The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand

The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly...
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Gespeichert in:

Autor*in:	Stefan Krehl [verfasserIn] Diana Geißler [verfasserIn] Sylvia Hauke [verfasserIn] Oliver Kunz [verfasserIn] Lucia Staude [verfasserIn] Bernd Schmidt [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2010

Schlagwörter:	homogeneous catalysis N-heterocyclic carbenes olefin metathesis pyridine ligand Ruthenium carbene complexes

Übergeordnetes Werk:	In: Beilstein Journal of Organic Chemistry - Beilstein-Institut, 2005, 6(2010), 1, Seite 1188-1198
Übergeordnetes Werk:	volume:6 ; year:2010 ; number:1 ; pages:1188-1198

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3762/bjoc.6.136

Katalog-ID:	DOAJ056168276

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callnumber-first	Q - Science
author	Stefan Krehl
spellingShingle	Stefan Krehl misc QD241-441 misc homogeneous catalysis misc N-heterocyclic carbenes misc olefin metathesis misc pyridine ligand misc Ruthenium carbene complexes misc Science misc Q misc Organic chemistry The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand
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topic_title	QD241-441 The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand homogeneous catalysis N-heterocyclic carbenes olefin metathesis pyridine ligand Ruthenium carbene complexes
topic	misc QD241-441 misc homogeneous catalysis misc N-heterocyclic carbenes misc olefin metathesis misc pyridine ligand misc Ruthenium carbene complexes misc Science misc Q misc Organic chemistry
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title	The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand
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title_full	The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand
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title_sort	catalytic performance of ru–nhc alkylidene complexes: pcy3 versus pyridine as the dissociating ligand
callnumber	QD241-441
title_auth	The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand
abstract	The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions.
abstractGer	The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions.
abstract_unstemmed	The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions.
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title_short	The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand
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The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand

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