Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid
The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<...
Ausführliche Beschreibung
Autor*in: |
Monika Kalinowska [verfasserIn] Ewelina Gołębiewska [verfasserIn] Liliana Mazur [verfasserIn] Hanna Lewandowska [verfasserIn] Marek Pruszyński [verfasserIn] Grzegorz Świderski [verfasserIn] Marta Wyrwas [verfasserIn] Natalia Pawluczuk [verfasserIn] Włodzimierz Lewandowski [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2021 |
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Übergeordnetes Werk: |
In: Materials - MDPI AG, 2009, 14(2021), 12, p 3236 |
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Übergeordnetes Werk: |
volume:14 ; year:2021 ; number:12, p 3236 |
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DOI / URN: |
10.3390/ma14123236 |
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Katalog-ID: |
DOAJ058775641 |
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520 | |a The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). | ||
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10.3390/ma14123236 doi (DE-627)DOAJ058775641 (DE-599)DOAJ15c4ef4bc25c4920bb0a706697672c57 DE-627 ger DE-627 rakwb eng TK1-9971 TA1-2040 QH201-278.5 QC120-168.85 Monika Kalinowska verfasserin aut Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). plant phenolic compounds metal complexes 3-hydroxy-4-methoxycinnamic acid isoferulic acid magnesium manganese Technology T Electrical engineering. Electronics. Nuclear engineering Engineering (General). Civil engineering (General) Microscopy Descriptive and experimental mechanics Ewelina Gołębiewska verfasserin aut Liliana Mazur verfasserin aut Hanna Lewandowska verfasserin aut Marek Pruszyński verfasserin aut Grzegorz Świderski verfasserin aut Marta Wyrwas verfasserin aut Natalia Pawluczuk verfasserin aut Włodzimierz Lewandowski verfasserin aut In Materials MDPI AG, 2009 14(2021), 12, p 3236 (DE-627)595712649 (DE-600)2487261-1 19961944 nnns volume:14 year:2021 number:12, p 3236 https://doi.org/10.3390/ma14123236 kostenfrei https://doaj.org/article/15c4ef4bc25c4920bb0a706697672c57 kostenfrei https://www.mdpi.com/1996-1944/14/12/3236 kostenfrei https://doaj.org/toc/1996-1944 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2021 12, p 3236 |
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10.3390/ma14123236 doi (DE-627)DOAJ058775641 (DE-599)DOAJ15c4ef4bc25c4920bb0a706697672c57 DE-627 ger DE-627 rakwb eng TK1-9971 TA1-2040 QH201-278.5 QC120-168.85 Monika Kalinowska verfasserin aut Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). plant phenolic compounds metal complexes 3-hydroxy-4-methoxycinnamic acid isoferulic acid magnesium manganese Technology T Electrical engineering. Electronics. Nuclear engineering Engineering (General). Civil engineering (General) Microscopy Descriptive and experimental mechanics Ewelina Gołębiewska verfasserin aut Liliana Mazur verfasserin aut Hanna Lewandowska verfasserin aut Marek Pruszyński verfasserin aut Grzegorz Świderski verfasserin aut Marta Wyrwas verfasserin aut Natalia Pawluczuk verfasserin aut Włodzimierz Lewandowski verfasserin aut In Materials MDPI AG, 2009 14(2021), 12, p 3236 (DE-627)595712649 (DE-600)2487261-1 19961944 nnns volume:14 year:2021 number:12, p 3236 https://doi.org/10.3390/ma14123236 kostenfrei https://doaj.org/article/15c4ef4bc25c4920bb0a706697672c57 kostenfrei https://www.mdpi.com/1996-1944/14/12/3236 kostenfrei https://doaj.org/toc/1996-1944 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2021 12, p 3236 |
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10.3390/ma14123236 doi (DE-627)DOAJ058775641 (DE-599)DOAJ15c4ef4bc25c4920bb0a706697672c57 DE-627 ger DE-627 rakwb eng TK1-9971 TA1-2040 QH201-278.5 QC120-168.85 Monika Kalinowska verfasserin aut Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). plant phenolic compounds metal complexes 3-hydroxy-4-methoxycinnamic acid isoferulic acid magnesium manganese Technology T Electrical engineering. Electronics. Nuclear engineering Engineering (General). Civil engineering (General) Microscopy Descriptive and experimental mechanics Ewelina Gołębiewska verfasserin aut Liliana Mazur verfasserin aut Hanna Lewandowska verfasserin aut Marek Pruszyński verfasserin aut Grzegorz Świderski verfasserin aut Marta Wyrwas verfasserin aut Natalia Pawluczuk verfasserin aut Włodzimierz Lewandowski verfasserin aut In Materials MDPI AG, 2009 14(2021), 12, p 3236 (DE-627)595712649 (DE-600)2487261-1 19961944 nnns volume:14 year:2021 number:12, p 3236 https://doi.org/10.3390/ma14123236 kostenfrei https://doaj.org/article/15c4ef4bc25c4920bb0a706697672c57 kostenfrei https://www.mdpi.com/1996-1944/14/12/3236 kostenfrei https://doaj.org/toc/1996-1944 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2021 12, p 3236 |
