Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes

Terpyridine-functionalized Ti nanospike electrodes (TiNS-SiTpy) were developed and applied to cyclic voltammetry and amperometry of Ln (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb) ions and mixed Eu (III) + Ln (III) ions in a 0.1 M NaClO<sub<4</sub< electrolyte. Electrodeposit...
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Autor*in:	Min Hee Joo [verfasserIn] So Jeong Park [verfasserIn] Hye Ji Jang [verfasserIn] Sung-Min Hong [verfasserIn] Choong Kyun Rhee [verfasserIn] Youngku Sohn [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2021

Schlagwörter:	lanthanide Ti nanospike electrodeposition cyclic voltammetry amperometry photoluminescence

Übergeordnetes Werk:	In: Metals - MDPI AG, 2012, 11(2021), 6, p 977
Übergeordnetes Werk:	volume:11 ; year:2021 ; number:6, p 977

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/met11060977

Katalog-ID:	DOAJ05309428X

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520			\|a Terpyridine-functionalized Ti nanospike electrodes (TiNS-SiTpy) were developed and applied to cyclic voltammetry and amperometry of Ln (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb) ions and mixed Eu (III) + Ln (III) ions in a 0.1 M NaClO<sub<4</sub< electrolyte. Electrodeposition was successfully performed over TiNS-SiTpy electrodes, which were fully examined by scanning electron microscopy, X-ray diffraction crystallography, Fourier-transform infrared spectroscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, photoluminescence (PL), and PL decay kinetics. The Gd and Tb ions were found to increase PL intensities with 10× longer lifetimes of 1.32 μs and 1.03 μs, respectively, compared with that of the electrodeposited Eu sample. The crystal phase and the oxidation states were fully examined for the mixed Ln (Eu + Gd and Eu + Tb) complex structures.
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spelling	10.3390/met11060977 doi (DE-627)DOAJ05309428X (DE-599)DOAJ6ce639bfa96a4b5aad85eb8867ab298c DE-627 ger DE-627 rakwb eng TN1-997 Min Hee Joo verfasserin aut Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Terpyridine-functionalized Ti nanospike electrodes (TiNS-SiTpy) were developed and applied to cyclic voltammetry and amperometry of Ln (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb) ions and mixed Eu (III) + Ln (III) ions in a 0.1 M NaClO<sub<4</sub< electrolyte. Electrodeposition was successfully performed over TiNS-SiTpy electrodes, which were fully examined by scanning electron microscopy, X-ray diffraction crystallography, Fourier-transform infrared spectroscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, photoluminescence (PL), and PL decay kinetics. The Gd and Tb ions were found to increase PL intensities with 10× longer lifetimes of 1.32 μs and 1.03 μs, respectively, compared with that of the electrodeposited Eu sample. The crystal phase and the oxidation states were fully examined for the mixed Ln (Eu + Gd and Eu + Tb) complex structures. lanthanide Ti nanospike electrodeposition cyclic voltammetry amperometry photoluminescence Mining engineering. Metallurgy So Jeong Park verfasserin aut Hye Ji Jang verfasserin aut Sung-Min Hong verfasserin aut Choong Kyun Rhee verfasserin aut Youngku Sohn verfasserin aut In Metals MDPI AG, 2012 11(2021), 6, p 977 (DE-627)718627172 (DE-600)2662252-X 20754701 nnns volume:11 year:2021 number:6, p 977 https://doi.org/10.3390/met11060977 kostenfrei https://doaj.org/article/6ce639bfa96a4b5aad85eb8867ab298c kostenfrei https://www.mdpi.com/2075-4701/11/6/977 kostenfrei https://doaj.org/toc/2075-4701 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 6, p 977
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language	English
source	In Metals 11(2021), 6, p 977 volume:11 year:2021 number:6, p 977
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topic_facet	lanthanide Ti nanospike electrodeposition cyclic voltammetry amperometry photoluminescence Mining engineering. Metallurgy
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container_title	Metals
authorswithroles_txt_mv	Min Hee Joo @@aut@@ So Jeong Park @@aut@@ Hye Ji Jang @@aut@@ Sung-Min Hong @@aut@@ Choong Kyun Rhee @@aut@@ Youngku Sohn @@aut@@
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callnumber-first	T - Technology
author	Min Hee Joo
spellingShingle	Min Hee Joo misc TN1-997 misc lanthanide misc Ti nanospike misc electrodeposition misc cyclic voltammetry misc amperometry misc photoluminescence misc Mining engineering. Metallurgy Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes
