Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes

Solid electrolytes are crucial materials for lithium-ion or fuel-cell battery technology due to their structural stability and easiness for handling. Emergence of high conductivity in solid electrolytes requires precise control of the composition and structure. A promising strategy toward highly-con...
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Autor*in:	Takeru Ito [verfasserIn] Saki Otobe [verfasserIn] Tatsuma Oda [verfasserIn] Tatsuhiro Kojima [verfasserIn] Seiji Ono [verfasserIn] Masayuki Watanabe [verfasserIn] Yoshiki Kiyota [verfasserIn] Toshiyuki Misawa [verfasserIn] Shinichi Koguchi [verfasserIn] Masashi Higuchi [verfasserIn] Masaki Kawano [verfasserIn] Yu Nagase [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2017

Schlagwörter:	inorganic-organic hybrid polymer ionic liquid polyoxometalate conductivity

Übergeordnetes Werk:	In: Polymers - MDPI AG, 2011, 9(2017), 7, p 290
Übergeordnetes Werk:	volume:9 ; year:2017 ; number:7, p 290

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/polym9070290

Katalog-ID:	DOAJ069190763

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spelling	10.3390/polym9070290 doi (DE-627)DOAJ069190763 (DE-599)DOAJ58ace0e21c1b4df8bbc9d84c3e0e2e77 DE-627 ger DE-627 rakwb eng QD241-441 Takeru Ito verfasserin aut Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Solid electrolytes are crucial materials for lithium-ion or fuel-cell battery technology due to their structural stability and easiness for handling. Emergence of high conductivity in solid electrolytes requires precise control of the composition and structure. A promising strategy toward highly-conductive solid electrolytes is employing a thermally-stable inorganic component and a structurally-flexible organic moiety to construct inorganic-organic hybrid materials. Ionic liquids as the organic component will be advantageous for the emergence of high conductivity, and polyoxometalate, such as heteropolyacids, are well-known as inorganic proton conductors. Here, newly-designed ionic liquid imidazolium cations, having a polymerizable methacryl group (denoted as MAImC1), were successfully hybridized with heteropolyanions of [PW12O40]3− (PW12) to form inorganic-organic hybrid monomers of MAImC1-PW12. The synthetic procedure of MAImC1-PW12 was a simple ion-exchange reaction, being generally applicable to several polyoxometalates, in principle. MAImC1-PW12 was obtained as single crystals, and its molecular and crystal structures were clearly revealed. Additionally, the hybrid monomer of MAImC1-PW12 was polymerized by a radical polymerization using AIBN as an initiator. Some of the resulting inorganic-organic hybrid polymers exhibited conductivity of 10−4 S·cm−1 order under humidified conditions at 313 K. inorganic-organic hybrid polymer ionic liquid polyoxometalate conductivity Organic chemistry Saki Otobe verfasserin aut Tatsuma Oda verfasserin aut Tatsuhiro Kojima verfasserin aut Seiji Ono verfasserin aut Masayuki Watanabe verfasserin aut Yoshiki Kiyota verfasserin aut Toshiyuki Misawa verfasserin aut Shinichi Koguchi verfasserin aut Masashi Higuchi verfasserin aut Masaki Kawano verfasserin aut Yu Nagase verfasserin aut In Polymers MDPI AG, 2011 9(2017), 7, p 290 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:9 year:2017 number:7, p 290 https://doi.org/10.3390/polym9070290 kostenfrei https://doaj.org/article/58ace0e21c1b4df8bbc9d84c3e0e2e77 kostenfrei https://www.mdpi.com/2073-4360/9/7/290 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2017 7, p 290
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allfieldsGer	10.3390/polym9070290 doi (DE-627)DOAJ069190763 (DE-599)DOAJ58ace0e21c1b4df8bbc9d84c3e0e2e77 DE-627 ger DE-627 rakwb eng QD241-441 Takeru Ito verfasserin aut Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Solid electrolytes are crucial materials for lithium-ion or fuel-cell battery technology due to their structural stability and easiness for handling. Emergence of high conductivity in solid electrolytes requires precise control of the composition and structure. A promising strategy toward highly-conductive solid electrolytes is employing a thermally-stable inorganic component and a structurally-flexible organic moiety to construct inorganic-organic hybrid materials. Ionic liquids as the organic component will be advantageous for the emergence of high conductivity, and polyoxometalate, such as heteropolyacids, are well-known as inorganic proton conductors. Here, newly-designed ionic liquid imidazolium cations, having a polymerizable methacryl group (denoted as MAImC1), were successfully hybridized with heteropolyanions of [PW12O40]3− (PW12) to form inorganic-organic hybrid monomers of MAImC1-PW12. The synthetic procedure of MAImC1-PW12 was a simple ion-exchange reaction, being generally applicable to several polyoxometalates, in principle. MAImC1-PW12 was obtained as single crystals, and its molecular and crystal structures were clearly revealed. Additionally, the hybrid monomer of MAImC1-PW12 was polymerized by a radical polymerization using AIBN as an initiator. Some of the resulting inorganic-organic