Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes

Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage syste...
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Gespeichert in:

Autor*in:	Ashish Rudola [verfasserIn] Christopher J. Wright [verfasserIn] Jerry Barker [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2022

Schlagwörter:	bipolar battery sodium-ion battery bipolar Na-ion battery high voltage batteries bipolar electrodes beyond 5 V battery

Übergeordnetes Werk:	In: Frontiers in Energy Research - Frontiers Media S.A., 2014, 10(2022)
Übergeordnetes Werk:	volume:10 ; year:2022

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3389/fenrg.2022.852630

Katalog-ID:	DOAJ058344136

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allfields	10.3389/fenrg.2022.852630 doi (DE-627)DOAJ058344136 (DE-599)DOAJ7e1a791e93304f0f815a806ea574ce4b DE-627 ger DE-627 rakwb eng Ashish Rudola verfasserin aut Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage systems irrespective of the voltage of the cathode//anode couple used. The sodium-ion battery, being well-suited for the bipolar concept, is now rapidly being commercialized and has higher energy densities than most rechargeable battery technologies. However, bipolar sodium-ion batteries using commercially-feasible liquid electrolytes and manufacturing methodologies, have not been demonstrated at scale yet. Herein, we explore the design methodology needed to enable commercial realization of such bipolar sodium-ion batteries, using liquid electrolytes and different types of cathode//anode couples. We show good cycling stabilities over 200 cycles and potential for voltages beyond 6 V for bipolar Na-ion pouch cells. We also introduce a scalable method to fabricate nSmP Na-ion/mixed-chemistry bipolar cells (n cells in series; m cells in parallel) in a single, sealed cell. Our results point to realistic promise for high voltage and sustainable bipolar sodium-ion batteries. bipolar battery sodium-ion battery bipolar Na-ion battery high voltage batteries bipolar electrodes beyond 5 V battery General Works A Christopher J. Wright verfasserin aut Jerry Barker verfasserin aut In Frontiers in Energy Research Frontiers Media S.A., 2014 10(2022) (DE-627)768576768 (DE-600)2733788-1 2296598X nnns volume:10 year:2022 https://doi.org/10.3389/fenrg.2022.852630 kostenfrei https://doaj.org/article/7e1a791e93304f0f815a806ea574ce4b kostenfrei https://www.frontiersin.org/articles/10.3389/fenrg.2022.852630/full kostenfrei https://doaj.org/toc/2296-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2022
spelling	10.3389/fenrg.2022.852630 doi (DE-627)DOAJ058344136 (DE-599)DOAJ7e1a791e93304f0f815a806ea574ce4b DE-627 ger DE-627 rakwb eng Ashish Rudola verfasserin aut Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage systems irrespective of the voltage of the cathode//anode couple used. The sodium-ion battery, being well-suited for the bipolar concept, is now rapidly being commercialized and has higher energy densities than most rechargeable battery technologies. However, bipolar sodium-ion batteries using commercially-feasible liquid electrolytes and manufacturing methodologies, have not been demonstrated at scale yet. Herein, we explore the design methodology needed to enable commercial realization of such bipolar sodium-ion batteries, using liquid electrolytes and different types of cathode//anode couples. We show good cycling stabilities over 200 cycles and potential for voltages beyond 6 V for bipolar Na-ion pouch cells. We also introduce a scalable method to fabricate nSmP Na-ion/mixed-chemistry bipolar cells (n cells in series; m cells in parallel) in a single, sealed cell. Our results point to realistic promise for high voltage and sustainable bipolar sodium-ion batteries. bipolar battery sodium-ion battery bipolar Na-ion battery high voltage batteries bipolar electrodes beyond 5 V battery General Works A Christopher J. Wright verfasserin aut Jerry Barker verfasserin aut In Frontiers in Energy Research Frontiers Media S.A., 2014 10(2022) (DE-627)768576768 (DE-600)2733788-1 2296598X nnns volume:10 year:2022 https://doi.org/10.3389/fenrg.2022.852630 kostenfrei https://doaj.org/article/7e1a791e93304f0f815a806ea574ce4b kostenfrei https://www.frontiersin.org/articles/10.3389/fenrg.2022.852630/full kostenfrei https://doaj.org/toc/2296-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2022
