Activation of Pt Nanoclusters on TiO<sub<2</sub< via Tuning the Metallic Sites to Promote Low-Temperature CO Oxidation
Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H<sub<2</sub< pretreatment of Pt clusters at 2...
Ausführliche Beschreibung
Autor*in: |
Kailin He [verfasserIn] Qingyue Wang [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2021 |
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Übergeordnetes Werk: |
In: Catalysts - MDPI AG, 2012, 11(2021), 11, p 1280 |
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Übergeordnetes Werk: |
volume:11 ; year:2021 ; number:11, p 1280 |
Links: |
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DOI / URN: |
10.3390/catal11111280 |
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Katalog-ID: |
DOAJ071537295 |
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10.3390/catal11111280 doi (DE-627)DOAJ071537295 (DE-599)DOAJ2c6af36c859444f68067f9b988cd491c DE-627 ger DE-627 rakwb eng TP1-1185 QD1-999 Kailin He verfasserin aut Activation of Pt Nanoclusters on TiO<sub<2</sub< via Tuning the Metallic Sites to Promote Low-Temperature CO Oxidation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H<sub<2</sub< pretreatment of Pt clusters at 200 °C decreases the T<sub<50</sub< from 208 °C to 183 °C in the 0.1 wt % Pt/TiO<sub<2</sub< catalyst. The T<sub<50</sub< shows a remarkable improvement using a CO pretreatment, which decreases the T<sub<50</sub< further to 135 °C. A comprehensive characterization study reveals the integrated reasons behind this phenomenon: (i) the extent of PtO transition to metallic Pt sites, (ii) the ample surface active oxygen triggered by metallic Pt, (iii) the CO selectively adsorbs on metallic Pt sites which participate in low-temperature CO oxidation, and (iv) the formation of the unstable intermediate such as bicarbonate, contributes together to the enhanced activity of CO pretreated Pt/TiO<sub<2</sub<. reduction pretreatment metallic Pt sites CO adsorption CO oxidation reactive intermediate Chemical technology Chemistry Qingyue Wang verfasserin aut In Catalysts MDPI AG, 2012 11(2021), 11, p 1280 (DE-627)71862646X (DE-600)2662126-5 20734344 nnns volume:11 year:2021 number:11, p 1280 https://doi.org/10.3390/catal11111280 kostenfrei https://doaj.org/article/2c6af36c859444f68067f9b988cd491c kostenfrei https://www.mdpi.com/2073-4344/11/11/1280 kostenfrei https://doaj.org/toc/2073-4344 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 11, p 1280 |
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10.3390/catal11111280 doi (DE-627)DOAJ071537295 (DE-599)DOAJ2c6af36c859444f68067f9b988cd491c DE-627 ger DE-627 rakwb eng TP1-1185 QD1-999 Kailin He verfasserin aut Activation of Pt Nanoclusters on TiO<sub<2</sub< via Tuning the Metallic Sites to Promote Low-Temperature CO Oxidation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H<sub<2</sub< pretreatment of Pt clusters at 200 °C decreases the T<sub<50</sub< from 208 °C to 183 °C in the 0.1 wt % Pt/TiO<sub<2</sub< catalyst. The T<sub<50</sub< shows a remarkable improvement using a CO pretreatment, which decreases the T<sub<50</sub< further to 135 °C. A comprehensive characterization study reveals the integrated reasons behind this phenomenon: (i) the extent of PtO transition to metallic Pt sites, (ii) the ample surface active oxygen triggered by metallic Pt, (iii) the CO selectively adsorbs on metallic Pt sites which participate in low-temperature CO oxidation, and (iv) the formation of the unstable intermediate such as bicarbonate, contributes together to the enhanced activity of CO pretreated Pt/TiO<sub<2</sub<. reduction pretreatment metallic Pt sites CO adsorption CO oxidation reactive intermediate Chemical technology Chemistry Qingyue Wang verfasserin aut In Catalysts MDPI AG, 2012 11(2021), 11, p 1280 (DE-627)71862646X (DE-600)2662126-5 20734344 nnns volume:11 year:2021 number:11, p 1280 https://doi.org/10.3390/catal11111280 kostenfrei https://doaj.org/article/2c6af36c859444f68067f9b988cd491c kostenfrei https://www.mdpi.com/2073-4344/11/11/1280 kostenfrei https://doaj.org/toc/2073-4344 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 11, p 1280 |
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10.3390/catal11111280 doi (DE-627)DOAJ071537295 (DE-599)DOAJ2c6af36c859444f68067f9b988cd491c DE-627 ger DE-627 rakwb eng TP1-1185 QD1-999 Kailin He verfasserin aut Activation of Pt Nanoclusters on TiO<sub<2</sub< via Tuning the Metallic Sites to Promote Low-Temperature CO Oxidation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H<sub<2</sub< pretreatment of Pt clusters at 200 °C decreases the T<sub<50</sub< from 208 °C to 183 °C in the 0.1 wt % Pt/TiO<sub<2</sub< catalyst. The T<sub<50</sub< shows a remarkable improvement using a CO pretreatment, which decreases the T<sub<50</sub< further to 135 °C. A comprehensive characterization study reveals the integrated reasons behind this phenomenon: (i) the extent of PtO transition to metallic Pt sites, (ii) the ample surface active oxygen triggered by metallic Pt, (iii) the CO selectively adsorbs on metallic Pt sites which participate in low-temperature CO oxidation, and (iv) the formation of the unstable intermediate such as bicarbonate, contributes together to the enhanced activity of CO pretreated Pt/TiO<sub<2</sub<. reduction pretreatment metallic Pt sites CO adsorption CO oxidation reactive intermediate Chemical technology Chemistry Qingyue Wang verfasserin aut In Catalysts MDPI AG, 2012 11(2021), 11, p 1280 (DE-627)71862646X (DE-600)2662126-5 20734344 nnns volume:11 year:2021 number:11, p 1280 https://doi.org/10.3390/catal11111280 kostenfrei https://doaj.org/article/2c6af36c859444f68067f9b988cd491c kostenfrei https://www.mdpi.com/2073-4344/11/11/1280 kostenfrei https://doaj.org/toc/2073-4344 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 11, p 1280 |