hybrid polymers exhibited conductivity of 10−4 S·cm−1 order under humidified conditions at 313 K. inorganic-organic hybrid polymer ionic liquid polyoxometalate conductivity Organic chemistry Saki Otobe verfasserin aut Tatsuma Oda verfasserin aut Tatsuhiro Kojima verfasserin aut Seiji Ono verfasserin aut Masayuki Watanabe verfasserin aut Yoshiki Kiyota verfasserin aut Toshiyuki Misawa verfasserin aut Shinichi Koguchi verfasserin aut Masashi Higuchi verfasserin aut Masaki Kawano verfasserin aut Yu Nagase verfasserin aut In Polymers MDPI AG, 2011 9(2017), 7, p 290 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:9 year:2017 number:7, p 290 https://doi.org/10.3390/polym9070290 kostenfrei https://doaj.org/article/58ace0e21c1b4df8bbc9d84c3e0e2e77 kostenfrei https://www.mdpi.com/2073-4360/9/7/290 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2017 7, p 290
allfieldsSound	10.3390/polym9070290 doi (DE-627)DOAJ069190763 (DE-599)DOAJ58ace0e21c1b4df8bbc9d84c3e0e2e77 DE-627 ger DE-627 rakwb eng QD241-441 Takeru Ito verfasserin aut Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Solid electrolytes are crucial materials for lithium-ion or fuel-cell battery technology due to their structural stability and easiness for handling. Emergence of high conductivity in solid electrolytes requires precise control of the composition and structure. A promising strategy toward highly-conductive solid electrolytes is employing a thermally-stable inorganic component and a structurally-flexible organic moiety to construct inorganic-organic hybrid materials. Ionic liquids as the organic component will be advantageous for the emergence of high conductivity, and polyoxometalate, such as heteropolyacids, are well-known as inorganic proton conductors. Here, newly-designed ionic liquid imidazolium cations, having a polymerizable methacryl group (denoted as MAImC1), were successfully hybridized with heteropolyanions of [PW12O40]3− (PW12) to form inorganic-organic hybrid monomers of MAImC1-PW12. The synthetic procedure of MAImC1-PW12 was a simple ion-exchange reaction, being generally applicable to several polyoxometalates, in principle. MAImC1-PW12 was obtained as single crystals, and its molecular and crystal structures were clearly revealed. Additionally, the hybrid monomer of MAImC1-PW12 was polymerized by a radical polymerization using AIBN as an initiator. Some of the resulting inorganic-organic hybrid polymers exhibited conductivity of 10−4 S·cm−1 order under humidified conditions at 313 K. inorganic-organic hybrid polymer ionic liquid polyoxometalate conductivity Organic chemistry Saki Otobe verfasserin aut Tatsuma Oda verfasserin aut Tatsuhiro Kojima verfasserin aut Seiji Ono verfasserin aut Masayuki Watanabe verfasserin aut Yoshiki Kiyota verfasserin aut Toshiyuki Misawa verfasserin aut Shinichi Koguchi verfasserin aut Masashi Higuchi verfasserin aut Masaki Kawano verfasserin aut Yu Nagase verfasserin aut In Polymers MDPI AG, 2011 9(2017), 7, p 290 (DE-627)61409612X (DE-600)2527146-5 20734360 nnns volume:9 year:2017 number:7, p 290 https://doi.org/10.3390/polym9070290 kostenfrei https://doaj.org/article/58ace0e21c1b4df8bbc9d84c3e0e2e77 kostenfrei https://www.mdpi.com/2073-4360/9/7/290 kostenfrei https://doaj.org/toc/2073-4360 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2119 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 9 2017 7, p 290
language	English
source	In Polymers 9(2017), 7, p 290 volume:9 year:2017 number:7, p 290
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authorswithroles_txt_mv	Takeru Ito @@aut@@ Saki Otobe @@aut@@ Tatsuma Oda @@aut@@ Tatsuhiro Kojima @@aut@@ Seiji Ono @@aut@@ Masayuki Watanabe @@aut@@ Yoshiki Kiyota @@aut@@ Toshiyuki Misawa @@aut@@ Shinichi Koguchi @@aut@@ Masashi Higuchi @@aut@@ Masaki Kawano @@aut@@ Yu Nagase @@aut@@
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author	Takeru Ito
spellingShingle	Takeru Ito misc QD241-441 misc inorganic-organic hybrid misc polymer misc ionic liquid misc polyoxometalate misc conductivity misc Organic chemistry Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes
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topic_title	QD241-441 Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes inorganic-organic hybrid polymer ionic liquid polyoxometalate conductivity
topic	misc QD241-441 misc inorganic-organic hybrid misc polymer misc ionic liquid misc polyoxometalate misc conductivity misc Organic chemistry
topic_unstemmed	misc QD241-441 misc inorganic-organic hybrid misc polymer misc ionic liquid misc polyoxometalate misc conductivity misc Organic chemistry
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title	Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes
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title_sort	polymerizable ionic liquid crystals comprising polyoxometalate clusters toward inorganic-organic hybrid solid electrolytes
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title_auth	Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes
