The Influence Mechanism of Temperature and Storage Period on Polarization Properties of Poly (Vinylidene Fluoride–Trifluoroethylene) Ultrathin Films
The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polariz...
Ausführliche Beschreibung
Autor*in: |
Xingjia Li [verfasserIn] Zhi Shi [verfasserIn] Xiuli Zhang [verfasserIn] Xiangjian Meng [verfasserIn] Zhiqiang Huang [verfasserIn] Dandan Zhang [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2021 |
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Übergeordnetes Werk: |
In: Membranes - MDPI AG, 2011, 11(2021), 5, p 301 |
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Übergeordnetes Werk: |
volume:11 ; year:2021 ; number:5, p 301 |
Links: |
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DOI / URN: |
10.3390/membranes11050301 |
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Katalog-ID: |
DOAJ067433138 |
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10.3390/membranes11050301 doi (DE-627)DOAJ067433138 (DE-599)DOAJ968b78e3bab5487c8e7cf64b239b8e82 DE-627 ger DE-627 rakwb eng TP1-1185 TP155-156 Xingjia Li verfasserin aut The Influence Mechanism of Temperature and Storage Period on Polarization Properties of Poly (Vinylidene Fluoride–Trifluoroethylene) Ultrathin Films 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (<inline-formula<<math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"<<semantics<<mrow<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo</</mo<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo stretchy="false"<(</mo<<mn<0</mn<<mo stretchy="false"<)</mo<</mrow<</semantics<</math<</inline-formula<) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples. ferroelectric P(VDF–TrFE) ultrathin films temporal stability molecular modeling polarization switching Chemical technology Chemical engineering Zhi Shi verfasserin aut Xiuli Zhang verfasserin aut Xiangjian Meng verfasserin aut Zhiqiang Huang verfasserin aut Dandan Zhang verfasserin aut In Membranes MDPI AG, 2011 11(2021), 5, p 301 (DE-627)662495683 (DE-600)2614641-1 20770375 nnns volume:11 year:2021 number:5, p 301 https://doi.org/10.3390/membranes11050301 kostenfrei https://doaj.org/article/968b78e3bab5487c8e7cf64b239b8e82 kostenfrei https://www.mdpi.com/2077-0375/11/5/301 kostenfrei https://doaj.org/toc/2077-0375 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_2190 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 5, p 301 |
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10.3390/membranes11050301 doi (DE-627)DOAJ067433138 (DE-599)DOAJ968b78e3bab5487c8e7cf64b239b8e82 DE-627 ger DE-627 rakwb eng TP1-1185 TP155-156 Xingjia Li verfasserin aut The Influence Mechanism of Temperature and Storage Period on Polarization Properties of Poly (Vinylidene Fluoride–Trifluoroethylene) Ultrathin Films 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (<inline-formula<<math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"<<semantics<<mrow<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo</</mo<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo stretchy="false"<(</mo<<mn<0</mn<<mo stretchy="false"<)</mo<</mrow<</semantics<</math<</inline-formula<) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples. ferroelectric P(VDF–TrFE) ultrathin films temporal stability molecular modeling polarization switching Chemical technology Chemical engineering Zhi Shi verfasserin aut Xiuli Zhang verfasserin aut Xiangjian Meng verfasserin aut Zhiqiang Huang verfasserin aut Dandan Zhang verfasserin aut In Membranes MDPI AG, 2011 11(2021), 5, p 301 (DE-627)662495683 (DE-600)2614641-1 20770375 nnns volume:11 year:2021 number:5, p 301 https://doi.org/10.3390/membranes11050301 kostenfrei https://doaj.org/article/968b78e3bab5487c8e7cf64b239b8e82 kostenfrei https://www.mdpi.com/2077-0375/11/5/301 kostenfrei https://doaj.org/toc/2077-0375 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_2190 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 5, p 301 |
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10.3390/membranes11050301 doi (DE-627)DOAJ067433138 (DE-599)DOAJ968b78e3bab5487c8e7cf64b239b8e82 DE-627 ger DE-627 rakwb eng TP1-1185 TP155-156 Xingjia Li verfasserin aut The Influence Mechanism of Temperature and Storage Period on Polarization Properties of Poly (Vinylidene Fluoride–Trifluoroethylene) Ultrathin Films 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (<inline-formula<<math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"<<semantics<<mrow<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo</</mo<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo stretchy="false"<(</mo<<mn<0</mn<<mo stretchy="false"<)</mo<</mrow<</semantics<</math<</inline-formula<) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples. ferroelectric P(VDF–TrFE) ultrathin films temporal stability molecular modeling polarization switching Chemical technology Chemical engineering Zhi Shi verfasserin aut Xiuli Zhang verfasserin aut Xiangjian Meng verfasserin aut Zhiqiang Huang verfasserin aut Dandan Zhang verfasserin aut In Membranes MDPI AG, 2011 11(2021), 5, p 301 (DE-627)662495683 (DE-600)2614641-1 20770375 nnns volume:11 year:2021 number:5, p 301 https://doi.org/10.3390/membranes11050301 kostenfrei https://doaj.org/article/968b78e3bab5487c8e7cf64b239b8e82 kostenfrei https://www.mdpi.com/2077-0375/11/5/301 kostenfrei https://doaj.org/toc/2077-0375 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_2190 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 5, p 301 |
