Nitroalkanes as Central Reagents in the Synthesis of Spiroketals

Nitroalkanes can be profitably employed as carbanionic precursors for theassembly of dihydroxy ketone frameworks, suitable for the preparation of spiroketals. Thecarbon-carbon bond formation is carried out exploiting nitroaldol and Michael reactions,while the nitro to carbonyl conversion (Nef reacti...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Goffredo Rosini [verfasserIn] Marino Petrini [verfasserIn] Roberto Ballini [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2008

Schlagwörter:	Conjugate addition Nef reaction nitroaldol reaction nitroalkanes spiroketals.

Übergeordnetes Werk:	In: Molecules - MDPI AG, 2003, 13(2008), 2, Seite 319-330
Übergeordnetes Werk:	volume:13 ; year:2008 ; number:2 ; pages:319-330

Links:	Link aufrufen Link aufrufen Link aufrufen Journal toc

DOI / URN:	10.3390/molecules13020319

Katalog-ID:	DOAJ071066454

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allfields	10.3390/molecules13020319 doi (DE-627)DOAJ071066454 (DE-599)DOAJe6d0770fa7b54bf0bc276fe61fecca21 DE-627 ger DE-627 rakwb eng QD241-441 Goffredo Rosini verfasserin aut Nitroalkanes as Central Reagents in the Synthesis of Spiroketals 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nitroalkanes can be profitably employed as carbanionic precursors for theassembly of dihydroxy ketone frameworks, suitable for the preparation of spiroketals. Thecarbon-carbon bond formation is carried out exploiting nitroaldol and Michael reactions,while the nitro to carbonyl conversion (Nef reaction) ensures the correct introduction of theketo group. Several spiroketal systems endowed with considerable biological activity canbe prepared using this synthetic strategy. Conjugate addition Nef reaction nitroaldol reaction nitroalkanes spiroketals. Organic chemistry Marino Petrini verfasserin aut Roberto Ballini verfasserin aut In Molecules MDPI AG, 2003 13(2008), 2, Seite 319-330 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:13 year:2008 number:2 pages:319-330 https://doi.org/10.3390/molecules13020319 kostenfrei https://doaj.org/article/e6d0770fa7b54bf0bc276fe61fecca21 kostenfrei http://www.mdpi.com/1420-3049/13/2/319/ kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 13 2008 2 319-330
spelling	10.3390/molecules13020319 doi (DE-627)DOAJ071066454 (DE-599)DOAJe6d0770fa7b54bf0bc276fe61fecca21 DE-627 ger DE-627 rakwb eng QD241-441 Goffredo Rosini verfasserin aut Nitroalkanes as Central Reagents in the Synthesis of Spiroketals 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nitroalkanes can be profitably employed as carbanionic precursors for theassembly of dihydroxy ketone frameworks, suitable for the preparation of spiroketals. Thecarbon-carbon bond formation is carried out exploiting nitroaldol and Michael reactions,while the nitro to carbonyl conversion (Nef reaction) ensures the correct introduction of theketo group. Several spiroketal systems endowed with considerable biological activity canbe prepared using this synthetic strategy. Conjugate addition Nef reaction nitroaldol reaction nitroalkanes spiroketals. Organic chemistry Marino Petrini verfasserin aut Roberto Ballini verfasserin aut In Molecules MDPI AG, 2003 13(2008), 2, Seite 319-330 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:13 year:2008 number:2 pages:319-330 https://doi.org/10.3390/molecules13020319 kostenfrei https://doaj.org/article/e6d0770fa7b54bf0bc276fe61fecca21 kostenfrei http://www.mdpi.com/1420-3049/13/2/319/ kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 13 2008 2 319-330
allfields_unstemmed	10.3390/molecules13020319 doi (DE-627)DOAJ071066454 (DE-599)DOAJe6d0770fa7b54bf0bc276fe61fecca21 DE-627 ger DE-627 rakwb eng QD241-441 Goffredo Rosini verfasserin aut Nitroalkanes as Central Reagents in the Synthesis of Spiroketals 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Nitroalkanes can be profitably employed as carbanionic precursors for theassembly of dihydroxy ketone frameworks, suitable for the preparation of spiroketals. Thecarbon-carbon bond formation is carried out exploiting nitroaldol and Michael reactions,while the nitro to carbonyl conversion (Nef reaction) ensures the correct introduction of theketo group. Several spiroketal systems endowed with considerable biological activity canbe prepared using this synthetic strategy. Conjugate addition Nef reaction nitroaldol reaction nitroalkanes spiroketals. Organic chemistry Marino Petrini verfasserin aut Roberto Ballini verfasserin aut In Molecules MDPI AG, 2003 13(2008), 2, Seite 319-330 (DE-627)311313132 (DE-600)2008644-1 14203049 nnns volume:13 year:2008 number:2 pages:319-330 https://doi.org/10.3390/molecules13020319 kostenfrei https://doaj.org/article/e6d0770fa7b54bf0bc276fe61fecca21 kostenfrei http://www.mdpi.com/1420-3049/13/2/319/ kostenfrei https://doaj.org/toc/1420-3049 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 13 2008 2 319-330
