A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc

Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigm...
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Autor*in:	Linzhen Hu [verfasserIn] Kongchao Wang [verfasserIn] Zhenzhen Wang [verfasserIn] Junjun Liu [verfasserIn] Kaiping Wang [verfasserIn] Jinwen Zhang [verfasserIn] Zengwei Luo [verfasserIn] Yongbo Xue [verfasserIn] Yu Zhang [verfasserIn] Yonghui Zhang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2016

Schlagwörter:	zanthoxylum schinifolium megastigmane sesquiterpenoid Kaposi’s sarcoma associated herpes virus

Übergeordnetes Werk:	In: Molecules - MDPI AG, 2003, 21(2016), 3, p 383
Übergeordnetes Werk:	volume:21 ; year:2016 ; number:3, p 383

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/molecules21030383

Katalog-ID:	DOAJ053643968

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allfields	10.3390/molecules21030383 doi (DE-627)DOAJ053643968 (DE-599)DOAJ6dd2738972e045d9b364f247641003ac DE-627 ger DE-627 rakwb eng QD241-441 Linzhen Hu verfasserin aut A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigmane sesquiterpenoid, which is referred to as schinifolenol A (1), was isolated from Z. schinifolium. The stereochemistry was characterized via the analyses of extensive spectra. The absolute configuration was established by the application of a modified Mosher’s experiment and assisted by a time-dependent density functional theory (TD-DFT) on calculated electronic circular dichroism (ECD). Bioactivity screenings showed that compound 1 exhibited a safe hypotoxicity and a better selectivity on anti-Kaposi’s sarcoma associated herpes virus (KSHV). zanthoxylum schinifolium megastigmane sesquiterpenoid Kaposi’s sarcoma associated herpes virus Organic chemistry Kongchao Wang verfasserin aut Zhenzhen Wang verfasserin aut Junjun Liu verfasserin aut Kaiping Wang verfasserin aut Jinwen Zhang verfasserin aut Zengwei Luo verfasserin aut Yongbo Xue verfasserin aut Yu Zhang verfasserin aut Yonghui Zhang verfasserin aut In Molecules MDPI AG, 2003 21(2016), 3, p 383 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:21 year:2016 number:3, p 383 https://doi.org/10.3390/molecules21030383 kostenfrei https://doaj.org/article/6dd2738972e045d9b364f247641003ac kostenfrei http://www.mdpi.com/1420-3049/21/3/383 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 21 2016 3, p 383
spelling	10.3390/molecules21030383 doi (DE-627)DOAJ053643968 (DE-599)DOAJ6dd2738972e045d9b364f247641003ac DE-627 ger DE-627 rakwb eng QD241-441 Linzhen Hu verfasserin aut A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigmane sesquiterpenoid, which is referred to as schinifolenol A (1), was isolated from Z. schinifolium. The stereochemistry was characterized via the analyses of extensive spectra. The absolute configuration was established by the application of a modified Mosher’s experiment and assisted by a time-dependent density functional theory (TD-DFT) on calculated electronic circular dichroism (ECD). Bioactivity screenings showed that compound 1 exhibited a safe hypotoxicity and a better selectivity on anti-Kaposi’s sarcoma associated herpes virus (KSHV). zanthoxylum schinifolium megastigmane sesquiterpenoid Kaposi’s sarcoma associated herpes virus Organic chemistry Kongchao Wang verfasserin aut Zhenzhen Wang verfasserin aut Junjun Liu verfasserin aut Kaiping Wang verfasserin aut Jinwen Zhang verfasserin aut Zengwei Luo verfasserin aut Yongbo Xue verfasserin aut Yu Zhang verfasserin aut Yonghui Zhang verfasserin aut In Molecules MDPI AG, 2003 21(2016), 3, p 383 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:21 year:2016 number:3, p 383 https://doi.org/10.3390/molecules21030383 kostenfrei https://doaj.org/article/6dd2738972e045d9b364f247641003ac kostenfrei http://www.mdpi.com/1420-3049/21/3/383 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 21 2016 3, p 383
