Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements.

ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as f...
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Autor*in:	Xin Jin [verfasserIn] Mao Deng [verfasserIn] Sören Kaps [verfasserIn] Xinwei Zhu [verfasserIn] Iris Hölken [verfasserIn] Kristin Mess [verfasserIn] Rainer Adelung [verfasserIn] Yogendra Kumar Mishra [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2014

Übergeordnetes Werk:	In: PLoS ONE - Public Library of Science (PLoS), 2007, 9(2014), 9, p e106991
Übergeordnetes Werk:	volume:9 ; year:2014 ; number:9, p e106991

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.1371/journal.pone.0106991

Katalog-ID:	DOAJ048062316

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allfields	10.1371/journal.pone.0106991 doi (DE-627)DOAJ048062316 (DE-599)DOAJabf5a884d3c547f898cc0729d40c7f62 DE-627 ger DE-627 rakwb eng Xin Jin verfasserin aut Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements. 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as fillers to fabricate the different ZnO-Silicone composites. The detailed microstructures of the fillers as well as synthesized composites using scanning electron microscopy have been presented here. The tensile elastic modulus and water contact angle, which are important parameters for bio-mimetic applications, of fabricated composites with different fillers have been measured and compared. Among all three types of fillers, tetrapodal shaped ZnO microparticles showed the best performance in terms of increase in hydrophobicity of material cross-section as well as the stiffness of the composites. It has been demonstrated that the tetrapodal shaped microparticles gain their advantage due to the special shape, which avoids agglomeration problems as in the case for nanoparticles, and the difficulty of achieving truly random distribution for whisker fillers. Medicine R Science Q Mao Deng verfasserin aut Sören Kaps verfasserin aut Xinwei Zhu verfasserin aut Iris Hölken verfasserin aut Kristin Mess verfasserin aut Rainer Adelung verfasserin aut Yogendra Kumar Mishra verfasserin aut In PLoS ONE Public Library of Science (PLoS), 2007 9(2014), 9, p e106991 (DE-627)523574592 (DE-600)2267670-3 19326203 nnns volume:9 year:2014 number:9, p e106991 https://doi.org/10.1371/journal.pone.0106991 kostenfrei https://doaj.org/article/abf5a884d3c547f898cc0729d40c7f62 kostenfrei http://europepmc.org/articles/PMC4160218?pdf=render kostenfrei https://doaj.org/toc/1932-6203 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_34 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_235 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2014 9, p e106991
spelling	10.1371/journal.pone.0106991 doi (DE-627)DOAJ048062316 (DE-599)DOAJabf5a884d3c547f898cc0729d40c7f62 DE-627 ger DE-627 rakwb eng Xin Jin verfasserin aut Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements. 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as fillers to fabricate the different ZnO-Silicone composites. The detailed microstructures of the fillers as well as synthesized composites using scanning electron microscopy have been presented here. The tensile elastic modulus and water contact angle, which are important parameters for bio-mimetic applications, of fabricated composites with different fillers have been measured and compared. Among all three types of fillers, tetrapodal shaped ZnO microparticles showed the best performance in terms of increase in hydrophobicity of material cross-section as well as the stiffness of the composites. It has been demonstrated that the tetrapodal shaped microparticles gain their advantage due to the special shape, which avoids agglomeration problems as in the case for nanoparticles, and the difficulty of achieving truly random distribution for whisker fillers. Medicine R Science Q Mao Deng verfasserin aut Sören Kaps verfasserin aut Xinwei Zhu verfasserin aut Iris Hölken verfasserin aut Kristin Mess verfasserin aut Rainer Adelung verfasserin aut Yogendra Kumar Mishra verfasserin aut In PLoS ONE Public Library of Science (PLoS), 2007 9(2014), 9, p e106991 (DE-627)523574592 (DE-600)2267670-3 19326203 nnns volume:9 year:2014 number:9, p e106991 https://doi.org/10.1371/journal.pone.0106991 kostenfrei https://doaj.org/article/abf5a884d3c547f898cc0729d40c7f62 kostenfrei http://europepmc.org/articles/PMC4160218?pdf=render kostenfrei https://doaj.org/toc/1932-6203 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_34 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_235 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2014 9, p e106991
