Di Wu verfasserin aut Xiaolian Chao verfasserin aut Zupei Yang verfasserin aut In Journal of Advanced Dielectrics World Scientific Publishing, 2018 8(2018), 6, Seite 1830006-1-1830006-9 (DE-627)778146960 (DE-600)2756564-6 20101368 nnns volume:8 year:2018 number:6 pages:1830006-1-1830006-9 https://doi.org/10.1142/S2010135X18300062 kostenfrei https://doaj.org/article/acba23f58765485dac4598e3c38c3941 kostenfrei http://www.worldscientific.com/doi/pdf/10.1142/S2010135X18300062 kostenfrei https://doaj.org/toc/2010-135X Journal toc kostenfrei https://doaj.org/toc/2010-1368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2018 6 1830006-1-1830006-9 |
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10.1142/S2010135X18300062 doi (DE-627)DOAJ044634579 (DE-599)DOAJacba23f58765485dac4598e3c38c3941 DE-627 ger DE-627 rakwb eng QC501-721 Xiaoshuang Qiao verfasserin aut Influence of Bi nonstoichiometry on the energy storage properties of 0.93KNN–0.07BixMN relaxor ferroelectrics 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties. Oxygen vacancy nonstoichiometry energy storage Electricity Xiaoshuai Zhang verfasserin aut Di Wu verfasserin aut Xiaolian Chao verfasserin aut Zupei Yang verfasserin aut In Journal of Advanced Dielectrics World Scientific Publishing, 2018 8(2018), 6, Seite 1830006-1-1830006-9 (DE-627)778146960 (DE-600)2756564-6 20101368 nnns volume:8 year:2018 number:6 pages:1830006-1-1830006-9 https://doi.org/10.1142/S2010135X18300062 kostenfrei https://doaj.org/article/acba23f58765485dac4598e3c38c3941 kostenfrei http://www.worldscientific.com/doi/pdf/10.1142/S2010135X18300062 kostenfrei https://doaj.org/toc/2010-135X Journal toc kostenfrei https://doaj.org/toc/2010-1368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2018 6 1830006-1-1830006-9 |
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10.1142/S2010135X18300062 doi (DE-627)DOAJ044634579 (DE-599)DOAJacba23f58765485dac4598e3c38c3941 DE-627 ger DE-627 rakwb eng QC501-721 Xiaoshuang Qiao verfasserin aut Influence of Bi nonstoichiometry on the energy storage properties of 0.93KNN–0.07BixMN relaxor ferroelectrics 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties. Oxygen vacancy nonstoichiometry energy storage Electricity Xiaoshuai Zhang verfasserin aut Di Wu verfasserin aut Xiaolian Chao verfasserin aut Zupei Yang verfasserin aut In Journal of Advanced Dielectrics World Scientific Publishing, 2018 8(2018), 6, Seite 1830006-1-1830006-9 (DE-627)778146960 (DE-600)2756564-6 20101368 nnns volume:8 year:2018 number:6 pages:1830006-1-1830006-9 https://doi.org/10.1142/S2010135X18300062 kostenfrei https://doaj.org/article/acba23f58765485dac4598e3c38c3941 kostenfrei http://www.worldscientific.com/doi/pdf/10.1142/S2010135X18300062 kostenfrei https://doaj.org/toc/2010-135X Journal toc kostenfrei https://doaj.org/toc/2010-1368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2018 6 1830006-1-1830006-9 |
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10.1142/S2010135X18300062 doi (DE-627)DOAJ044634579 (DE-599)DOAJacba23f58765485dac4598e3c38c3941 DE-627 ger DE-627 rakwb eng QC501-721 Xiaoshuang Qiao verfasserin aut Influence of Bi nonstoichiometry on the energy storage properties of 0.93KNN–0.07BixMN relaxor ferroelectrics 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties. Oxygen vacancy nonstoichiometry energy storage Electricity Xiaoshuai Zhang verfasserin aut Di Wu verfasserin aut Xiaolian Chao verfasserin aut Zupei Yang verfasserin aut In Journal of Advanced Dielectrics World Scientific Publishing, 2018 8(2018), 6, Seite 1830006-1-1830006-9 (DE-627)778146960 (DE-600)2756564-6 20101368 nnns volume:8 year:2018 number:6 pages:1830006-1-1830006-9 https://doi.org/10.1142/S2010135X18300062 kostenfrei https://doaj.org/article/acba23f58765485dac4598e3c38c3941 kostenfrei http://www.worldscientific.com/doi/pdf/10.1142/S2010135X18300062 kostenfrei https://doaj.org/toc/2010-135X Journal toc kostenfrei https://doaj.org/toc/2010-1368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 8 2018 6 1830006-1-1830006-9 |
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The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. 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Influence of Bi nonstoichiometry on the energy storage properties of 0.93KNN–0.07BixMN relaxor ferroelectrics |
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Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties. |
abstractGer |
Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties. |
abstract_unstemmed |
Ceramic-based dielectric capacitors are becoming more and more important in electronic devices. The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties. |
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Influence of Bi nonstoichiometry on the energy storage properties of 0.93KNN–0.07BixMN relaxor ferroelectrics |
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The ceramics of 0.93K0.5Na0.5NbO3–0.07Bix(Mg1∕3Nb2∕3)O3 (0.93KNN–0.07BixMN) (x=0.60, 2/3, 0.75 and 0.95) were successfully fabricated by virtue of the solid reaction process in this work. The results showed that the amount of Bi content has a significant impact on the ceramics of 0.93KNN–0.07BixMN. XRD indicates that all specimens exhibit a pure perovskite structure and existing oxygen vacancy in the specimens. The mean grain size for all specimens belong to submicron scale, and the sample of x=0.95 owns the smallest grain size is 0.11μm. The maximum dielectric constant increases but the phase transition temperature Tm exhibits a contrary tendency at 1MHz with increasing Bi concentration. Besides, all ceramics are relaxor ferroelectric. The impedance analysis further revealed that the activation energy of the ceramics increases with Bi content. Eventually, the highest η of 58.8% and Wrec of 1.30J/cm3 are simultaneously achieved in the sample with x=0.60. Overall, we demonstrate in this work that stoichiometry control of Bi in 0.93KNN–0.07BixMN ceramics is a practical method to obtain the desired structural, dielectric and energy storage properties.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxygen vacancy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">nonstoichiometry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">energy storage</subfield></datafield><datafield tag="653" ind1=" " ind2="0"><subfield code="a">Electricity</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiaoshuai Zhang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Di Wu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Xiaolian Chao</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="0" ind2=" "><subfield code="a">Zupei Yang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="t">Journal of Advanced Dielectrics</subfield><subfield code="d">World Scientific Publishing, 2018</subfield><subfield code="g">8(2018), 6, Seite 1830006-1-1830006-9</subfield><subfield code="w">(DE-627)778146960</subfield><subfield code="w">(DE-600)2756564-6</subfield><subfield code="x">20101368</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:8</subfield><subfield code="g">year:2018</subfield><subfield code="g">number:6</subfield><subfield code="g">pages:1830006-1-1830006-9</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield 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