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10.3390/ma14123236 doi (DE-627)DOAJ058775641 (DE-599)DOAJ15c4ef4bc25c4920bb0a706697672c57 DE-627 ger DE-627 rakwb eng TK1-9971 TA1-2040 QH201-278.5 QC120-168.85 Monika Kalinowska verfasserin aut Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). plant phenolic compounds metal complexes 3-hydroxy-4-methoxycinnamic acid isoferulic acid magnesium manganese Technology T Electrical engineering. Electronics. Nuclear engineering Engineering (General). Civil engineering (General) Microscopy Descriptive and experimental mechanics Ewelina Gołębiewska verfasserin aut Liliana Mazur verfasserin aut Hanna Lewandowska verfasserin aut Marek Pruszyński verfasserin aut Grzegorz Świderski verfasserin aut Marta Wyrwas verfasserin aut Natalia Pawluczuk verfasserin aut Włodzimierz Lewandowski verfasserin aut In Materials MDPI AG, 2009 14(2021), 12, p 3236 (DE-627)595712649 (DE-600)2487261-1 19961944 nnns volume:14 year:2021 number:12, p 3236 https://doi.org/10.3390/ma14123236 kostenfrei https://doaj.org/article/15c4ef4bc25c4920bb0a706697672c57 kostenfrei https://www.mdpi.com/1996-1944/14/12/3236 kostenfrei https://doaj.org/toc/1996-1944 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2021 12, p 3236 |
allfieldsSound |
10.3390/ma14123236 doi (DE-627)DOAJ058775641 (DE-599)DOAJ15c4ef4bc25c4920bb0a706697672c57 DE-627 ger DE-627 rakwb eng TK1-9971 TA1-2040 QH201-278.5 QC120-168.85 Monika Kalinowska verfasserin aut Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). plant phenolic compounds metal complexes 3-hydroxy-4-methoxycinnamic acid isoferulic acid magnesium manganese Technology T Electrical engineering. Electronics. Nuclear engineering Engineering (General). Civil engineering (General) Microscopy Descriptive and experimental mechanics Ewelina Gołębiewska verfasserin aut Liliana Mazur verfasserin aut Hanna Lewandowska verfasserin aut Marek Pruszyński verfasserin aut Grzegorz Świderski verfasserin aut Marta Wyrwas verfasserin aut Natalia Pawluczuk verfasserin aut Włodzimierz Lewandowski verfasserin aut In Materials MDPI AG, 2009 14(2021), 12, p 3236 (DE-627)595712649 (DE-600)2487261-1 19961944 nnns volume:14 year:2021 number:12, p 3236 https://doi.org/10.3390/ma14123236 kostenfrei https://doaj.org/article/15c4ef4bc25c4920bb0a706697672c57 kostenfrei https://www.mdpi.com/1996-1944/14/12/3236 kostenfrei https://doaj.org/toc/1996-1944 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 14 2021 12, p 3236 |
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Monika Kalinowska @@aut@@ Ewelina Gołębiewska @@aut@@ Liliana Mazur @@aut@@ Hanna Lewandowska @@aut@@ Marek Pruszyński @@aut@@ Grzegorz Świderski @@aut@@ Marta Wyrwas @@aut@@ Natalia Pawluczuk @@aut@@ Włodzimierz Lewandowski @@aut@@ |
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The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. 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Monika Kalinowska |
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Monika Kalinowska misc TK1-9971 misc TA1-2040 misc QH201-278.5 misc QC120-168.85 misc plant phenolic compounds misc metal complexes misc 3-hydroxy-4-methoxycinnamic acid misc isoferulic acid misc magnesium misc manganese misc Technology misc T misc Electrical engineering. Electronics. Nuclear engineering misc Engineering (General). Civil engineering (General) misc Microscopy misc Descriptive and experimental mechanics Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid |
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TK1-9971 TA1-2040 QH201-278.5 QC120-168.85 Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid plant phenolic compounds metal complexes 3-hydroxy-4-methoxycinnamic acid isoferulic acid magnesium manganese |
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misc TK1-9971 misc TA1-2040 misc QH201-278.5 misc QC120-168.85 misc plant phenolic compounds misc metal complexes misc 3-hydroxy-4-methoxycinnamic acid misc isoferulic acid misc magnesium misc manganese misc Technology misc T misc Electrical engineering. Electronics. Nuclear engineering misc Engineering (General). Civil engineering (General) misc Microscopy misc Descriptive and experimental mechanics |
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misc TK1-9971 misc TA1-2040 misc QH201-278.5 misc QC120-168.85 misc plant phenolic compounds misc metal complexes misc 3-hydroxy-4-methoxycinnamic acid misc isoferulic acid misc magnesium misc manganese misc Technology misc T misc Electrical engineering. Electronics. Nuclear engineering misc Engineering (General). Civil engineering (General) misc Microscopy misc Descriptive and experimental mechanics |