allfields_unstemmed	10.1371/journal.pone.0106991 doi (DE-627)DOAJ048062316 (DE-599)DOAJabf5a884d3c547f898cc0729d40c7f62 DE-627 ger DE-627 rakwb eng Xin Jin verfasserin aut Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements. 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as fillers to fabricate the different ZnO-Silicone composites. The detailed microstructures of the fillers as well as synthesized composites using scanning electron microscopy have been presented here. The tensile elastic modulus and water contact angle, which are important parameters for bio-mimetic applications, of fabricated composites with different fillers have been measured and compared. Among all three types of fillers, tetrapodal shaped ZnO microparticles showed the best performance in terms of increase in hydrophobicity of material cross-section as well as the stiffness of the composites. It has been demonstrated that the tetrapodal shaped microparticles gain their advantage due to the special shape, which avoids agglomeration problems as in the case for nanoparticles, and the difficulty of achieving truly random distribution for whisker fillers. Medicine R Science Q Mao Deng verfasserin aut Sören Kaps verfasserin aut Xinwei Zhu verfasserin aut Iris Hölken verfasserin aut Kristin Mess verfasserin aut Rainer Adelung verfasserin aut Yogendra Kumar Mishra verfasserin aut In PLoS ONE Public Library of Science (PLoS), 2007 9(2014), 9, p e106991 (DE-627)523574592 (DE-600)2267670-3 19326203 nnns volume:9 year:2014 number:9, p e106991 https://doi.org/10.1371/journal.pone.0106991 kostenfrei https://doaj.org/article/abf5a884d3c547f898cc0729d40c7f62 kostenfrei http://europepmc.org/articles/PMC4160218?pdf=render kostenfrei https://doaj.org/toc/1932-6203 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_34 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_235 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2014 9, p e106991
allfieldsGer	10.1371/journal.pone.0106991 doi (DE-627)DOAJ048062316 (DE-599)DOAJabf5a884d3c547f898cc0729d40c7f62 DE-627 ger DE-627 rakwb eng Xin Jin verfasserin aut Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements. 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as fillers to fabricate the different ZnO-Silicone composites. The detailed microstructures of the fillers as well as synthesized composites using scanning electron microscopy have been presented here. The tensile elastic modulus and water contact angle, which are important parameters for bio-mimetic applications, of fabricated composites with different fillers have been measured and compared. Among all three types of fillers, tetrapodal shaped ZnO microparticles showed the best performance in terms of increase in hydrophobicity of material cross-section as well as the stiffness of the composites. It has been demonstrated that the tetrapodal shaped microparticles gain their advantage due to the special shape, which avoids agglomeration problems as in the case for nanoparticles, and the difficulty of achieving truly random distribution for whisker fillers. Medicine R Science Q Mao Deng verfasserin aut Sören Kaps verfasserin aut Xinwei Zhu verfasserin aut Iris Hölken verfasserin aut Kristin Mess verfasserin aut Rainer Adelung verfasserin aut Yogendra Kumar Mishra verfasserin aut In PLoS ONE Public Library of Science (PLoS), 2007 9(2014), 9, p e106991 (DE-627)523574592 (DE-600)2267670-3 19326203 nnns volume:9 year:2014 number:9, p e106991 https://doi.org/10.1371/journal.pone.0106991 kostenfrei https://doaj.org/article/abf5a884d3c547f898cc0729d40c7f62 kostenfrei http://europepmc.org/articles/PMC4160218?pdf=render kostenfrei https://doaj.org/toc/1932-6203 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_34 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_235 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2014 9, p e106991
allfieldsSound	10.1371/journal.pone.0106991 doi (DE-627)DOAJ048062316 (DE-599)DOAJabf5a884d3c547f898cc0729d40c7f62 DE-627 ger DE-627 rakwb eng Xin Jin verfasserin aut Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements. 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as fillers to fabricate the different ZnO-Silicone composites. The detailed microstructures of the fillers as well as synthesized composites using scanning electron microscopy have been presented here. The tensile elastic modulus and water contact angle, which are important parameters for bio-mimetic applications, of fabricated composites with different fillers have been measured and compared. Among all three types of fillers, tetrapodal shaped ZnO microparticles showed the best performance in terms of increase in hydrophobicity of material cross-section as well as the stiffness of the composites. It has been demonstrated that the tetrapodal shaped microparticles gain their advantage due to the special shape, which avoids agglomeration problems as in the case for nanoparticles, and the difficulty of achieving truly random distribution for whisker fillers. Medicine R Science Q Mao Deng verfasserin aut Sören Kaps verfasserin aut Xinwei Zhu verfasserin aut Iris Hölken verfasserin aut Kristin Mess verfasserin aut Rainer Adelung verfasserin aut Yogendra Kumar Mishra verfasserin aut In PLoS ONE Public Library of Science (PLoS), 2007 9(2014), 9, p e106991 (DE-627)523574592 (DE-600)2267670-3 19326203 nnns volume:9 year:2014 number:9, p e106991 https://doi.org/10.1371/journal.pone.0106991 kostenfrei https://doaj.org/article/abf5a884d3c547f898cc0729d40c7f62 kostenfrei http://europepmc.org/articles/PMC4160218?pdf=render kostenfrei https://doaj.org/toc/1932-6203 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_34 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_235 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2014 9, p e106991
