Poly[μ3-aqua-aqua-μ5-(4-nitrobenzoato)-caesium]
In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxylate O,O′-chelate interaction, a triple-bridging water molecule and a monodentate water molecu...
Ausführliche Beschreibung
Autor*in: |
Graham Smith [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2013 |
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Übergeordnetes Werk: |
In: Acta Crystallographica Section E - International Union of Crystallography, 2005, 69(2013), 12, Seite m664-m665 |
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Übergeordnetes Werk: |
volume:69 ; year:2013 ; number:12 ; pages:m664-m665 |
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DOI / URN: |
10.1107/S1600536813030638 |
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Katalog-ID: |
DOAJ073762342 |
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10.1107/S1600536813030638 doi (DE-627)DOAJ073762342 (DE-599)DOAJc2a8de76a6114054a132a678e668fdeb DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[μ3-aqua-aqua-μ5-(4-nitrobenzoato)-caesium] 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxylate O,O′-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water–carboxylate O—H...O and water–water O—H...O hydrogen-bonding interactions. Crystallography In Acta Crystallographica Section E International Union of Crystallography, 2005 69(2013), 12, Seite m664-m665 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:69 year:2013 number:12 pages:m664-m665 https://doi.org/10.1107/S1600536813030638 kostenfrei https://doaj.org/article/c2a8de76a6114054a132a678e668fdeb kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536813030638 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 69 2013 12 m664-m665 |
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10.1107/S1600536813030638 doi (DE-627)DOAJ073762342 (DE-599)DOAJc2a8de76a6114054a132a678e668fdeb DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[μ3-aqua-aqua-μ5-(4-nitrobenzoato)-caesium] 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxylate O,O′-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water–carboxylate O—H...O and water–water O—H...O hydrogen-bonding interactions. Crystallography In Acta Crystallographica Section E International Union of Crystallography, 2005 69(2013), 12, Seite m664-m665 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:69 year:2013 number:12 pages:m664-m665 https://doi.org/10.1107/S1600536813030638 kostenfrei https://doaj.org/article/c2a8de76a6114054a132a678e668fdeb kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536813030638 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 69 2013 12 m664-m665 |
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10.1107/S1600536813030638 doi (DE-627)DOAJ073762342 (DE-599)DOAJc2a8de76a6114054a132a678e668fdeb DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[μ3-aqua-aqua-μ5-(4-nitrobenzoato)-caesium] 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxylate O,O′-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water–carboxylate O—H...O and water–water O—H...O hydrogen-bonding interactions. Crystallography In Acta Crystallographica Section E International Union of Crystallography, 2005 69(2013), 12, Seite m664-m665 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:69 year:2013 number:12 pages:m664-m665 https://doi.org/10.1107/S1600536813030638 kostenfrei https://doaj.org/article/c2a8de76a6114054a132a678e668fdeb kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536813030638 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 69 2013 12 m664-m665 |
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10.1107/S1600536813030638 doi (DE-627)DOAJ073762342 (DE-599)DOAJc2a8de76a6114054a132a678e668fdeb DE-627 ger DE-627 rakwb eng QD901-999 Graham Smith verfasserin aut Poly[μ3-aqua-aqua-μ5-(4-nitrobenzoato)-caesium] 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxylate O,O′-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water–carboxylate O—H...O and water–water O—H...O hydrogen-bonding interactions. Crystallography In Acta Crystallographica Section E International Union of Crystallography, 2005 69(2013), 12, Seite m664-m665 (DE-627)326977392 (DE-600)2041947-8 16005368 nnns volume:69 year:2013 number:12 pages:m664-m665 https://doi.org/10.1107/S1600536813030638 kostenfrei https://doaj.org/article/c2a8de76a6114054a132a678e668fdeb kostenfrei http://scripts.iucr.org/cgi-bin/paper?S1600536813030638 kostenfrei https://doaj.org/toc/1600-5368 Journal toc kostenfrei GBV_USEFLAG_A SYSFLAG_A GBV_DOAJ GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_213 GBV_ILN_230 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_381 GBV_ILN_602 GBV_ILN_2014 GBV_ILN_4012 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4249 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 AR 69 2013 12 m664-m665 |
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In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxylate O,O′-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water–carboxylate O—H...O and water–water O—H...O hydrogen-bonding interactions. |
abstractGer |
In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxylate O,O′-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water–carboxylate O—H...O and water–water O—H...O hydrogen-bonding interactions. |
abstract_unstemmed |
In the structure of the title complex, [Cs(C7H4NO2)(H2O)2]n, the caesium salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-atom donors, a bidentate carboxylate O,O′-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water–carboxylate O—H...O and water–water O—H...O hydrogen-bonding interactions. |
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