allfieldsGer |
10.3390/membranes11050301 doi (DE-627)DOAJ067433138 (DE-599)DOAJ968b78e3bab5487c8e7cf64b239b8e82 DE-627 ger DE-627 rakwb eng TP1-1185 TP155-156 Xingjia Li verfasserin aut The Influence Mechanism of Temperature and Storage Period on Polarization Properties of Poly (Vinylidene Fluoride–Trifluoroethylene) Ultrathin Films 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (<inline-formula<<math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"<<semantics<<mrow<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo</</mo<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo stretchy="false"<(</mo<<mn<0</mn<<mo stretchy="false"<)</mo<</mrow<</semantics<</math<</inline-formula<) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples. ferroelectric P(VDF–TrFE) ultrathin films temporal stability molecular modeling polarization switching Chemical technology Chemical engineering Zhi Shi verfasserin aut Xiuli Zhang verfasserin aut Xiangjian Meng verfasserin aut Zhiqiang Huang verfasserin aut Dandan Zhang verfasserin aut In Membranes MDPI AG, 2011 11(2021), 5, p 301 (DE-627)662495683 (DE-600)2614641-1 20770375 nnns volume:11 year:2021 number:5, p 301 https://doi.org/10.3390/membranes11050301 kostenfrei https://doaj.org/article/968b78e3bab5487c8e7cf64b239b8e82 kostenfrei https://www.mdpi.com/2077-0375/11/5/301 kostenfrei https://doaj.org/toc/2077-0375 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_2190 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 5, p 301 |
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10.3390/membranes11050301 doi (DE-627)DOAJ067433138 (DE-599)DOAJ968b78e3bab5487c8e7cf64b239b8e82 DE-627 ger DE-627 rakwb eng TP1-1185 TP155-156 Xingjia Li verfasserin aut The Influence Mechanism of Temperature and Storage Period on Polarization Properties of Poly (Vinylidene Fluoride–Trifluoroethylene) Ultrathin Films 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (<inline-formula<<math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"<<semantics<<mrow<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo</</mo<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo stretchy="false"<(</mo<<mn<0</mn<<mo stretchy="false"<)</mo<</mrow<</semantics<</math<</inline-formula<) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples. ferroelectric P(VDF–TrFE) ultrathin films temporal stability molecular modeling polarization switching Chemical technology Chemical engineering Zhi Shi verfasserin aut Xiuli Zhang verfasserin aut Xiangjian Meng verfasserin aut Zhiqiang Huang verfasserin aut Dandan Zhang verfasserin aut In Membranes MDPI AG, 2011 11(2021), 5, p 301 (DE-627)662495683 (DE-600)2614641-1 20770375 nnns volume:11 year:2021 number:5, p 301 https://doi.org/10.3390/membranes11050301 kostenfrei https://doaj.org/article/968b78e3bab5487c8e7cf64b239b8e82 kostenfrei https://www.mdpi.com/2077-0375/11/5/301 kostenfrei https://doaj.org/toc/2077-0375 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2031 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2061 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_2190 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 5, p 301 |
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influence mechanism of temperature and storage period on polarization properties of poly (vinylidene fluoride–trifluoroethylene) ultrathin films |
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The Influence Mechanism of Temperature and Storage Period on Polarization Properties of Poly (Vinylidene Fluoride–Trifluoroethylene) Ultrathin Films |
abstract |
The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (<inline-formula<<math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"<<semantics<<mrow<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo</</mo<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo stretchy="false"<(</mo<<mn<0</mn<<mo stretchy="false"<)</mo<</mrow<</semantics<</math<</inline-formula<) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples. |
abstractGer |
The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (<inline-formula<<math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"<<semantics<<mrow<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo</</mo<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo stretchy="false"<(</mo<<mn<0</mn<<mo stretchy="false"<)</mo<</mrow<</semantics<</math<</inline-formula<) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples. |
abstract_unstemmed |
The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (<inline-formula<<math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"<<semantics<<mrow<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo</</mo<<msub<<mi<P</mi<<mi<r</mi<</msub<<mo stretchy="false"<(</mo<<mn<0</mn<<mo stretchy="false"<)</mo<</mrow<</semantics<</math<</inline-formula<) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples. |
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5, p 301 |
title_short |
The Influence Mechanism of Temperature and Storage Period on Polarization Properties of Poly (Vinylidene Fluoride–Trifluoroethylene) Ultrathin Films |
url |
https://doi.org/10.3390/membranes11050301 https://doaj.org/article/968b78e3bab5487c8e7cf64b239b8e82 https://www.mdpi.com/2077-0375/11/5/301 https://doaj.org/toc/2077-0375 |
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