language	English
source	In PLoS ONE 9(2014), 9, p e106991 volume:9 year:2014 number:9, p e106991
sourceStr	In PLoS ONE 9(2014), 9, p e106991 volume:9 year:2014 number:9, p e106991
format_phy_str_mv	Article
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container_title	PLoS ONE
authorswithroles_txt_mv	Xin Jin @@aut@@ Mao Deng @@aut@@ Sören Kaps @@aut@@ Xinwei Zhu @@aut@@ Iris Hölken @@aut@@ Kristin Mess @@aut@@ Rainer Adelung @@aut@@ Yogendra Kumar Mishra @@aut@@
publishDateDaySort_date	2014-01-01T00:00:00Z
hierarchy_top_id	523574592
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author	Xin Jin
spellingShingle	Xin Jin misc Medicine misc R misc Science misc Q Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements.
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topic_title	Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements
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title	Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements.
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title_sort	study of tetrapodal zno-pdms composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements
title_auth	Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements.
abstract	ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as fillers to fabricate the different ZnO-Silicone composites. The detailed microstructures of the fillers as well as synthesized composites using scanning electron microscopy have been presented here. The tensile elastic modulus and water contact angle, which are important parameters for bio-mimetic applications, of fabricated composites with different fillers have been measured and compared. Among all three types of fillers, tetrapodal shaped ZnO microparticles showed the best performance in terms of increase in hydrophobicity of material cross-section as well as the stiffness of the composites. It has been demonstrated that the tetrapodal shaped microparticles gain their advantage due to the special shape, which avoids agglomeration problems as in the case for nanoparticles, and the difficulty of achieving truly random distribution for whisker fillers.
abstractGer	ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as fillers to fabricate the different ZnO-Silicone composites. The detailed microstructures of the fillers as well as synthesized composites using scanning electron microscopy have been presented here. The tensile elastic modulus and water contact angle, which are important parameters for bio-mimetic applications, of fabricated composites with different fillers have been measured and compared. Among all three types of fillers, tetrapodal shaped ZnO microparticles showed the best performance in terms of increase in hydrophobicity of material cross-section as well as the stiffness of the composites. It has been demonstrated that the tetrapodal shaped microparticles gain their advantage due to the special shape, which avoids agglomeration problems as in the case for nanoparticles, and the difficulty of achieving truly random distribution for whisker fillers.
abstract_unstemmed	ZnO particles of different size and structures were used as fillers to modify the silicone rubber, in order to reveal the effect of the filler shape in the polymer composites. Tetrapodal shaped microparticles, short microfibers/whiskers, and nanosized spherical particles from ZnO have been used as fillers to fabricate the different ZnO-Silicone composites. The detailed microstructures of the fillers as well as synthesized composites using scanning electron microscopy have been presented here. The tensile elastic modulus and water contact angle, which are important parameters for bio-mimetic applications, of fabricated composites with different fillers have been measured and compared. Among all three types of fillers, tetrapodal shaped ZnO microparticles showed the best performance in terms of increase in hydrophobicity of material cross-section as well as the stiffness of the composites. It has been demonstrated that the tetrapodal shaped microparticles gain their advantage due to the special shape, which avoids agglomeration problems as in the case for nanoparticles, and the difficulty of achieving truly random distribution for whisker fillers.
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title_short	Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements.
url	https://doi.org/10.1371/journal.pone.0106991 https://doaj.org/article/abf5a884d3c547f898cc0729d40c7f62 http://europepmc.org/articles/PMC4160218?pdf=render https://doaj.org/toc/1932-6203
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Study of tetrapodal ZnO-PDMS composites: a comparison of fillers shapes in stiffness and hydrophobicity improvements.

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