abstract	Solid electrolytes are crucial materials for lithium-ion or fuel-cell battery technology due to their structural stability and easiness for handling. Emergence of high conductivity in solid electrolytes requires precise control of the composition and structure. A promising strategy toward highly-conductive solid electrolytes is employing a thermally-stable inorganic component and a structurally-flexible organic moiety to construct inorganic-organic hybrid materials. Ionic liquids as the organic component will be advantageous for the emergence of high conductivity, and polyoxometalate, such as heteropolyacids, are well-known as inorganic proton conductors. Here, newly-designed ionic liquid imidazolium cations, having a polymerizable methacryl group (denoted as MAImC1), were successfully hybridized with heteropolyanions of [PW12O40]3− (PW12) to form inorganic-organic hybrid monomers of MAImC1-PW12. The synthetic procedure of MAImC1-PW12 was a simple ion-exchange reaction, being generally applicable to several polyoxometalates, in principle. MAImC1-PW12 was obtained as single crystals, and its molecular and crystal structures were clearly revealed. Additionally, the hybrid monomer of MAImC1-PW12 was polymerized by a radical polymerization using AIBN as an initiator. Some of the resulting inorganic-organic hybrid polymers exhibited conductivity of 10−4 S·cm−1 order under humidified conditions at 313 K.
abstractGer	Solid electrolytes are crucial materials for lithium-ion or fuel-cell battery technology due to their structural stability and easiness for handling. Emergence of high conductivity in solid electrolytes requires precise control of the composition and structure. A promising strategy toward highly-conductive solid electrolytes is employing a thermally-stable inorganic component and a structurally-flexible organic moiety to construct inorganic-organic hybrid materials. Ionic liquids as the organic component will be advantageous for the emergence of high conductivity, and polyoxometalate, such as heteropolyacids, are well-known as inorganic proton conductors. Here, newly-designed ionic liquid imidazolium cations, having a polymerizable methacryl group (denoted as MAImC1), were successfully hybridized with heteropolyanions of [PW12O40]3− (PW12) to form inorganic-organic hybrid monomers of MAImC1-PW12. The synthetic procedure of MAImC1-PW12 was a simple ion-exchange reaction, being generally applicable to several polyoxometalates, in principle. MAImC1-PW12 was obtained as single crystals, and its molecular and crystal structures were clearly revealed. Additionally, the hybrid monomer of MAImC1-PW12 was polymerized by a radical polymerization using AIBN as an initiator. Some of the resulting inorganic-organic hybrid polymers exhibited conductivity of 10−4 S·cm−1 order under humidified conditions at 313 K.
abstract_unstemmed	Solid electrolytes are crucial materials for lithium-ion or fuel-cell battery technology due to their structural stability and easiness for handling. Emergence of high conductivity in solid electrolytes requires precise control of the composition and structure. A promising strategy toward highly-conductive solid electrolytes is employing a thermally-stable inorganic component and a structurally-flexible organic moiety to construct inorganic-organic hybrid materials. Ionic liquids as the organic component will be advantageous for the emergence of high conductivity, and polyoxometalate, such as heteropolyacids, are well-known as inorganic proton conductors. Here, newly-designed ionic liquid imidazolium cations, having a polymerizable methacryl group (denoted as MAImC1), were successfully hybridized with heteropolyanions of [PW12O40]3− (PW12) to form inorganic-organic hybrid monomers of MAImC1-PW12. The synthetic procedure of MAImC1-PW12 was a simple ion-exchange reaction, being generally applicable to several polyoxometalates, in principle. MAImC1-PW12 was obtained as single crystals, and its molecular and crystal structures were clearly revealed. Additionally, the hybrid monomer of MAImC1-PW12 was polymerized by a radical polymerization using AIBN as an initiator. Some of the resulting inorganic-organic hybrid polymers exhibited conductivity of 10−4 S·cm−1 order under humidified conditions at 313 K.
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url	https://doi.org/10.3390/polym9070290 https://doaj.org/article/58ace0e21c1b4df8bbc9d84c3e0e2e77 https://www.mdpi.com/2073-4360/9/7/290 https://doaj.org/toc/2073-4360
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author2	Saki Otobe Tatsuma Oda Tatsuhiro Kojima Seiji Ono Masayuki Watanabe Yoshiki Kiyota Toshiyuki Misawa Shinichi Koguchi Masashi Higuchi Masaki Kawano Yu Nagase
author2Str	Saki Otobe Tatsuma Oda Tatsuhiro Kojima Seiji Ono Masayuki Watanabe Yoshiki Kiyota Toshiyuki Misawa Shinichi Koguchi Masashi Higuchi Masaki Kawano Yu Nagase
ppnlink	61409612X
callnumber-subject	QD - Chemistry
mediatype_str_mv	c
isOA_txt	true
hochschulschrift_bool	false
doi_str	10.3390/polym9070290
callnumber-a	QD241-441
up_date	2024-07-03T21:59:46.139Z
_version_	1803596842820173824
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Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes

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