Antimony and antimony oxidegraphene oxide obtained by the peroxide route as anodes for lithium-ion batteries

Zero-valent antimony and antimony oxide were deposited on graphene oxide by the recently introduced peroxide deposition route. The antimonygraphene oxide (GO) anode exhibits a charging capacity of 340 mAh g-1 with excellent stability at a current rate of 250 mA g-1 after 50 cycles of lithiation, whi...
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Autor*in:	Yu Denis Y.W. [verfasserIn] Batabyal Sudip K. [verfasserIn] Gun Jenny [verfasserIn] Sladkevich Sergey [verfasserIn] Mikhaylov Alexey A. [verfasserIn] Medvedev Alexander G. [verfasserIn] Novotortsev Vladimir M. [verfasserIn] Lev Ovadia [verfasserIn] Prikhodchenko Petr V. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2015

Schlagwörter:	antimony antimony oxide hydroperoxoantimonate lithium-ion battery reduced graphene oxide

Übergeordnetes Werk:	In: Main Group Metal Chemistry - De Gruyter, 2019, 38(2015), 1-2, Seite 43-50
Übergeordnetes Werk:	volume:38 ; year:2015 ; number:1-2 ; pages:43-50

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc Journal toc

DOI / URN:	10.1515/mgmc-2015-0001

Katalog-ID:	DOAJ061014737

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topic_facet	antimony antimony oxide hydroperoxoantimonate lithium-ion battery reduced graphene oxide Chemistry
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authorswithroles_txt_mv	Yu Denis Y.W. @@aut@@ Batabyal Sudip K. @@aut@@ Gun Jenny @@aut@@ Sladkevich Sergey @@aut@@ Mikhaylov Alexey A. @@aut@@ Medvedev Alexander G. @@aut@@ Novotortsev Vladimir M. @@aut@@ Lev Ovadia @@aut@@ Prikhodchenko Petr V. @@aut@@
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callnumber-first	Q - Science
author	Yu Denis Y.W.
spellingShingle	Yu Denis Y.W. misc QD1-999 misc antimony misc antimony oxide misc hydroperoxoantimonate misc lithium-ion battery misc reduced graphene oxide misc Chemistry Antimony and antimony oxidegraphene oxide obtained by the peroxide route as anodes for lithium-ion batteries
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topic_title	QD1-999 Antimony and antimony oxidegraphene oxide obtained by the peroxide route as anodes for lithium-ion batteries antimony antimony oxide hydroperoxoantimonate lithium-ion battery reduced graphene oxide
topic	misc QD1-999 misc antimony misc antimony oxide misc hydroperoxoantimonate misc lithium-ion battery misc reduced graphene oxide misc Chemistry
topic_unstemmed	misc QD1-999 misc antimony misc antimony oxide misc hydroperoxoantimonate misc lithium-ion battery misc reduced graphene oxide misc Chemistry
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title	Antimony and antimony oxidegraphene oxide obtained by the peroxide route as anodes for lithium-ion batteries
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title_full	Antimony and antimony oxidegraphene oxide obtained by the peroxide route as anodes for lithium-ion batteries
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author_browse	Yu Denis Y.W. Batabyal Sudip K. Gun Jenny Sladkevich Sergey Mikhaylov Alexey A. Medvedev Alexander G. Novotortsev Vladimir M. Lev Ovadia Prikhodchenko Petr V.
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title_sort	and antimony oxidegraphene oxide obtained by the peroxide route as anodes for lithium-ion batteries
callnumber	QD1-999
title_auth	Antimony and antimony oxidegraphene oxide obtained by the peroxide route as anodes for lithium-ion batteries
abstract	Zero-valent antimony and antimony oxide were deposited on graphene oxide by the recently introduced peroxide deposition route. The antimonygraphene oxide (GO) anode exhibits a charging capacity of 340 mAh g-1 with excellent stability at a current rate of 250 mA g-1 after 50 cycles of lithiation, which is superior to all other forms of antimony anodes that have been reported thus far. The electrode also exhibits a good rate performance, with a capacity of 230 and 180 mAh g-1 at a rate of 500 and 1000 mA g-1, respectively. We attribute the superior performance of the antimony@GO anodes to our coating protocol, which provides a thin layer of nanometric antimony coating on the graphene oxide, and to a small amount of antimony oxide that is left in the anode material after heat treatment and imparts some flexibility. The efficient charge distribution by the large surface area of reduced GO and the expansion buffering of the elastic graphene sheets also contributed to the superior stability of the anode.
abstractGer	Zero-valent antimony and antimony oxide were deposited on graphene oxide by the recently introduced peroxide deposition route. The antimonygraphene oxide (GO) anode exhibits a charging capacity of 340 mAh g-1 with excellent stability at a current rate of 250 mA g-1 after 50 cycles of lithiation, which is superior to all other forms of antimony anodes that have been reported thus far. The electrode also exhibits a good rate performance, with a capacity of 230 and 180 mAh g-1 at a rate of 500 and 1000 mA g-1, respectively. We attribute the superior performance of the antimony@GO anodes to our coating protocol, which provides a thin layer of nanometric antimony coating on the graphene oxide, and to a small amount of antimony oxide that is left in the anode material after heat treatment and imparts some flexibility. The efficient charge distribution by the large surface area of reduced GO and the expansion buffering of the elastic graphene sheets also contributed to the superior stability of the anode.
abstract_unstemmed	Zero-valent antimony and antimony oxide were deposited on graphene oxide by the recently introduced peroxide deposition route. The antimonygraphene oxide (GO) anode exhibits a charging capacity of 340 mAh g-1 with excellent stability at a current rate of 250 mA g-1 after 50 cycles of lithiation, which is superior to all other forms of antimony anodes that have been reported thus far. The electrode also exhibits a good rate performance, with a capacity of 230 and 180 mAh g-1 at a rate of 500 and 1000 mA g-1, respectively. We attribute the superior performance of the antimony@GO anodes to our coating protocol, which provides a thin layer of nanometric antimony coating on the graphene oxide, and to a small amount of antimony oxide that is left in the anode material after heat treatment and imparts some flexibility. The efficient charge distribution by the large surface area of reduced GO and the expansion buffering of the elastic graphene sheets also contributed to the superior stability of the anode.
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title_short	Antimony and antimony oxidegraphene oxide obtained by the peroxide route as anodes for lithium-ion batteries
url	https://doi.org/10.1515/mgmc-2015-0001 https://doaj.org/article/90324aec3766404892ae85b07c96b376 https://doaj.org/toc/0792-1241 https://doaj.org/toc/2191-0219
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