Hydrogen isotope of natural gas from the Xujiahe Formation and its implications for water salinization in central Sichuan Basin, China
Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significa...
Ausführliche Beschreibung
Autor*in: |
Yunyan Ni [verfasserIn] Fengrong Liao [verfasserIn] Limiao Yao [verfasserIn] Jinliang Gao [verfasserIn] Dijia Zhang [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2019 |
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Übergeordnetes Werk: |
In: Journal of Natural Gas Geoscience - KeAi Communications Co., Ltd., 2017, 4(2019), 4, Seite 215-230 |
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Übergeordnetes Werk: |
volume:4 ; year:2019 ; number:4 ; pages:215-230 |
Links: |
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DOI / URN: |
10.1016/j.jnggs.2019.08.003 |
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Katalog-ID: |
DOAJ072386533 |
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520 | |a Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization | ||
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10.1016/j.jnggs.2019.08.003 doi (DE-627)DOAJ072386533 (DE-599)DOAJ9dce0ecb2ec340f2ab2f9738842aa471 DE-627 ger DE-627 rakwb eng TP751-762 Yunyan Ni verfasserin aut Hydrogen isotope of natural gas from the Xujiahe Formation and its implications for water salinization in central Sichuan Basin, China 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization Gas industry Fengrong Liao verfasserin aut Limiao Yao verfasserin aut Jinliang Gao verfasserin aut Dijia Zhang verfasserin aut In Journal of Natural Gas Geoscience KeAi Communications Co., Ltd., 2017 4(2019), 4, Seite 215-230 (DE-627)871310600 (DE-600)2872751-4 2468256X nnns volume:4 year:2019 number:4 pages:215-230 https://doi.org/10.1016/j.jnggs.2019.08.003 kostenfrei https://doaj.org/article/9dce0ecb2ec340f2ab2f9738842aa471 kostenfrei http://www.sciencedirect.com/science/article/pii/S2468256X19300483 kostenfrei https://doaj.org/toc/2468-256X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2019 4 215-230 |
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10.1016/j.jnggs.2019.08.003 doi (DE-627)DOAJ072386533 (DE-599)DOAJ9dce0ecb2ec340f2ab2f9738842aa471 DE-627 ger DE-627 rakwb eng TP751-762 Yunyan Ni verfasserin aut Hydrogen isotope of natural gas from the Xujiahe Formation and its implications for water salinization in central Sichuan Basin, China 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization Gas industry Fengrong Liao verfasserin aut Limiao Yao verfasserin aut Jinliang Gao verfasserin aut Dijia Zhang verfasserin aut In Journal of Natural Gas Geoscience KeAi Communications Co., Ltd., 2017 4(2019), 4, Seite 215-230 (DE-627)871310600 (DE-600)2872751-4 2468256X nnns volume:4 year:2019 number:4 pages:215-230 https://doi.org/10.1016/j.jnggs.2019.08.003 kostenfrei https://doaj.org/article/9dce0ecb2ec340f2ab2f9738842aa471 kostenfrei http://www.sciencedirect.com/science/article/pii/S2468256X19300483 kostenfrei https://doaj.org/toc/2468-256X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2019 4 215-230 |
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10.1016/j.jnggs.2019.08.003 doi (DE-627)DOAJ072386533 (DE-599)DOAJ9dce0ecb2ec340f2ab2f9738842aa471 DE-627 ger DE-627 rakwb eng TP751-762 Yunyan Ni verfasserin aut Hydrogen isotope of natural gas from the Xujiahe Formation and its implications for water salinization in central Sichuan Basin, China 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization Gas industry Fengrong Liao verfasserin aut Limiao Yao verfasserin aut Jinliang Gao verfasserin aut Dijia Zhang verfasserin aut In Journal of Natural Gas Geoscience KeAi Communications Co., Ltd., 2017 4(2019), 4, Seite 215-230 (DE-627)871310600 (DE-600)2872751-4 2468256X nnns volume:4 year:2019 number:4 pages:215-230 https://doi.org/10.1016/j.jnggs.2019.08.003 kostenfrei https://doaj.org/article/9dce0ecb2ec340f2ab2f9738842aa471 kostenfrei http://www.sciencedirect.com/science/article/pii/S2468256X19300483 kostenfrei https://doaj.org/toc/2468-256X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2019 4 215-230 |
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10.1016/j.jnggs.2019.08.003 doi (DE-627)DOAJ072386533 (DE-599)DOAJ9dce0ecb2ec340f2ab2f9738842aa471 DE-627 ger DE-627 rakwb eng TP751-762 Yunyan Ni verfasserin aut Hydrogen isotope of natural gas from the Xujiahe Formation and its implications for water salinization in central Sichuan Basin, China 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization Gas industry Fengrong Liao verfasserin aut Limiao Yao verfasserin aut Jinliang Gao verfasserin aut Dijia Zhang verfasserin aut In Journal of Natural Gas Geoscience KeAi Communications Co., Ltd., 2017 4(2019), 4, Seite 215-230 (DE-627)871310600 (DE-600)2872751-4 2468256X nnns volume:4 year:2019 number:4 pages:215-230 https://doi.org/10.1016/j.jnggs.2019.08.003 kostenfrei https://doaj.org/article/9dce0ecb2ec340f2ab2f9738842aa471 kostenfrei http://www.sciencedirect.com/science/article/pii/S2468256X19300483 kostenfrei https://doaj.org/toc/2468-256X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2019 4 215-230 |