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topic_title	TN1-997 Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes lanthanide Ti nanospike electrodeposition cyclic voltammetry amperometry photoluminescence
topic	misc TN1-997 misc lanthanide misc Ti nanospike misc electrodeposition misc cyclic voltammetry misc amperometry misc photoluminescence misc Mining engineering. Metallurgy
topic_unstemmed	misc TN1-997 misc lanthanide misc Ti nanospike misc electrodeposition misc cyclic voltammetry misc amperometry misc photoluminescence misc Mining engineering. Metallurgy
topic_browse	misc TN1-997 misc lanthanide misc Ti nanospike misc electrodeposition misc cyclic voltammetry misc amperometry misc photoluminescence misc Mining engineering. Metallurgy
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title	Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes
ctrlnum	(DE-627)DOAJ05309428X (DE-599)DOAJ6ce639bfa96a4b5aad85eb8867ab298c
title_full	Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes
author_sort	Min Hee Joo
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author_browse	Min Hee Joo So Jeong Park Hye Ji Jang Sung-Min Hong Choong Kyun Rhee Youngku Sohn
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title_sort	electrochemistry, electrodeposition, and photoluminescence of eu (iii)/lanthanides (iii) on terpyridine-functionalized ti nanospikes
callnumber	TN1-997
title_auth	Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes
abstract	Terpyridine-functionalized Ti nanospike electrodes (TiNS-SiTpy) were developed and applied to cyclic voltammetry and amperometry of Ln (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb) ions and mixed Eu (III) + Ln (III) ions in a 0.1 M NaClO<sub<4</sub< electrolyte. Electrodeposition was successfully performed over TiNS-SiTpy electrodes, which were fully examined by scanning electron microscopy, X-ray diffraction crystallography, Fourier-transform infrared spectroscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, photoluminescence (PL), and PL decay kinetics. The Gd and Tb ions were found to increase PL intensities with 10× longer lifetimes of 1.32 μs and 1.03 μs, respectively, compared with that of the electrodeposited Eu sample. The crystal phase and the oxidation states were fully examined for the mixed Ln (Eu + Gd and Eu + Tb) complex structures.
abstractGer	Terpyridine-functionalized Ti nanospike electrodes (TiNS-SiTpy) were developed and applied to cyclic voltammetry and amperometry of Ln (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb) ions and mixed Eu (III) + Ln (III) ions in a 0.1 M NaClO<sub<4</sub< electrolyte. Electrodeposition was successfully performed over TiNS-SiTpy electrodes, which were fully examined by scanning electron microscopy, X-ray diffraction crystallography, Fourier-transform infrared spectroscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, photoluminescence (PL), and PL decay kinetics. The Gd and Tb ions were found to increase PL intensities with 10× longer lifetimes of 1.32 μs and 1.03 μs, respectively, compared with that of the electrodeposited Eu sample. The crystal phase and the oxidation states were fully examined for the mixed Ln (Eu + Gd and Eu + Tb) complex structures.
abstract_unstemmed	Terpyridine-functionalized Ti nanospike electrodes (TiNS-SiTpy) were developed and applied to cyclic voltammetry and amperometry of Ln (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb) ions and mixed Eu (III) + Ln (III) ions in a 0.1 M NaClO<sub<4</sub< electrolyte. Electrodeposition was successfully performed over TiNS-SiTpy electrodes, which were fully examined by scanning electron microscopy, X-ray diffraction crystallography, Fourier-transform infrared spectroscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, photoluminescence (PL), and PL decay kinetics. The Gd and Tb ions were found to increase PL intensities with 10× longer lifetimes of 1.32 μs and 1.03 μs, respectively, compared with that of the electrodeposited Eu sample. The crystal phase and the oxidation states were fully examined for the mixed Ln (Eu + Gd and Eu + Tb) complex structures.
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title_short	Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes
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Electrochemistry, Electrodeposition, and Photoluminescence of Eu (III)/Lanthanides (III) on Terpyridine-Functionalized Ti Nanospikes

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