allfields_unstemmed	10.3390/molecules21030383 doi (DE-627)DOAJ053643968 (DE-599)DOAJ6dd2738972e045d9b364f247641003ac DE-627 ger DE-627 rakwb eng QD241-441 Linzhen Hu verfasserin aut A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigmane sesquiterpenoid, which is referred to as schinifolenol A (1), was isolated from Z. schinifolium. The stereochemistry was characterized via the analyses of extensive spectra. The absolute configuration was established by the application of a modified Mosher’s experiment and assisted by a time-dependent density functional theory (TD-DFT) on calculated electronic circular dichroism (ECD). Bioactivity screenings showed that compound 1 exhibited a safe hypotoxicity and a better selectivity on anti-Kaposi’s sarcoma associated herpes virus (KSHV). zanthoxylum schinifolium megastigmane sesquiterpenoid Kaposi’s sarcoma associated herpes virus Organic chemistry Kongchao Wang verfasserin aut Zhenzhen Wang verfasserin aut Junjun Liu verfasserin aut Kaiping Wang verfasserin aut Jinwen Zhang verfasserin aut Zengwei Luo verfasserin aut Yongbo Xue verfasserin aut Yu Zhang verfasserin aut Yonghui Zhang verfasserin aut In Molecules MDPI AG, 2003 21(2016), 3, p 383 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:21 year:2016 number:3, p 383 https://doi.org/10.3390/molecules21030383 kostenfrei https://doaj.org/article/6dd2738972e045d9b364f247641003ac kostenfrei http://www.mdpi.com/1420-3049/21/3/383 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 21 2016 3, p 383
allfieldsGer	10.3390/molecules21030383 doi (DE-627)DOAJ053643968 (DE-599)DOAJ6dd2738972e045d9b364f247641003ac DE-627 ger DE-627 rakwb eng QD241-441 Linzhen Hu verfasserin aut A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigmane sesquiterpenoid, which is referred to as schinifolenol A (1), was isolated from Z. schinifolium. The stereochemistry was characterized via the analyses of extensive spectra. The absolute configuration was established by the application of a modified Mosher’s experiment and assisted by a time-dependent density functional theory (TD-DFT) on calculated electronic circular dichroism (ECD). Bioactivity screenings showed that compound 1 exhibited a safe hypotoxicity and a better selectivity on anti-Kaposi’s sarcoma associated herpes virus (KSHV). zanthoxylum schinifolium megastigmane sesquiterpenoid Kaposi’s sarcoma associated herpes virus Organic chemistry Kongchao Wang verfasserin aut Zhenzhen Wang verfasserin aut Junjun Liu verfasserin aut Kaiping Wang verfasserin aut Jinwen Zhang verfasserin aut Zengwei Luo verfasserin aut Yongbo Xue verfasserin aut Yu Zhang verfasserin aut Yonghui Zhang verfasserin aut In Molecules MDPI AG, 2003 21(2016), 3, p 383 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:21 year:2016 number:3, p 383 https://doi.org/10.3390/molecules21030383 kostenfrei https://doaj.org/article/6dd2738972e045d9b364f247641003ac kostenfrei http://www.mdpi.com/1420-3049/21/3/383 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 21 2016 3, p 383
allfieldsSound	10.3390/molecules21030383 doi (DE-627)DOAJ053643968 (DE-599)DOAJ6dd2738972e045d9b364f247641003ac DE-627 ger DE-627 rakwb eng QD241-441 Linzhen Hu verfasserin aut A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigmane sesquiterpenoid, which is referred to as schinifolenol A (1), was isolated from Z. schinifolium. The stereochemistry was characterized via the analyses of extensive spectra. The absolute configuration was established by the application of a modified Mosher’s experiment and assisted by a time-dependent density functional theory (TD-DFT) on calculated electronic circular dichroism (ECD). Bioactivity screenings showed that compound 1 exhibited a safe hypotoxicity and a better selectivity on anti-Kaposi’s sarcoma associated herpes virus (KSHV). zanthoxylum schinifolium megastigmane sesquiterpenoid Kaposi’s sarcoma associated herpes virus Organic chemistry Kongchao Wang verfasserin aut Zhenzhen Wang verfasserin aut Junjun Liu verfasserin aut Kaiping Wang verfasserin aut Jinwen Zhang verfasserin aut Zengwei Luo verfasserin aut Yongbo Xue verfasserin aut Yu Zhang verfasserin aut Yonghui Zhang verfasserin aut In Molecules MDPI AG, 2003 21(2016), 3, p 383 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:21 year:2016 number:3, p 383 https://doi.org/10.3390/molecules21030383 kostenfrei https://doaj.org/article/6dd2738972e045d9b364f247641003ac kostenfrei http://www.mdpi.com/1420-3049/21/3/383 kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 21 2016 3, p 383
language	English
