Preparation and Electrical Properties of Polyacrylonitrile Based Porous Carbon by Different Activation Methods
Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres te...
Ausführliche Beschreibung
Autor*in: |
Xiaoqiang Wang [verfasserIn] Yifan Tan [verfasserIn] Meijiao Sun [verfasserIn] Binbin Yu [verfasserIn] Junhe Yang [verfasserIn] Yuhua Xue [verfasserIn] Guangzhi Yang [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2021 |
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Übergeordnetes Werk: |
In: Molecules - MDPI AG, 2003, 26(2021), 12, p 3499 |
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Übergeordnetes Werk: |
volume:26 ; year:2021 ; number:12, p 3499 |
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DOI / URN: |
10.3390/molecules26123499 |
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Katalog-ID: |
DOAJ051682257 |
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520 | |a Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. | ||
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10.3390/molecules26123499 doi (DE-627)DOAJ051682257 (DE-599)DOAJ558728ca01364a7d9894ad781a3e32c7 DE-627 ger DE-627 rakwb eng QD241-441 Xiaoqiang Wang verfasserin aut Preparation and Electrical Properties of Polyacrylonitrile Based Porous Carbon by Different Activation Methods 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. porous carbon activation method specific capacitance retentions Organic chemistry Yifan Tan verfasserin aut Meijiao Sun verfasserin aut Binbin Yu verfasserin aut Junhe Yang verfasserin aut Yuhua Xue verfasserin aut Guangzhi Yang verfasserin aut In Molecules MDPI AG, 2003 26(2021), 12, p 3499 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:26 year:2021 number:12, p 3499 https://doi.org/10.3390/molecules26123499 kostenfrei https://doaj.org/article/558728ca01364a7d9894ad781a3e32c7 kostenfrei https://www.mdpi.com/1420-3049/26/12/3499 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 26 2021 12, p 3499 |
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10.3390/molecules26123499 doi (DE-627)DOAJ051682257 (DE-599)DOAJ558728ca01364a7d9894ad781a3e32c7 DE-627 ger DE-627 rakwb eng QD241-441 Xiaoqiang Wang verfasserin aut Preparation and Electrical Properties of Polyacrylonitrile Based Porous Carbon by Different Activation Methods 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. porous carbon activation method specific capacitance retentions Organic chemistry Yifan Tan verfasserin aut Meijiao Sun verfasserin aut Binbin Yu verfasserin aut Junhe Yang verfasserin aut Yuhua Xue verfasserin aut Guangzhi Yang verfasserin aut In Molecules MDPI AG, 2003 26(2021), 12, p 3499 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:26 year:2021 number:12, p 3499 https://doi.org/10.3390/molecules26123499 kostenfrei https://doaj.org/article/558728ca01364a7d9894ad781a3e32c7 kostenfrei https://www.mdpi.com/1420-3049/26/12/3499 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 26 2021 12, p 3499 |
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10.3390/molecules26123499 doi (DE-627)DOAJ051682257 (DE-599)DOAJ558728ca01364a7d9894ad781a3e32c7 DE-627 ger DE-627 rakwb eng QD241-441 Xiaoqiang Wang verfasserin aut Preparation and Electrical Properties of Polyacrylonitrile Based Porous Carbon by Different Activation Methods 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. porous carbon activation method specific capacitance retentions Organic chemistry Yifan Tan verfasserin aut Meijiao Sun verfasserin aut Binbin Yu verfasserin aut Junhe Yang verfasserin aut Yuhua Xue verfasserin aut Guangzhi Yang verfasserin aut In Molecules MDPI AG, 2003 26(2021), 12, p 3499 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:26 year:2021 number:12, p 3499 https://doi.org/10.3390/molecules26123499 kostenfrei https://doaj.org/article/558728ca01364a7d9894ad781a3e32c7 kostenfrei https://www.mdpi.com/1420-3049/26/12/3499 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 26 2021 12, p 3499 |
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10.3390/molecules26123499 doi (DE-627)DOAJ051682257 (DE-599)DOAJ558728ca01364a7d9894ad781a3e32c7 DE-627 ger DE-627 rakwb eng QD241-441 Xiaoqiang Wang verfasserin aut Preparation and Electrical Properties of Polyacrylonitrile Based Porous Carbon by Different Activation Methods 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. porous carbon activation method specific capacitance retentions Organic chemistry Yifan Tan verfasserin aut Meijiao Sun verfasserin aut Binbin Yu verfasserin aut Junhe Yang verfasserin aut Yuhua Xue verfasserin aut Guangzhi Yang verfasserin aut In Molecules MDPI AG, 2003 26(2021), 12, p 3499 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:26 year:2021 number:12, p 3499 https://doi.org/10.3390/molecules26123499 kostenfrei https://doaj.org/article/558728ca01364a7d9894ad781a3e32c7 kostenfrei https://www.mdpi.com/1420-3049/26/12/3499 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 26 2021 12, p 3499 |
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10.3390/molecules26123499 doi (DE-627)DOAJ051682257 (DE-599)DOAJ558728ca01364a7d9894ad781a3e32c7 DE-627 ger DE-627 rakwb eng QD241-441 Xiaoqiang Wang verfasserin aut Preparation and Electrical Properties of Polyacrylonitrile Based Porous Carbon by Different Activation Methods 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. porous carbon activation method specific capacitance retentions Organic chemistry Yifan Tan verfasserin aut Meijiao Sun verfasserin aut Binbin Yu verfasserin aut Junhe Yang verfasserin aut Yuhua Xue verfasserin aut Guangzhi Yang verfasserin aut In Molecules MDPI AG, 2003 26(2021), 12, p 3499 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:26 year:2021 number:12, p 3499 https://doi.org/10.3390/molecules26123499 kostenfrei https://doaj.org/article/558728ca01364a7d9894ad781a3e32c7 kostenfrei https://www.mdpi.com/1420-3049/26/12/3499 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 26 2021 12, p 3499 |
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Preparation and Electrical Properties of Polyacrylonitrile Based Porous Carbon by Different Activation Methods |
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Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. |
abstractGer |
Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. |
abstract_unstemmed |
Polyacrylonitrile (PAN)-based porous carbon was prepared by different methods of activation with PAN polymer microsphere as precursor. The morphology, structure and electrical properties for supercapacitor of the porous carbon were investigated. It was found that the morphology of PAN nanospheres tended to be destroyed in the process of one-step activation (activation and carbonization were carried out simultaneously, and could only be retained when the amount of activating agent KOH was small). While the spherical morphology could be well reserved during the two-step activation method (carbonization and activation sequentially). The specific surface area and pore volume increased first and then decreased, with the increase in activation holding time for both one-step and two-step activation methods. The specific surface area reached the maximum value with 2430 m<sup<2</sup< g<sup<−1</sup< for the one-step activation method and 2830 m<sup<2</sup< g<sup<−1</sup< for the two-step activation method. Additionally, their mass-specific capacitances were 178.8 F g<sup<−1</sup< and 160.2 F g<sup<−1</sup<, respectively, under the current density of 1 A g<sup<−1</sup<. After 2000 cycles, the specific capacitance retentions were 92.9% and 91.3%. |
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