allfields_unstemmed	10.3389/fenrg.2022.852630 doi (DE-627)DOAJ058344136 (DE-599)DOAJ7e1a791e93304f0f815a806ea574ce4b DE-627 ger DE-627 rakwb eng Ashish Rudola verfasserin aut Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage systems irrespective of the voltage of the cathode//anode couple used. The sodium-ion battery, being well-suited for the bipolar concept, is now rapidly being commercialized and has higher energy densities than most rechargeable battery technologies. However, bipolar sodium-ion batteries using commercially-feasible liquid electrolytes and manufacturing methodologies, have not been demonstrated at scale yet. Herein, we explore the design methodology needed to enable commercial realization of such bipolar sodium-ion batteries, using liquid electrolytes and different types of cathode//anode couples. We show good cycling stabilities over 200 cycles and potential for voltages beyond 6 V for bipolar Na-ion pouch cells. We also introduce a scalable method to fabricate nSmP Na-ion/mixed-chemistry bipolar cells (n cells in series; m cells in parallel) in a single, sealed cell. Our results point to realistic promise for high voltage and sustainable bipolar sodium-ion batteries. bipolar battery sodium-ion battery bipolar Na-ion battery high voltage batteries bipolar electrodes beyond 5 V battery General Works A Christopher J. Wright verfasserin aut Jerry Barker verfasserin aut In Frontiers in Energy Research Frontiers Media S.A., 2014 10(2022) (DE-627)768576768 (DE-600)2733788-1 2296598X nnns volume:10 year:2022 https://doi.org/10.3389/fenrg.2022.852630 kostenfrei https://doaj.org/article/7e1a791e93304f0f815a806ea574ce4b kostenfrei https://www.frontiersin.org/articles/10.3389/fenrg.2022.852630/full kostenfrei https://doaj.org/toc/2296-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2022
allfieldsGer	10.3389/fenrg.2022.852630 doi (DE-627)DOAJ058344136 (DE-599)DOAJ7e1a791e93304f0f815a806ea574ce4b DE-627 ger DE-627 rakwb eng Ashish Rudola verfasserin aut Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage systems irrespective of the voltage of the cathode//anode couple used. The sodium-ion battery, being well-suited for the bipolar concept, is now rapidly being commercialized and has higher energy densities than most rechargeable battery technologies. However, bipolar sodium-ion batteries using commercially-feasible liquid electrolytes and manufacturing methodologies, have not been demonstrated at scale yet. Herein, we explore the design methodology needed to enable commercial realization of such bipolar sodium-ion batteries, using liquid electrolytes and different types of cathode//anode couples. We show good cycling stabilities over 200 cycles and potential for voltages beyond 6 V for bipolar Na-ion pouch cells. We also introduce a scalable method to fabricate nSmP Na-ion/mixed-chemistry bipolar cells (n cells in series; m cells in parallel) in a single, sealed cell. Our results point to realistic promise for high voltage and sustainable bipolar sodium-ion batteries. bipolar battery sodium-ion battery bipolar Na-ion battery high voltage batteries bipolar electrodes beyond 5 V battery General Works A Christopher J. Wright verfasserin aut Jerry Barker verfasserin aut In Frontiers in Energy Research Frontiers Media S.A., 2014 10(2022) (DE-627)768576768 (DE-600)2733788-1 2296598X nnns volume:10 year:2022 https://doi.org/10.3389/fenrg.2022.852630 kostenfrei https://doaj.org/article/7e1a791e93304f0f815a806ea574ce4b kostenfrei https://www.frontiersin.org/articles/10.3389/fenrg.2022.852630/full kostenfrei https://doaj.org/toc/2296-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2022
allfieldsSound	10.3389/fenrg.2022.852630 doi (DE-627)DOAJ058344136 (DE-599)DOAJ7e1a791e93304f0f815a806ea574ce4b DE-627 ger DE-627 rakwb eng Ashish Rudola verfasserin aut Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes 2022 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage systems irrespective of the voltage of the cathode//anode couple used. The sodium-ion battery, being well-suited for the bipolar concept, is now rapidly being commercialized and has higher energy densities than most rechargeable battery technologies. However, bipolar sodium-ion batteries using commercially-feasible liquid electrolytes and manufacturing methodologies, have not been demonstrated at scale yet. Herein, we explore the design methodology needed to enable commercial realization of such bipolar sodium-ion batteries, using liquid electrolytes and different types of cathode//anode couples. We show good cycling stabilities over 200 cycles and potential for voltages beyond 6 V for bipolar Na-ion pouch cells. We also introduce a scalable method to fabricate nSmP Na-ion/mixed-chemistry bipolar cells (n cells in series; m cells in parallel) in a single, sealed cell. Our results point to realistic promise for high voltage and sustainable bipolar sodium-ion batteries. bipolar battery sodium-ion battery bipolar Na-ion battery high voltage batteries bipolar electrodes beyond 5 V battery General Works A Christopher J. Wright verfasserin aut Jerry Barker verfasserin aut In Frontiers in Energy Research Frontiers Media S.A., 2014 10(2022) (DE-627)768576768 (DE-600)2733788-1 2296598X nnns volume:10 year:2022 https://doi.org/10.3389/fenrg.2022.852630 kostenfrei https://doaj.org/article/7e1a791e93304f0f815a806ea574ce4b kostenfrei https://www.frontiersin.org/articles/10.3389/fenrg.2022.852630/full kostenfrei https://doaj.org/toc/2296-598X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2003 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 10 2022