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Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid |
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Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid |
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Monika Kalinowska Ewelina Gołębiewska Liliana Mazur Hanna Lewandowska Marek Pruszyński Grzegorz Świderski Marta Wyrwas Natalia Pawluczuk Włodzimierz Lewandowski |
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crystal structure, spectroscopic characterization, antioxidant and cytotoxic activity of new mg(ii) and mn(ii)/na(i) complexes of isoferulic acid |
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TK1-9971 |
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Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid |
abstract |
The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). |
abstractGer |
The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). |
abstract_unstemmed |
The Mg(II) and heterometallic Mn(II)/Na(I) complexes of isoferulic acid (3-hydroxy-4-methoxycinnamic acid, IFA) were synthesized and characterized by infrared spectroscopy FT-IR, FT-Raman, electronic absorption spectroscopy UV/VIS, and single-crystal X-ray diffraction. The reaction of MgCl<sub<2</sub< with isoferulic acid in the aqueous solutions of NaOH resulted in synthesis of the complex salt of the general formula of [Mg(H<sub<2</sub<O)<sub<6</sub<]⋅(C<sub<10</sub<H<sub<9</sub<O<sub<4</sub<)<sub<2</sub<⋅6H<sub<2</sub<O. The crystal structure of this compound consists of discrete octahedral [Mg(H<sub<2</sub<O)<sub<6</sub<]<sup<2+</sup< cations, isoferulic acid anions and solvent water molecules. The hydrated metal cations are arranged among the organic layers. The multiple hydrogen-bonding interactions established between the coordinated and lattice water molecules and the functional groups of the ligand stabilize the 3D architecture of the crystal. The use of MnCl<sub<2</sub< instead of MgCl<sub<2</sub< led to the formation of the Mn(II)/Na(I) complex of the general formula [Mn<sub<3</sub<Na<sub<2</sub<(C<sub<10</sub<H<sub<7</sub<O<sub<4</sub<)<sub<8</sub<(H<sub<2</sub<O)<sub<8</sub<]. The compound is a 3D coordination polymer composed of centrosymmetric pentanuclear subunits. The antioxidant activity of these compounds was evaluated by assays based on different antioxidant mechanisms of action, i.e., with <sup<•</sup<OH, DPPH<sup<•</sup< and ABTS<sup<•+</sup< radicals as well as CUPRAC (cupric ions reducing power) and lipid peroxidation inhibition assays. The pro-oxidant property of compounds was measured as the rate of oxidation of Trolox. The Mg(II) and Mn(II)/Na(I) complexes with isoferulic acid showed higher antioxidant activity than ligand alone in DPPH (IFA, IC<sub<50</sub< = 365.27 μM, Mg(II) IFA IC<sub<50</sub< = 153.50 μM, Mn(II)/Na(I) IFA IC<sub<50</sub< = 149.00 μM) and CUPRAC assays (IFA 40.92 μM of Trolox, Mg(II) IFA 87.93 μM and Mn(II)/Na(I) IFA 105.85 μM of Trolox; for compounds’ concentration 10 μM). Mg(II) IFA is a better scavenger of <sup<•</sup<OH than IFA and Mn(II)/Na(I) IFA complex. There was no distinct difference in ABTS<sup<•+</sup< and lipid peroxidation assays between isoferulic acid and its Mg(II) complex, while Mn(II)/Na(I) complex showed lower activity than these compounds. The tested complexes displayed only slight antiproliferative activity tested in HaCaT human immortalized keratinocyte cell line within the solubility range. The Mn(II)/Na(I) IFA (16 μM in medium) caused an 87% (±5%) decrease in cell viability, the Mg salt caused a comparable, i.e., 87% (±4%) viability decrease in a concentration of 45 μM, while IFA caused this level of cell activity attenuation (87% ± 5%) at the concentration of 1582 μM (significant at α = 0.05). |
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container_issue |
12, p 3236 |
title_short |
Crystal Structure, Spectroscopic Characterization, Antioxidant and Cytotoxic Activity of New Mg(II) and Mn(II)/Na(I) Complexes of Isoferulic Acid |
url |
https://doi.org/10.3390/ma14123236 https://doaj.org/article/15c4ef4bc25c4920bb0a706697672c57 https://www.mdpi.com/1996-1944/14/12/3236 https://doaj.org/toc/1996-1944 |
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author2 |
Ewelina Gołębiewska Liliana Mazur Hanna Lewandowska Marek Pruszyński Grzegorz Świderski Marta Wyrwas Natalia Pawluczuk Włodzimierz Lewandowski |
author2Str |
Ewelina Gołębiewska Liliana Mazur Hanna Lewandowska Marek Pruszyński Grzegorz Świderski Marta Wyrwas Natalia Pawluczuk Włodzimierz Lewandowski |
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doi_str |
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up_date |
2024-07-03T20:00:41.026Z |
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|
score |
7.40007 |