allfieldsSound |
10.1016/j.jnggs.2019.08.003 doi (DE-627)DOAJ072386533 (DE-599)DOAJ9dce0ecb2ec340f2ab2f9738842aa471 DE-627 ger DE-627 rakwb eng TP751-762 Yunyan Ni verfasserin aut Hydrogen isotope of natural gas from the Xujiahe Formation and its implications for water salinization in central Sichuan Basin, China 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization Gas industry Fengrong Liao verfasserin aut Limiao Yao verfasserin aut Jinliang Gao verfasserin aut Dijia Zhang verfasserin aut In Journal of Natural Gas Geoscience KeAi Communications Co., Ltd., 2017 4(2019), 4, Seite 215-230 (DE-627)871310600 (DE-600)2872751-4 2468256X nnns volume:4 year:2019 number:4 pages:215-230 https://doi.org/10.1016/j.jnggs.2019.08.003 kostenfrei https://doaj.org/article/9dce0ecb2ec340f2ab2f9738842aa471 kostenfrei http://www.sciencedirect.com/science/article/pii/S2468256X19300483 kostenfrei https://doaj.org/toc/2468-256X Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 4 2019 4 215-230 |
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The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. 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Hydrogen isotope of natural gas from the Xujiahe Formation and its implications for water salinization in central Sichuan Basin, China |
abstract |
Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization |
abstractGer |
Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization |
abstract_unstemmed |
Based on the analysis of the molecular composition as well as carbon and hydrogen isotopes of gases from the Upper Triassic Xujiahe and other formations in the Sichuan Basin in China, by combining previous research results and regional geological background, the gas origin, gas source, and significance of hydrogen isotopes are studied. The results show that gas from the Triassic Xujiahe Formation in the Sichuan Basin is mainly hydrocarbon gas. The methane content ranges 67.89%–98.05%, whereas the content of heavy hydrocarbon gas (C2+) ranges 0.42%–16.62%. Meanwhile, the non-hydrocarbon gas content (CO2, N2) is low. Except for the relatively high content of N2 and CO2 in Well Yue121, the average content of N2 and CO2 are 0.82% and 0.26%, respectively. The gas from the Xujiahe Formation in the Yuanba area has a high average dryness coefficient of 0.991, which indicates that it is dry gas. It is also worth noting that gases from other areas of central Sichuan have a dryness coefficient of less than 0.95, which is indicative of wet gas. The δ13C1 value varies from −43.8‰ to −29.2‰, the δ13C2 value ranges from −33.5‰ to −20.7‰, δ13C3 value ranges from −33.6‰ to −19.3‰, and the δ13C4 value ranges from −27.2‰ to −22.2‰. The δD1 value ranges from −191‰ to −148‰, δD2 value ranges from −165‰ to −115‰, and δD3 value ranges from −153‰ to −107‰. Methane and its homologues (C2-4) become more enriched in 13C and D as the carbon number increases (δ13C1 < δ13C2 < δ13C3 < δ13C4, δD1 < δD2 < δD3); the aforementioned is consistent with the carbon and hydrogen isotopic characteristics of thermogenic gases. The thermal maturity RO of the natural gas from the Xujiahe Formation in the Yuanba area ranges 1.09%–1.78%, whereas the RO value of the natural gas from the Xujiahe Formation in other areas of central Sichuan ranges 0.64%–0.92%. The natural gas from the Xujiahe Formation in central Sichuan is mainly from the coal measure source rocks of the Xujiahe Formation. The gas from the 2nd Member of the Xujiahe Formation (Xu-2 Member) in the Yuanba area is mixed gas; it is a mixture of the high-mature coal-derived gas from the coal measure source rock of the Xujiahe Formation and the oil-cracked gas from the Lower Cambrian (and Lower Silurian). The δD value of methane from the Xujiahe Formation in the Sichuan Basin is relatively high as it is higher than −200‰. Compared to the coal-derived gas from the source rocks formed in limnetic facies with freshwater in the Taibei Sag, Turpan-Hami Basin, though at similar thermal evolution stage, the difference of the δD values of methane can be as high as 90‰, indicating that the source rock of the Xujiahe Formation is formed in an environment with water salinization. Keywords: Sichuan Basin, Central Sichuan Basin, Xujiahe Formation, Carbon isotope, Hydrogen isotope, Water salinization |
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Hydrogen isotope of natural gas from the Xujiahe Formation and its implications for water salinization in central Sichuan Basin, China |
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