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language	English
source	In Molecules 13(2008), 2, Seite 319-330 volume:13 year:2008 number:2 pages:319-330
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topic_facet	Conjugate addition Nef reaction nitroaldol reaction nitroalkanes spiroketals. Organic chemistry
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authorswithroles_txt_mv	Goffredo Rosini @@aut@@ Marino Petrini @@aut@@ Roberto Ballini @@aut@@
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callnumber-first	Q - Science
author	Goffredo Rosini
spellingShingle	Goffredo Rosini misc QD241-441 misc Conjugate addition misc Nef reaction misc nitroaldol reaction misc nitroalkanes misc spiroketals. misc Organic chemistry Nitroalkanes as Central Reagents in the Synthesis of Spiroketals
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topic_title	QD241-441 Nitroalkanes as Central Reagents in the Synthesis of Spiroketals Conjugate addition Nef reaction nitroaldol reaction nitroalkanes spiroketals
topic	misc QD241-441 misc Conjugate addition misc Nef reaction misc nitroaldol reaction misc nitroalkanes misc spiroketals. misc Organic chemistry
topic_unstemmed	misc QD241-441 misc Conjugate addition misc Nef reaction misc nitroaldol reaction misc nitroalkanes misc spiroketals. misc Organic chemistry
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title	Nitroalkanes as Central Reagents in the Synthesis of Spiroketals
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title_full	Nitroalkanes as Central Reagents in the Synthesis of Spiroketals
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title_sort	nitroalkanes as central reagents in the synthesis of spiroketals
callnumber	QD241-441
title_auth	Nitroalkanes as Central Reagents in the Synthesis of Spiroketals
abstract	Nitroalkanes can be profitably employed as carbanionic precursors for theassembly of dihydroxy ketone frameworks, suitable for the preparation of spiroketals. Thecarbon-carbon bond formation is carried out exploiting nitroaldol and Michael reactions,while the nitro to carbonyl conversion (Nef reaction) ensures the correct introduction of theketo group. Several spiroketal systems endowed with considerable biological activity canbe prepared using this synthetic strategy.
abstractGer	Nitroalkanes can be profitably employed as carbanionic precursors for theassembly of dihydroxy ketone frameworks, suitable for the preparation of spiroketals. Thecarbon-carbon bond formation is carried out exploiting nitroaldol and Michael reactions,while the nitro to carbonyl conversion (Nef reaction) ensures the correct introduction of theketo group. Several spiroketal systems endowed with considerable biological activity canbe prepared using this synthetic strategy.
abstract_unstemmed	Nitroalkanes can be profitably employed as carbanionic precursors for theassembly of dihydroxy ketone frameworks, suitable for the preparation of spiroketals. Thecarbon-carbon bond formation is carried out exploiting nitroaldol and Michael reactions,while the nitro to carbonyl conversion (Nef reaction) ensures the correct introduction of theketo group. Several spiroketal systems endowed with considerable biological activity canbe prepared using this synthetic strategy.
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title_short	Nitroalkanes as Central Reagents in the Synthesis of Spiroketals
url	https://doi.org/10.3390/molecules13020319 https://doaj.org/article/e6d0770fa7b54bf0bc276fe61fecca21 http://www.mdpi.com/1420-3049/13/2/319/ https://doaj.org/toc/1420-3049
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up_date	2024-07-03T18:14:50.385Z
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