The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand
The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly...
Ausführliche Beschreibung
Autor*in: |
Stefan Krehl [verfasserIn] Diana Geißler [verfasserIn] Sylvia Hauke [verfasserIn] Oliver Kunz [verfasserIn] Lucia Staude [verfasserIn] Bernd Schmidt [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2010 |
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Übergeordnetes Werk: |
In: Beilstein Journal of Organic Chemistry - Beilstein-Institut, 2005, 6(2010), 1, Seite 1188-1198 |
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Übergeordnetes Werk: |
volume:6 ; year:2010 ; number:1 ; pages:1188-1198 |
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DOI / URN: |
10.3762/bjoc.6.136 |
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Katalog-ID: |
DOAJ056168276 |
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10.3762/bjoc.6.136 doi (DE-627)DOAJ056168276 (DE-599)DOAJed06104856df45b09b7bd23b370389b9 DE-627 ger DE-627 rakwb eng QD241-441 Stefan Krehl verfasserin aut The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions. homogeneous catalysis N-heterocyclic carbenes olefin metathesis pyridine ligand Ruthenium carbene complexes Science Q Organic chemistry Diana Geißler verfasserin aut Sylvia Hauke verfasserin aut Oliver Kunz verfasserin aut Lucia Staude verfasserin aut Bernd Schmidt verfasserin aut In Beilstein Journal of Organic Chemistry Beilstein-Institut, 2005 6(2010), 1, Seite 1188-1198 (DE-627)490226256 (DE-600)2192461-2 18605397 nnns volume:6 year:2010 number:1 pages:1188-1198 https://doi.org/10.3762/bjoc.6.136 kostenfrei https://doaj.org/article/ed06104856df45b09b7bd23b370389b9 kostenfrei https://doi.org/10.3762/bjoc.6.136 kostenfrei https://doaj.org/toc/1860-5397 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_267 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2010 1 1188-1198 |
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10.3762/bjoc.6.136 doi (DE-627)DOAJ056168276 (DE-599)DOAJed06104856df45b09b7bd23b370389b9 DE-627 ger DE-627 rakwb eng QD241-441 Stefan Krehl verfasserin aut The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions. homogeneous catalysis N-heterocyclic carbenes olefin metathesis pyridine ligand Ruthenium carbene complexes Science Q Organic chemistry Diana Geißler verfasserin aut Sylvia Hauke verfasserin aut Oliver Kunz verfasserin aut Lucia Staude verfasserin aut Bernd Schmidt verfasserin aut In Beilstein Journal of Organic Chemistry Beilstein-Institut, 2005 6(2010), 1, Seite 1188-1198 (DE-627)490226256 (DE-600)2192461-2 18605397 nnns volume:6 year:2010 number:1 pages:1188-1198 https://doi.org/10.3762/bjoc.6.136 kostenfrei https://doaj.org/article/ed06104856df45b09b7bd23b370389b9 kostenfrei https://doi.org/10.3762/bjoc.6.136 kostenfrei https://doaj.org/toc/1860-5397 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_267 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2010 1 1188-1198 |
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10.3762/bjoc.6.136 doi (DE-627)DOAJ056168276 (DE-599)DOAJed06104856df45b09b7bd23b370389b9 DE-627 ger DE-627 rakwb eng QD241-441 Stefan Krehl verfasserin aut The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions. homogeneous catalysis N-heterocyclic carbenes olefin metathesis pyridine ligand Ruthenium carbene complexes Science Q Organic chemistry Diana Geißler verfasserin aut Sylvia Hauke verfasserin aut Oliver Kunz verfasserin aut Lucia Staude verfasserin aut Bernd Schmidt verfasserin aut In Beilstein Journal of Organic Chemistry Beilstein-Institut, 2005 6(2010), 1, Seite 1188-1198 (DE-627)490226256 (DE-600)2192461-2 18605397 nnns volume:6 year:2010 number:1 pages:1188-1198 https://doi.org/10.3762/bjoc.6.136 kostenfrei https://doaj.org/article/ed06104856df45b09b7bd23b370389b9 kostenfrei https://doi.org/10.3762/bjoc.6.136 kostenfrei https://doaj.org/toc/1860-5397 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_267 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 6 2010 1 1188-1198 |
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QD241-441 The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand homogeneous catalysis N-heterocyclic carbenes olefin metathesis pyridine ligand Ruthenium carbene complexes |
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The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand |
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The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions. |
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The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions. |
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The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions. |
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The catalytic performance of Ru–NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand |
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score |
7.3996973 |