source	In Molecules 21(2016), 3, p 383 volume:21 year:2016 number:3, p 383
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topic_facet	zanthoxylum schinifolium megastigmane sesquiterpenoid Kaposi’s sarcoma associated herpes virus Organic chemistry
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authorswithroles_txt_mv	Linzhen Hu @@aut@@ Kongchao Wang @@aut@@ Zhenzhen Wang @@aut@@ Junjun Liu @@aut@@ Kaiping Wang @@aut@@ Jinwen Zhang @@aut@@ Zengwei Luo @@aut@@ Yongbo Xue @@aut@@ Yu Zhang @@aut@@ Yonghui Zhang @@aut@@
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callnumber-first	Q - Science
author	Linzhen Hu
spellingShingle	Linzhen Hu misc QD241-441 misc zanthoxylum schinifolium misc megastigmane misc sesquiterpenoid misc Kaposi’s sarcoma associated herpes virus misc Organic chemistry A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc
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topic_title	QD241-441 A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc zanthoxylum schinifolium megastigmane sesquiterpenoid Kaposi’s sarcoma associated herpes virus
topic	misc QD241-441 misc zanthoxylum schinifolium misc megastigmane misc sesquiterpenoid misc Kaposi’s sarcoma associated herpes virus misc Organic chemistry
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title	A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc
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title_full	A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc
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title_sort	new megastigmane sesquiterpenoid from zanthoxylum schinifolium sieb. et zucc
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title_auth	A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc
abstract	Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigmane sesquiterpenoid, which is referred to as schinifolenol A (1), was isolated from Z. schinifolium. The stereochemistry was characterized via the analyses of extensive spectra. The absolute configuration was established by the application of a modified Mosher’s experiment and assisted by a time-dependent density functional theory (TD-DFT) on calculated electronic circular dichroism (ECD). Bioactivity screenings showed that compound 1 exhibited a safe hypotoxicity and a better selectivity on anti-Kaposi’s sarcoma associated herpes virus (KSHV).
abstractGer	Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigmane sesquiterpenoid, which is referred to as schinifolenol A (1), was isolated from Z. schinifolium. The stereochemistry was characterized via the analyses of extensive spectra. The absolute configuration was established by the application of a modified Mosher’s experiment and assisted by a time-dependent density functional theory (TD-DFT) on calculated electronic circular dichroism (ECD). Bioactivity screenings showed that compound 1 exhibited a safe hypotoxicity and a better selectivity on anti-Kaposi’s sarcoma associated herpes virus (KSHV).
abstract_unstemmed	Zanthoxylum schinifolium Sieb. et Zucc. (Rutaceae), a dioecious shrub with hooked prickly branches, has been used as folk medicine for the treatment of the common cold, stomach ache, diarrhea, and jaundice in China, Korea, and Japan. In our phytochemical investigations on this genus, a new megastigmane sesquiterpenoid, which is referred to as schinifolenol A (1), was isolated from Z. schinifolium. The stereochemistry was characterized via the analyses of extensive spectra. The absolute configuration was established by the application of a modified Mosher’s experiment and assisted by a time-dependent density functional theory (TD-DFT) on calculated electronic circular dichroism (ECD). Bioactivity screenings showed that compound 1 exhibited a safe hypotoxicity and a better selectivity on anti-Kaposi’s sarcoma associated herpes virus (KSHV).
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container_issue	3, p 383
title_short	A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc
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up_date	2024-07-03T18:47:30.931Z
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A New Megastigmane Sesquiterpenoid from Zanthoxylum Schinifolium Sieb. et Zucc

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