MULLITE AND ITS ISOMORPHIC SUBSTITUTION OVERVIEW

The phase diagram of SiO2-Al2O3 is considered. The paper presents an overview of the methods of synthesising mullite, including the calcining of natural aluminosilicates, the Czochralski process (synthesising mullite from melt), the Verneuil process (synthesising mullite from gel), and the solid sta...
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Gespeichert in:

Autor*in:	Evgeniya G. Yarotskaya [verfasserIn] Pavel P. Fedorov [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch ; Russisch

Erschienen:	2018

Schlagwörter:	mullite synthesis structure habit whiskers isomorphous substitutions.

Übergeordnetes Werk:	In: Конденсированные среды и межфазные границы - Voronezh State University, 2019, 20(2018), 4, Seite 537-544
Übergeordnetes Werk:	volume:20 ; year:2018 ; number:4 ; pages:537-544

Links:	Link aufrufen Link aufrufen Journal toc Journal toc

DOI / URN:	10.17308/kcmf.2018.20/626

Katalog-ID:	DOAJ053348397

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language	English Russian
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callnumber-first	Q - Science
author	Evgeniya G. Yarotskaya
spellingShingle	Evgeniya G. Yarotskaya misc QD1-999 misc mullite misc synthesis misc structure misc habit misc whiskers misc isomorphous substitutions. misc Chemistry MULLITE AND ITS ISOMORPHIC SUBSTITUTION OVERVIEW
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topic_title	QD1-999 MULLITE AND ITS ISOMORPHIC SUBSTITUTION OVERVIEW mullite synthesis structure habit whiskers isomorphous substitutions
topic	misc QD1-999 misc mullite misc synthesis misc structure misc habit misc whiskers misc isomorphous substitutions. misc Chemistry
topic_unstemmed	misc QD1-999 misc mullite misc synthesis misc structure misc habit misc whiskers misc isomorphous substitutions. misc Chemistry
topic_browse	misc QD1-999 misc mullite misc synthesis misc structure misc habit misc whiskers misc isomorphous substitutions. misc Chemistry
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title	MULLITE AND ITS ISOMORPHIC SUBSTITUTION OVERVIEW
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title_full	MULLITE AND ITS ISOMORPHIC SUBSTITUTION OVERVIEW
author_sort	Evgeniya G. Yarotskaya
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title_sort	mullite and its isomorphic substitution overview
callnumber	QD1-999
title_auth	MULLITE AND ITS ISOMORPHIC SUBSTITUTION OVERVIEW
abstract	The phase diagram of SiO2-Al2O3 is considered. The paper presents an overview of the methods of synthesising mullite, including the calcining of natural aluminosilicates, the Czochralski process (synthesising mullite from melt), the Verneuil process (synthesising mullite from gel), and the solid state method (synthesising mullite from the mixture of stoichiometric composition). Previous studies have determined that the parameters of the orthorhombic lattice and the habitus of mullite crystals depend directly on the ratio of aluminum and silicon in the initial batch, the content of impurities, the method of heat treatment, and the form of introduction of the initial components into the batch. The size of the mullite crystals is affected by the presence of aluminum fl uoride in the batch, which at a certain ratios allows to obtain the fi nal product in the form of whiskers. The effect of mineralizers on the yield of mullite was considered: alkali metal fl uorides reduce the yield, while sulfates and chlorides increase it and also infl uence the viscosity and structure of the melt. In order to determine the effect, we studied the infl uence of various additives on the process, structure, and properties of the synthesis. Structural features of the mullite crystal lattice affecting isomorphic substitutions were determined. The paper also considers the possibility of obtaining isomorphically substituted mullite varieties, and presents the optical characteristics of isomorphically substituted mullite containing d-elements.
abstractGer	The phase diagram of SiO2-Al2O3 is considered. The paper presents an overview of the methods of synthesising mullite, including the calcining of natural aluminosilicates, the Czochralski process (synthesising mullite from melt), the Verneuil process (synthesising mullite from gel), and the solid state method (synthesising mullite from the mixture of stoichiometric composition). Previous studies have determined that the parameters of the orthorhombic lattice and the habitus of mullite crystals depend directly on the ratio of aluminum and silicon in the initial batch, the content of impurities, the method of heat treatment, and the form of introduction of the initial components into the batch. The size of the mullite crystals is affected by the presence of aluminum fl uoride in the batch, which at a certain ratios allows to obtain the fi nal product in the form of whiskers. The effect of mineralizers on the yield of mullite was considered: alkali metal fl uorides reduce the yield, while sulfates and chlorides increase it and also infl uence the viscosity and structure of the melt. In order to determine the effect, we studied the infl uence of various additives on the process, structure, and properties of the synthesis. Structural features of the mullite crystal lattice affecting isomorphic substitutions were determined. The paper also considers the possibility of obtaining isomorphically substituted mullite varieties, and presents the optical characteristics of isomorphically substituted mullite containing d-elements.
abstract_unstemmed	The phase diagram of SiO2-Al2O3 is considered. The paper presents an overview of the methods of synthesising mullite, including the calcining of natural aluminosilicates, the Czochralski process (synthesising mullite from melt), the Verneuil process (synthesising mullite from gel), and the solid state method (synthesising mullite from the mixture of stoichiometric composition). Previous studies have determined that the parameters of the orthorhombic lattice and the habitus of mullite crystals depend directly on the ratio of aluminum and silicon in the initial batch, the content of impurities, the method of heat treatment, and the form of introduction of the initial components into the batch. The size of the mullite crystals is affected by the presence of aluminum fl uoride in the batch, which at a certain ratios allows to obtain the fi nal product in the form of whiskers. The effect of mineralizers on the yield of mullite was considered: alkali metal fl uorides reduce the yield, while sulfates and chlorides increase it and also infl uence the viscosity and structure of the melt. In order to determine the effect, we studied the infl uence of various additives on the process, structure, and properties of the synthesis. Structural features of the mullite crystal lattice affecting isomorphic substitutions were determined. The paper also considers the possibility of obtaining isomorphically substituted mullite varieties, and presents the optical characteristics of isomorphically substituted mullite containing d-elements.
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title_short	MULLITE AND ITS ISOMORPHIC SUBSTITUTION OVERVIEW
url	https://doi.org/10.17308/kcmf.2018.20/626 https://doaj.org/article/7686b02ce5424de68c7bb39e976aa640 https://doaj.org/toc/1606-867X
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