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10.3390/catal11111280 doi (DE-627)DOAJ071537295 (DE-599)DOAJ2c6af36c859444f68067f9b988cd491c DE-627 ger DE-627 rakwb eng TP1-1185 QD1-999 Kailin He verfasserin aut Activation of Pt Nanoclusters on TiO<sub<2</sub< via Tuning the Metallic Sites to Promote Low-Temperature CO Oxidation 2021 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H<sub<2</sub< pretreatment of Pt clusters at 200 °C decreases the T<sub<50</sub< from 208 °C to 183 °C in the 0.1 wt % Pt/TiO<sub<2</sub< catalyst. The T<sub<50</sub< shows a remarkable improvement using a CO pretreatment, which decreases the T<sub<50</sub< further to 135 °C. A comprehensive characterization study reveals the integrated reasons behind this phenomenon: (i) the extent of PtO transition to metallic Pt sites, (ii) the ample surface active oxygen triggered by metallic Pt, (iii) the CO selectively adsorbs on metallic Pt sites which participate in low-temperature CO oxidation, and (iv) the formation of the unstable intermediate such as bicarbonate, contributes together to the enhanced activity of CO pretreated Pt/TiO<sub<2</sub<. reduction pretreatment metallic Pt sites CO adsorption CO oxidation reactive intermediate Chemical technology Chemistry Qingyue Wang verfasserin aut In Catalysts MDPI AG, 2012 11(2021), 11, p 1280 (DE-627)71862646X (DE-600)2662126-5 20734344 nnns volume:11 year:2021 number:11, p 1280 https://doi.org/10.3390/catal11111280 kostenfrei https://doaj.org/article/2c6af36c859444f68067f9b988cd491c kostenfrei https://www.mdpi.com/2073-4344/11/11/1280 kostenfrei https://doaj.org/toc/2073-4344 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_206 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_602 GBV_ILN_2005 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2055 GBV_ILN_2111 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 11 2021 11, p 1280 |
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Kailin He misc TP1-1185 misc QD1-999 misc reduction pretreatment misc metallic Pt sites misc CO adsorption misc CO oxidation misc reactive intermediate misc Chemical technology misc Chemistry Activation of Pt Nanoclusters on TiO<sub<2</sub< via Tuning the Metallic Sites to Promote Low-Temperature CO Oxidation |
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Activation of Pt Nanoclusters on TiO<sub<2</sub< via Tuning the Metallic Sites to Promote Low-Temperature CO Oxidation |
abstract |
Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H<sub<2</sub< pretreatment of Pt clusters at 200 °C decreases the T<sub<50</sub< from 208 °C to 183 °C in the 0.1 wt % Pt/TiO<sub<2</sub< catalyst. The T<sub<50</sub< shows a remarkable improvement using a CO pretreatment, which decreases the T<sub<50</sub< further to 135 °C. A comprehensive characterization study reveals the integrated reasons behind this phenomenon: (i) the extent of PtO transition to metallic Pt sites, (ii) the ample surface active oxygen triggered by metallic Pt, (iii) the CO selectively adsorbs on metallic Pt sites which participate in low-temperature CO oxidation, and (iv) the formation of the unstable intermediate such as bicarbonate, contributes together to the enhanced activity of CO pretreated Pt/TiO<sub<2</sub<. |
abstractGer |
Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H<sub<2</sub< pretreatment of Pt clusters at 200 °C decreases the T<sub<50</sub< from 208 °C to 183 °C in the 0.1 wt % Pt/TiO<sub<2</sub< catalyst. The T<sub<50</sub< shows a remarkable improvement using a CO pretreatment, which decreases the T<sub<50</sub< further to 135 °C. A comprehensive characterization study reveals the integrated reasons behind this phenomenon: (i) the extent of PtO transition to metallic Pt sites, (ii) the ample surface active oxygen triggered by metallic Pt, (iii) the CO selectively adsorbs on metallic Pt sites which participate in low-temperature CO oxidation, and (iv) the formation of the unstable intermediate such as bicarbonate, contributes together to the enhanced activity of CO pretreated Pt/TiO<sub<2</sub<. |
abstract_unstemmed |
Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H<sub<2</sub< pretreatment of Pt clusters at 200 °C decreases the T<sub<50</sub< from 208 °C to 183 °C in the 0.1 wt % Pt/TiO<sub<2</sub< catalyst. The T<sub<50</sub< shows a remarkable improvement using a CO pretreatment, which decreases the T<sub<50</sub< further to 135 °C. A comprehensive characterization study reveals the integrated reasons behind this phenomenon: (i) the extent of PtO transition to metallic Pt sites, (ii) the ample surface active oxygen triggered by metallic Pt, (iii) the CO selectively adsorbs on metallic Pt sites which participate in low-temperature CO oxidation, and (iv) the formation of the unstable intermediate such as bicarbonate, contributes together to the enhanced activity of CO pretreated Pt/TiO<sub<2</sub<. |
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