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author	Ashish Rudola
spellingShingle	Ashish Rudola misc bipolar battery misc sodium-ion battery misc bipolar Na-ion battery misc high voltage batteries misc bipolar electrodes misc beyond 5 V battery misc General Works misc A Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes
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topic_title	Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes bipolar battery sodium-ion battery bipolar Na-ion battery high voltage batteries bipolar electrodes beyond 5 V battery
topic	misc bipolar battery misc sodium-ion battery misc bipolar Na-ion battery misc high voltage batteries misc bipolar electrodes misc beyond 5 V battery misc General Works misc A
topic_unstemmed	misc bipolar battery misc sodium-ion battery misc bipolar Na-ion battery misc high voltage batteries misc bipolar electrodes misc beyond 5 V battery misc General Works misc A
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title	Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes
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title_full	Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes
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title_sort	explorations into the viability of high voltage bipolar na-ion cells using liquid electrolytes
title_auth	Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes
abstract	Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage systems irrespective of the voltage of the cathode//anode couple used. The sodium-ion battery, being well-suited for the bipolar concept, is now rapidly being commercialized and has higher energy densities than most rechargeable battery technologies. However, bipolar sodium-ion batteries using commercially-feasible liquid electrolytes and manufacturing methodologies, have not been demonstrated at scale yet. Herein, we explore the design methodology needed to enable commercial realization of such bipolar sodium-ion batteries, using liquid electrolytes and different types of cathode//anode couples. We show good cycling stabilities over 200 cycles and potential for voltages beyond 6 V for bipolar Na-ion pouch cells. We also introduce a scalable method to fabricate nSmP Na-ion/mixed-chemistry bipolar cells (n cells in series; m cells in parallel) in a single, sealed cell. Our results point to realistic promise for high voltage and sustainable bipolar sodium-ion batteries.
abstractGer	Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage systems irrespective of the voltage of the cathode//anode couple used. The sodium-ion battery, being well-suited for the bipolar concept, is now rapidly being commercialized and has higher energy densities than most rechargeable battery technologies. However, bipolar sodium-ion batteries using commercially-feasible liquid electrolytes and manufacturing methodologies, have not been demonstrated at scale yet. Herein, we explore the design methodology needed to enable commercial realization of such bipolar sodium-ion batteries, using liquid electrolytes and different types of cathode//anode couples. We show good cycling stabilities over 200 cycles and potential for voltages beyond 6 V for bipolar Na-ion pouch cells. We also introduce a scalable method to fabricate nSmP Na-ion/mixed-chemistry bipolar cells (n cells in series; m cells in parallel) in a single, sealed cell. Our results point to realistic promise for high voltage and sustainable bipolar sodium-ion batteries.
abstract_unstemmed	Bipolar electrodes can be defined as electrodes where cathode and anode active materials exist on either side of a shared current collector substrate. The resultant rechargeable bipolar batteries, using series-connected electrochemical cells within one sealed enclosure, can enable high-voltage systems irrespective of the voltage of the cathode//anode couple used. The sodium-ion battery, being well-suited for the bipolar concept, is now rapidly being commercialized and has higher energy densities than most rechargeable battery technologies. However, bipolar sodium-ion batteries using commercially-feasible liquid electrolytes and manufacturing methodologies, have not been demonstrated at scale yet. Herein, we explore the design methodology needed to enable commercial realization of such bipolar sodium-ion batteries, using liquid electrolytes and different types of cathode//anode couples. We show good cycling stabilities over 200 cycles and potential for voltages beyond 6 V for bipolar Na-ion pouch cells. We also introduce a scalable method to fabricate nSmP Na-ion/mixed-chemistry bipolar cells (n cells in series; m cells in parallel) in a single, sealed cell. Our results point to realistic promise for high voltage and sustainable bipolar sodium-ion batteries.
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title_short	Explorations Into the Viability of High Voltage Bipolar Na-Ion Cells Using Liquid Electrolytes
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